Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Utilization Perspectives of Industrial Biomass Residue

Version 1 : Received: 29 April 2023 / Approved: 30 April 2023 / Online: 30 April 2023 (04:48:39 CEST)

A peer-reviewed article of this Preprint also exists.

Naydenova, I.; Radoykova, T.; Petrova, T.; Sandov, O.; Valchev, I. Utilization Perspectives of Lignin Biochar from Industrial Biomass Residue. Molecules 2023, 28, 4842. Naydenova, I.; Radoykova, T.; Petrova, T.; Sandov, O.; Valchev, I. Utilization Perspectives of Lignin Biochar from Industrial Biomass Residue. Molecules 2023, 28, 4842.

Abstract

The present study aimed at utilizing technically hydrolyzed lignin (THL), industrial biomass residue, derived in high-temperature diluted sulphuric acid hydrolysis of softwood and hardwood chips to sugars. The THL was carbonized in horizontal tube furnace at atmospheric pressure, in inert atmosphere and at three different temperatures (500, 600 and 700 ºC). Biochar chemical composition was investigated along with its HHV, thermal stability (thermogravimetric analysis) and textural properties. Surface area and pore volume were measured with nitrogen physisorption analysis often named upon Brunauer–Emmett–Teller (BET). Increasing the carbonization temperature reduced volatile organic compounds (40 ÷ 96 wt. %), increased fixed carbon (2.11 to 3.68 times the wt. % of fixed carbon in THL), ash and C-content. Moreover, H and O were reduced, while N- and S-content were below the detection limit. This suggested biochar application as solid biofuel. The biochar Fourier-transform infrared (FTIR) spectra revealed that the functional groups were gradually lost thus, forming materials having merely polycyclic aromatic structures and high condensation rate. The biochar obtained at 600 and 700 ºC proved having properties typical for microporous adsorbents, suitable for selective adsorption purposes. Based on the latest observations another biochar application was proposed - as catalyst.

Keywords

Technically Hydrolyzed Lignin; Carbonization; Biochar Characterization

Subject

Environmental and Earth Sciences, Sustainable Science and Technology

Comments (0)

We encourage comments and feedback from a broad range of readers. See criteria for comments and our Diversity statement.

Leave a public comment
Send a private comment to the author(s)
* All users must log in before leaving a comment
Views 0
Downloads 0
Comments 0


×
Alerts
Notify me about updates to this article or when a peer-reviewed version is published.
We use cookies on our website to ensure you get the best experience.
Read more about our cookies here.