Version 1
: Received: 12 January 2021 / Approved: 14 January 2021 / Online: 14 January 2021 (13:12:12 CET)
How to cite:
Esin, A. S.; Chernysheva, A. I.; Soldatov, M. A.; Karpova, E. A.; Kireev, V. V.; Sirotin, I. S.; Gorlov, M. V. Novel Approaches to Chemically Cross-Linked Phosphazene Structures: Hydrosilylation vs Piers–Rubinsztajn Reaction. Preprints2021, 2021010268. https://doi.org/10.20944/preprints202101.0268.v1
Esin, A. S.; Chernysheva, A. I.; Soldatov, M. A.; Karpova, E. A.; Kireev, V. V.; Sirotin, I. S.; Gorlov, M. V. Novel Approaches to Chemically Cross-Linked Phosphazene Structures: Hydrosilylation vs Piers–Rubinsztajn Reaction. Preprints 2021, 2021010268. https://doi.org/10.20944/preprints202101.0268.v1
Esin, A. S.; Chernysheva, A. I.; Soldatov, M. A.; Karpova, E. A.; Kireev, V. V.; Sirotin, I. S.; Gorlov, M. V. Novel Approaches to Chemically Cross-Linked Phosphazene Structures: Hydrosilylation vs Piers–Rubinsztajn Reaction. Preprints2021, 2021010268. https://doi.org/10.20944/preprints202101.0268.v1
APA Style
Esin, A. S., Chernysheva, A. I., Soldatov, M. A., Karpova, E. A., Kireev, V. V., Sirotin, I. S., & Gorlov, M. V. (2021). Novel Approaches to Chemically Cross-Linked Phosphazene Structures: Hydrosilylation vs Piers–Rubinsztajn Reaction. Preprints. https://doi.org/10.20944/preprints202101.0268.v1
Chicago/Turabian Style
Esin, A. S., Igor S. Sirotin and Mikhail V. Gorlov. 2021 "Novel Approaches to Chemically Cross-Linked Phosphazene Structures: Hydrosilylation vs Piers–Rubinsztajn Reaction" Preprints. https://doi.org/10.20944/preprints202101.0268.v1
Abstract
Finding new ways for the preparation of cross-linked structures is a significant problem in terms of materials for biomedical application, lithium batteries electrolytes, and etc. Within this work we have studied the possibility to utilize hydrosilylation and Piers-Rubinsztajn reactions to obtain cross-linked model phosphazene compounds, containing eugenoxy and guaiacoxy groups. It was shown that Piers-Rubinsztajn reaction cannot be efficiently used to prepare tailored polymer-matrix, due to the catalyst deactivation by nitrogen atoms of phosphazene units. A number of cross-linked phosphazene-based materials was obtained with the use of hydrosilylation reaction and their properties were studied by NMR spectroscopy, FTIR, DSC, and TGA. This work showed a perspective for the use of eugenoxy functional groups for the preparation of three-dimensional hybrid phosphazene/siloxane-based materials for various applications.
Keywords
phosphazenes; cross-linked; hydrosilylation; Piers–Rubinsztajn reaction; eugenol; siloxanes; model compounds; siloxane-phosphazene
Subject
Chemistry and Materials Science, Analytical Chemistry
Copyright:
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.