Gas can appear as a result of heating the equipment located below, so the gas will rise up. The density of the heated gas is less than the density of the air, so it is affected by a lifting force equal to the weight of the volume of air displaced by the gas. Practice shows that in the source the concentration (dynamic ratio) can be 300-350 ppm (parts per million), and on the ceiling at a height of H = 5-6 m, the concentration will be 80-90 ppm. In this case, an approximate concentration gradient is set, which can be considered as a potential difference.
Let the heat source heat the solid material, converting it into a gaseous state. The pressure acts the same in all directions, but under the influence of heating, the gas mainly moves upwards, creating convection currents. There is a stream of gas molecules that occupy a certain volume at the heating site at floor level. Let us assume that the source has a constant intensity, i.e., the same number of gas molecules appear every second. At constant pressure, the molecules occupy the same volume at any given moment, creating a cloud of gas step by step.
As the gas cloud propagates, it moves upward. Random factors (convection, turbulence, etc.) give the gas cloud a configuration that is difficult to predict. With a high degree of certainty, which is sufficient to solve the problem, we will assume that the gas cloud has the shape of a cone. In the process of movement, the cone occupies all new layers with a vertex at the ejection point. Rising, the gas cloud will touch the ceiling of the room, and then spread along the ceiling in all directions, falling into the GFS location areas.
The gas cloud will spread across the ceiling and reach one or more gas sensors, which will signal the presence of gas in the room. According to the coordinates of the SFS (gas sensors) that gave the signal, it is possible to solve the inverse problem of determining the location of the gas source on the floor.
Thus, the three-dimensional problem is reduced to a two-dimensional problem. The circle of gas on the ceiling that reaches the sensors must have a square that corresponds to a volume of gas less than the maximum permissible value.
The leading edge of the gas cloud on the ceiling will reach one or more gas sensors, which will signal the gas presence in the room. According to the GFS (gas sensors) coordinates that signaled, it is possible to solve the inverse problem in order to determine the location of the gas source on the floor. Thus, the three-dimensional problem is reduced to a two-dimensional problem - the need to rationally place the GFS on the room ceiling so that they are touched by the boundary of the gas propagation circle of a certain diameter.
The analysis shows that at an equal density in the gas cloud, the propagation rate changes in proportion to the cubic root of the time elapsed since the appearance of the source. With this dependence, the rate of gas propagation decreases rapidly with distance from the source.
2.2.1. Movement of gas from the source of danger to the ceiling of the room
Heating or a chemical reaction converts a substance that can cause a fire from a liquid or solid state to a gaseous state. The gas occupies a larger volume than the source substance, and this excess, which creates pressure, begins to push the gas molecules into the environment. They penetrate between air molecules, spreading throughout the room. The mass of the gas
mg ejected in the first time interval (per second) is equal to the density of the gas
q multiplied by the volume of the cone
V (the radius of the base
r and the height
h) that the gas will occupy.
The concentration unit is ppm (parts per million). With a constant source power, the same gas mass mg will be emitted in each unit of time. The main parameters reflecting the state of the gas are the dynamic pressure P, temperature and density q. In this case, the task is to determine the release of gas, the appearance of hazardous substance molecules. Thus, the physical effect of a fire hazardous process is the dynamic pressure created as a result of the emergence and propagation of gas molecules. In addition, the temperature decreases from the source to the GFS location.
The gas is formed as a result of pyrolysis (thermal decomposition). Heating can lead to fire, explosion, etc. The heated exhaust gas (H2, CO) tends to rise. The pressure on the gas acts in all directions. In addition, the gas molecules are affected by heating and buoyant force directed upwards, so the gas cloud takes on an upward shape. With a good approximation, we can assume that this is the shape of a cone. The top of the cone at each moment of time rests on a source of dangerous gas, where pressure is created.
As time passes, the gas occupies new layers of the truncated cone. Let the source have a constant intensity, i.e., emits the same number of mg molecules in each time interval. Then the layers of the cone have the same volumes for each time interval. The density of the gas during propagation remains constant q = const. This is a stronger condition than the assumption that the density gradually decreases as it moves towards the ceiling. Let us consider a change in the gas velocity under the condition of a constant flow of molecules emanating from the source and a constant gas density in a gas cloud.
Suppose that in the lower part of the room, near the floor, the pyrolysis process has begun due to heating, or for other reasons. The source has a local character, which can be represented as a point (see
Figure 1). Under the influence of pressure, gas molecules spread evenly, creating a cone-shaped cloud, penetrating between air molecules, displacing them, as well as each other. It is assumed that the intensity of the source is constant. For this reason, the number of molecules in all layers of the gas cone per unit time must be the same.
The cone volume occupied by the gas at the first moment of time will be:
where
h1 – cone height,
r1 – cone base radius,
S – cone base area.
As you can see in
Figure 1, the cone radius is equal to the height multiplied by the tangent of the angle а (equal to half the angle of the apex of the cone). Then the volume of the cone
V can be expressed in terms of the cone height
h and the angle
α.
The cone height is the distance traveled by the leading front of the gas per unit time, which is numerically equal to the velocity of gas propagation in the first period. Strictly speaking, for this reason, if the cone top is located in the source at the bottom, then the base at the top should have a convex spherical shape.
During the second period, per unit of time, the gas will spread further, occupying the next layer of the cone. The volume of this layer is equal to the volume created in the first unit of time. From here you can find out the estimated speed of gas propagation. Each layer of the gas volume increment has the shape of a truncated cone.
Let the angle of the cone
α = 45o. During the second period, the gas will occupy the volume
V2. Since the power of the source is constant, then the volume increment, the layer
dV2, which the gas occupies in the second unit of time, is equal to the volume that the gas occupied in the first unit of time
V1. The volume increment layer
dV2 has the shape of a truncated cone. Its volume is equal to the difference between the volume
V2 = 1/3 π r23 = 1/3 π h23 and the volume of the cone
V1 = 1/3π r13 = 1/3 π h13. Then one can write that
where
dV2 is the increase in the volume of gas propagation in the second unit of time; whence we get that
V2 = 2 V1 = 2/3 π r13 .
Hence it follows that the radius of the truncated cone
r2 is equal to
Similarly, we obtain that the radius of the third cone
r3 is equal to
Continuing step by step to consider the sequential movement of truncated cone layers from the gas source, we will thus obtain that in time
t = n the gas will propagate to a distance
There will come a moment when the next layer (the base of the truncated cone) reaches the location of the gas sensors at the level of the room ceiling. Further, the gas area will begin to spread along the ceiling in concentric circles. The cloud boundary will reach one or more gas sensors and the security system will signal the presence of gas. Let the angle of the cone apex be
α 0, (expressed in angles or radians). The volume of the cone
V through the height of the cone
h and the angle
α, at the first unit time.
Comparing the expressions for volumes at the first and second unit’s time, we obtain that the second height is expressed in terms of the first height as
Thus, the increase in height, and hence the rate of gas rise, does not depend on the angle at the cone base at a constant power of the gas source. The expected vertical gas velocity is equal to the difference in the heights of the gas cloud cones per unit time:
Thus, the room heights, the intensity of the gas source (the number of molecules that flow out per unit of time and occupy a certain volume) are given. It is necessary to calculate the time for the gas cloud to reach the room ceiling at the level of the gas sensors, and the time it takes for it to reach one of the sensors.
Since each height increment is created per unit time, the height increment is numerically equal to the upward gas velocity, which is shown in formula (6).
The time to reach the room ceiling is equal to the number of unit layers of the cone t = n, at which the total cone height of the gas cloud hn becomes equal to the height of the room H. The upward velocity of the gas, v, will decrease in proportion to the increase in the area of the cone layers base.
Height
H, the level of gas sensors location will be reached in time
t, equal to the number of layers of gas
n when it propagates to the ceiling
t = n
The volume of the initial gas emission depends on the magnitude of the angle of the base of the cone. If we assume that the angle at the base of the cone is 60 degrees, then the initial volume will be three times less than for an angle of 90 degrees. The radius of the gas cloud on the ceiling will be smaller. The speed of movement along the ceiling to the locations of gas sensors will also change.
Consider an example of calculating the time and speed of gas propagation in a room. Height values are selected taking into account the technological features of the protected premises.
Let the Room Height be 4 m. Let’s take a second as a unit time. The gas ejection cone in the first second has a height of 1 m, the cone apex angle is equal to the right angle, 90°, i.e., the cone radius is equal to the height,
r = h, the gas source has a constant intensity.
Table 1 gives the characteristics of the cloud: the cone height over time, the velocity of the upward gas propagation, and the volume dynamics of the gas cloud. It shows the time during which, under given conditions, the gas cloud reaches the height of the ceiling, and the accumulated volume of gas in the room.
At 64 seconds, the gas cloud reaches the ceiling. The accumulated volume of gas in the room is the circle radius, the cone base is equal to the cone height, therefore, is 4 meters, and then the gas begins to spread horizontally under the ceiling. A similar calculation shows that at a room height of 6 m, the gas reaches the ceiling at 220 seconds from the start of the ejection.
2.2.2. Gas movement from the place of reaching the ceiling to the sensors
After raising the gas cloud to the ceiling, we get a circle at the top, the dimensions of which may be less than the distance between the sensors. The gas will spread across the ceiling until it reaches the sensor, which will generate an alarm, i.e., report the danger.
Suppose that when moving along the ceiling, the thickness of the gas layer is constant, and is equal to the height of the last layer of the truncated cone that reached the ceiling. In
Table 1, the thickness of the gas layer at the ceiling was equal to 0.0207 m. For each subsequent period of time (second), a ring of gas diverges along the ceiling, the volume of which is equal to the previous volumes (assuming a constant intensity of the gas source). When the ceiling is reached, the area of the circle
Sn is equal (if the angle of the cone is 90
0):
This is a two-dimensional case of the pattern that is considered in the analysis of the rise of a cloud of gas to the ceiling. That is, each ring that spreads across the ceiling has the same area as the circle, the base of the cone, a cloud of gas that has risen to the ceiling.
In the second period, the gas will spread further, occupying the next ring. The area of the second ring, as well as subsequent rings, is equal to the area of the base of the cone. From here we find the rate of gas propagation. For the second period of time, gas will occupy an area of
Sn+1.
Since the power of the source is constant, the increment of the area of the circle, the ring,
dSn+1, occupied by the gas for the second unit of time, is equal to the area
S1, occupied by the gas for the first unit of time. The area of the ring is equal to the difference between the area
Sn+1 = π
rn+12 and the area
Sn = π
rn2 . Then we get that
where
dSn+1 is the increment of the gas propagation area for the second period of time of movement along the ceiling; from where we get that
Sn+1 = 2 Sn = 2 π
rn2. It follows that the radius of the ring
rn+1 is
Reasoning similarly, we get that in the third period of time the gas will occupy a ring of radius
rn+2.
Continuing to consider the sequential propagation of the rings, we obtain that during the time
t = n + m the gas will propagate over a distance
Two points in time are of interest. The first is when the radius of the ring exceeds the distance between the sensors. From this point on, gas detection is guaranteed. The second point is when the radius of the ring reaches the size of the room. From this point on, we can assume that the room is filled with gas.
Table 2 shows the calculation of the gas propagation on the ceiling before reaching the sensor. Further, the movement of gas to the boundaries of a square room, with a side of 15 m.
The first column shows the time elapsed since the beginning of the movement of the gas cloud on the ceiling. The radius of the ring is calculated by formula (12). The distance between the sensors is A = 6 m. In this case, the radius of the ring is equal to A at 40 seconds; the volume of gas will be 109 m3. The gas reaches a distance of 6 m to the walls of the room in 80 seconds. At the distance between the sensors A = 5, the radius of the ring is equal to A at 25 seconds, the volume of gas will then be 93 m3.
The intensity of the source determines the rate of propagation of the gas. At the same time, the higher the velocity of the gas, the faster it will reach the sensor layer and will be registered. In this respect, the power of the source and the increase in the dangerous volume of gas are not directly proportional. This dependence can be widely neglected. The amount of gas in the hemisphere under the ceiling is proportional to the volume and density of the gas. The assumption that the gas propagates in a hemisphere of the same density is sufficient to ensure a level of safety, since it is a stronger condition than would be necessary if the density of the gas decreases as it moves away from the source.
2.2.3. Selecting sensor locations
It is necessary to choose the location of sensors in the protected area, which will ensure safety and will be economically feasible. The hexagonal arrangement of the sensors provides the densest, without gaps, coverage of the protected area. The distances between the sensors form equilateral triangles, with the side that we denote through
A. In
Figure 2 shows two variants of the hexagonal arrangement of sensors - on the left with a lower frequency, with a distance between sensors
А1, on the right with a higher frequency, with a distance
А2. The black circle corresponds to the boundary of the gas area, which has risen to the top and spreads along the ceiling.
With a more frequent arrangement of sensors, gas is detected earlier, with a smaller volume of gas emissions. The ceiling area is covered with sensors without gaps, except for areas near the walls of the room. For complete closure, additional sensors can be placed near the walls. At the same time, when the gas rises along the walls, the pressure will more actively displace its molecules into the inner regions of the room, into the zones of action of the sensors. Thus, at the walls and in the corners of the room, the gas reaches the sensors faster than in the centre of the room.
In
Figure 3 shows a circle of gas on the ceiling of the room, which is described around a triangle of sensors arranged in a hexagonal pattern. This is an element of the situation shown in
Figure 2. The figure shows the most unfavourable situation that occurs when the gas region reaches the ceiling in the centre of the triangle, at the vertices of which the sensors are located.
The position of the gas source under the sensors corresponds to the largest volume of gas accumulated in the room. Therefore, if the gas reaches the level of the sensors at any other point, then the gas leak notification will be received with smaller volumes of gas in the room. The sensors form an equilateral triangle, the side of which is equal to
A – the distance between the sensors. The radius of the described circle L, which determines the area of gas propagation along the ceiling, is
The mass
mg of a given volume of gas, as shown in (1), with guaranteed registration, at a constant density
q will be (which can be considered the maximum, i.e., the upper estimate of the mass of the gas, taking into account diffusion and pressure change)
In this case, the minimum volume of gas
Vmin =
Vup for registration occurs when the gas cloud reaches the ceiling height
H, (the level of the sensors). Its mass is equal to
When the gas reaches one of the sensors, a message will appear indicating the presence of gas. The message will appear as a signal on the operator’s monitor, which shows the location of all sensors. The localization of the signals will indicate the location of the danger. At the same time, the signals are sent to the automated security system. In this system, the coordinates of the sensors that gave the signals are used to calculate the coordinates of the location of a possible gas source, and measures are taken to prevent the threat or eliminate the fire.
As the distance between sensors decreases, the number of sensors increases, and therefore the cost of the safety system increases. At the same time, the volume of flammable gas that will have time to spread before it is registered is reduced.
Let’s consider the
X and
Y coordinates of the placement of sensors under the ceiling, and the dependence of the volume of gas on the density of filling by the sensors. Let the room have dimensions
Tx on the
X axis and
Ty on the
Y axis; i.e., the area of the room
S is equal to
Let’s calculate the coordinates of the sensors at a hexagonal location. The distance between the sensors is A. The sensor is located in the centre of a regular hexagon with side C. Let’s start placing the sensors from the origin located in the lower left corner of the room.
The coordinates of the first sensor
D11, located in the first row, are equal to:
The coordinates of the second sensor in the first row
D12 are:
The coordinates of the
n-th sensor
D1n in the first row are:
The first row is filled, and it is necessary to consider the possibility and necessity of filling the remainder to the wall of the room, provided:
The coordinates of the first sensor
D12, located in the second row, are:
The coordinates of the
n2-th sensor
D2n, located in the second row, are:
The second row is filled, and it is necessary to consider the need to fill the space up to the wall of the room, provided:
Having filled the rows of sensors to the right and up, we solve the issues of closing the areas adjacent to the walls with sensors. Practice shows that no special control is required at the borders. Corners and walls direct gas to the central part of the protected room, where the sensors are located.
The sum of the intervals between the sensors in each row, taking into account the initial distance, should not exceed the length of the room.
The number of such rows
dy = 2Ty / A, where
A/2 is the distance between the rows. Thus, it is possible to obtain an estimate of the total number of sensors
d
The considered example demonstrates the application of the developed method of gas sensors location to ensure the fire safety of industrial premises.