Review
Version 1
Preserved in Portico This version is not peer-reviewed
Well-defined Conjugated Macromolecules in Sensing
Version 1
: Received: 8 April 2020 / Approved: 9 April 2020 / Online: 9 April 2020 (10:06:28 CEST)
A peer-reviewed article of this Preprint also exists.
Krywko-Cendrowska, A.; Szweda, D.; Szweda, R. Well-Defined Conjugated Macromolecules Based on Oligo(Arylene Ethynylene)s in Sensing. Processes 2020, 8, 539. Krywko-Cendrowska, A.; Szweda, D.; Szweda, R. Well-Defined Conjugated Macromolecules Based on Oligo(Arylene Ethynylene)s in Sensing. Processes 2020, 8, 539.
Abstract
Macromolecules with well-defined structures in terms of molar mass and monomer sequence became interesting building blocks for modern materials. The precision of the macromolecular structure makes fine-tuning of the properties of resulting materials possible. Conjugated macromolecules exhibit excellent optoelectronic properties that make them exceptional candidates for sensors construction. The importance of chain length and monomer sequence is particularly important in conjugated systems. The sequence lengths, monomer sequence and structural modification often influence the energy bang gap between HOMO and LUMO orbitals of the molecules that reflect in their properties. Moreover, the supramolecular aggregation that is often observed in oligo-conjugated systems is usually strongly affected by even minor structural changes that are used for sensor designs. This review summarizes the examples of well-defined conjugated macromolecules based on oligo(arylene ethynylene)s skeleton used for sensor applications. The sensing mechanisms and importance of uniformity of structure are discussed.
Keywords
well-defined macromolecules; sequence-defined macromolecules; sequence-defined polymers; conjugated oligomers; oligo(arylene ethynylene)s; biosensors; sensors; process monitoring
Subject
Chemistry and Materials Science, Applied Chemistry
Copyright: This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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