The co-word analysis was used to recognize (a) the conceptual structure of the smart textile literature, (b) most frequently used keywords used by researchers, and (c) main research areas and trends in the research field.
Clusters of KW as indicators of research areas
Cluster 1 (Red) was formed around the keyword SMART TEXTILES (occurrence 1,021), with 294 links and a total link strength of 842, which is the highest among all the authors' keywords. Overall, this leading term is closely linked to core terms in other four clusters. The red cluster is rather general and thematically covers smart textile materials, technologies, applications and properties. Examples of keywords with high occurrence (>10) in this cluster are: textiles, carbon nanotubes (CNTs), MXenes, strain sensors, supercapacitors, conductive textiles, conductive polymers, polyaniline (PANI), polypyrroles, reduced graphene oxides, graphene fibres, nanocomposites, nanoparticles, nanomaterials, nanotechnologies, energy storage, Joule heating, silver nanovires, silver nanoparticles, EMI shielding, shape memory, stretchable electronics, accelerometers, microcapsules, liquid-crystals, hydrogels, sol-gel, flexibility, flexible devices, washable.
The content analysis shows that among the materials, those that ensure the conductivity of the textiles through the use of nano-sized particles or through the use of nanotechnologies predominate. The applications are very broad and range from sensors (heart rate, pH, gas, monitoring human movements) to energy storage devices, EMI shielding and flexible displays. The properties depend on the type of smart textiles and their capability; flexibility and washability are often emphasised. Some properties in this cluster are related to functional textiles rather than smart textiles, such as flame retardant, UV protection, self-cleaning, antibacterial, antimicrobial. The reason may be historical, due to confusing terminology and incomplete standards for defining basic terms, namely smart and functional textiles in the early stages of research and development of new materials and technologies in this field.
Cluster 2 (Green) is focussed on the keyword E-TEXTILES (occurrence 665), with 237 links and a total link strength of 573. The cluster presents smart electronic textiles, their constitutive parts, such as sensors and conductive yarns, their design, and placement in computer networks for specific applications. Examples of specific keywords with high occurrence (>10) in this cluster include: wearable electronics, textile electronics, wearable computers, sensors, wearable sensors, wearable computing, ubiquitous computing, physical computing, internet of things (IoT), body area network, body sensor networks, machine learning, artificial intelligence, deep learning, conductive yarns, conductive threads, textile transmission lines, wireless power transfer, textronics, health-care, telemedicine, e-health, activity recognition, capacitive sensing, radio frequency identification (RFID), prototyping, fashion, technology acceptance, washability, durability, sustainability.
This cluster is more structurally distinct and narrow. Keyword analysis identifies materials for the production of e-textiles, such as conductive fibres, conductive yarns, conductive threads, conductive materials, and CNT fibres. They are applied in textile body sensors, wearable sensors, sensor networks, wireless sensor networks, thermistors, and RFID. During the operation of an e-textile, data is collected from sensors that monitor various body parameters and transmitted to body area networks and the IoT using microprocessors, physical computing interactive systems, displays, and other user interfaces. Large amounts of data are being processed using machine learning, deep learning, and other artificial intelligence methods. The emergence of e-textiles in the market is already impacting Industry 4.0 as well as e-health and telemedicine by solving complex medical challenges and improving population healthcare. Great efforts have already been made to improve the durability and washability of e-textiles, but there is still room for improvement by coating delicate parts of e-textiles with flexible and thin coatings that are resistant to moisture, water, wrinkling, and creasing during wear and textile care .
Cluster 3 (Blue) is organised around the keyword SMART FABRICS (occurrence 136), with 104 links and a total link strength of 106. The cluster presents smart fabrics items that are designed for clothing, from the viewpoints of textile technologies, specialized smart technologies and materials, as well as design and properties of products. Examples of specific keywords with high occurrence (>10) include electrospinning, triboelectric nanogenerators, energy harvesting, actuators, soft actuators, poly(3,4-ethylenedioxythiophene) (PEDOT), poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS), antennas, self-powered sensors, humidity sensors, thermoelectrics, thermal energy storage, embroidery, knitting, 3D printing, microencapsulation, smart materials, PCMs, nanofibres, conductive fibres, conducting polymers, artificial muscles, soft robotics, shape memory alloys, shape-memory polymers, polyvinylidene difluoride (PVDF), liquid metal, piezoelectric, self-powered, photoluminescence, electrical properties, thermoregulation, thermal comfort, rapid prototyping, design process, innovation.
Cluster 3 is oriented towards smart fabrics, which are only one of the segments of smart textiles. Fabrics can be woven, knitted or non-woven and thus technologies such as knitting, weaving and electrospinning can be used to create smart fabrics, in addition to embroidery and 3D printing. Advanced materials, such as conductive yarns or wires made from shape memory alloys can be incorporated into the fabric structure, while shape memory polymers (SMPs) can be used to produce shape memory fibres, shape memory yarns or shape memory fabrics. The latter may also be made by coating a shape memory emulsion or shape memory film. SMPs and their composites deform back to their original shape after severe deformation due to Joule heating, magnetism, moisture, light or solutions. The response of SMP composites depends on the type of filler (carbon particles, CNTs, mixture of CNTs and PVDF, carbon fibres, electromagnetic fillers, hybrid fibres) or the embedding of an optical fibre. Conductive polymers such as PEDOT or PEDOT:PSS can be used to make physical sensors for humidity, temperature, pressure and strain. Piezoelectric plastic materials such as PVDF can generate electrical charge when mechanically deformed. They are often used for health monitoring. The application of PCMs to textiles usually requires microencapsulation of the PCMs, and then the application of microcapsules to the fabric by coating or printing. Such a fabric responds to temperature and enables a thermoregulatory effect that ensures the thermal comfort of the wearer. Smart textiles require energy to maintain the sensors and actuators. An alternative device for energy harvesting is the triboelectric nanogenerator, a mechanical harvester based on triboelectricity that harvests electrical energy from the mechanical energy of the environment. The advantages of triboelectric nanogenerators are high instantaneous output power, an environmentally friendly, low cost manufacturing process and different operating modes tailored to target applications. In addition, the use of self-powered sensors or self-powered devices can reduce the need for additional devices for energy harvesting.
Cluster 4 (Yellow green) is focused on WEARABLES (occurrence 210), with 151 links and a total link strength of 193. The cluster presents products at a cross-section of wearables (a broader term for all items that can be worn) and smart textiles, as reflected in typical keywords with high occurrence (>10): wearable devices, wearable system, flexible electronics, smart shirt, smart socks; textile sensors, flexible sensors, temperature sensors, biosensors, fabric sensors, optical sensors, piezoresistive sensors, capacitive sensors, stretch sensors, strain sensing, textile pressure sensors, FBGs (Fibre Bragg gratings); health monitoring, m-health (mobile health), electromyography (EMG), rehabilitation, monitoring, respiratory monitoring, respiratory rate, heart rate variability, vital signs, gait analysis, sports.
The Wearables cluster contains publications on various sensors and other devices that can detect physiological changes and are used in close contact with the body in smart clothing such as shirts, socks, sportswear, belts, etc. Ideally, wearable sensors should be resistant to mechanical, chemical, and thermal impacts. Sensor concepts based on chemical, physical and thermal mechanisms of action are suitable for the application in smart textiles to detect various parameters such as forces, displacements, thermal energy, humidity, chemicals, UV radiation, etc. Stretch sensors are used to monitor body parameters because the fabric is in direct contact with the skin over a large area of the body. Therefore, monitoring occurs at several points on the body. Pressure sensors are used either as switches and interfaces to electronic devices or also to monitor the user's vital signs. Textile piezoelectric resistance sensors are used to detect movement and respiration. Fabric biosensors can be used to record the electrical signal from the heart – electrocardiogram (ECG), muscle response or electrical activity in response to stimulation of the muscle by a nerve (EMG), brain activity – electroencephalography (EEG), as well as general vital signs such as heart rate, blood pressure, body and skin temperature, respiratory rate, and oxygen saturation. Constant control over an individual's health and fitness through daily monitoring of vital signs can contribute to proactive care for healthy living in the treatment of chronic diseases, rehabilitation after surgery, progress in sports training, or simply for general preventive monitoring of the user's condition.
Cluster 5 (Violet) is grouped around the keyword WEARABLE TECHNOLOGIES (occurrence 124), with 89 links and a total link strength of 104. The cluster presents electronic technologies that are integrated into textiles to be worn on the body. Among keywords with highest occurrence (>25) in this cluster are intelligent textiles, ECG, electrodes, textile electrodes, textile antennas, wearable antennas, pressure sensors, printed electronics, screen-printing. Other specific terms with occurrence >10 include dry electrodes, sensing, wireless communications, structural health monitoring, conductive ink, melt spinning, multi-material fibres, composite materials, ergonomics.
Although the fourth and fifth clusters are closely related, the fifth cluster focuses more on technologies that support the production of wearables. These are electronic devices embedded in textile clothing worn by individuals that are responsible for collecting, analysing and transmitting personal data, usually with the specific aim of providing healthcare. The production of robust and rigid sensors is now being replaced by new materials that are stretchable, flexible and resistant to chemicals, so new materials and new technologies are receiving more attention. Printed electronics are made with screen or inkjet printing of conductive inks. Melt spinning is often used to spin highly stretchable and electrically conductive filaments. Composites and multi-material fibres are gaining acceptance in the manufacture of sensors due to their specific advantages over single fibres/materials. The use of dry electrodes, which include textile electrodes, is more suitable for daily and long-term use, as dehydration due to electrolyte deficiency does not occur. These types of electrodes are especially desirable for EMG recording. The classic antenna on textiles is nowadays replaced by a textile antenna whose task is to communicate between the sensor and the external device. Wearable antennas must be flexible, lightweight, washable and robust. They enable wireless communication between the body network, where the user's physiological data is collected, and the health centre.
An overview of new trends - the latest concepts and propulsive research topics
When considering the
time dimension, certain general keywords seem to be more important used and more frequently at the beginning of the observed period (e.g., wearable computing, smart materials, protective clothing), while specific terms such as wearable sensors, wearable electronics, textile electrodes became typical in the middle of the observed period. Research topics such as liquid metal, MXenes, textile electronics, triboelectric nanogenerators, have gained importance in the last years. The overlay visualisation of the authors’ keywords is shown in
Figure 12, where the colour of the circles is determined by the average publication year of the documents in which the authors’ keyword appears. A colour bar displayed in the lower right corner of the visualisation ranges from blue (oldest average publication year) to green and yellow (newest average publication year).
To further explore trends in the field of smart textiles, the most recent keywords with an average publication year younger than 2020 were identified and further examined in new scientific publications. The most recent keywords with at least 10 occurrences are listed in
Table 5, and are presented in the following text as
hotspots of recent research.
Liquid metal. Liquid metals possess unique properties in ambient environment, such as fluidity, high conductivity and intrinsic stretchability. In smart textiles they have been applied in chemical sensors, wearable electronics and stretchable devices [
127]. Elastic liquid metal based triboelectric fibres can harvest mechanical energy via the triboelectric effect, and have been be applied as power sources for wearable electronics and functional textiles [
128]. Conductance-stable liquid metal sheath-core microfibres are appropriate for the production of stretchy smart fabrics and self-powered sensing [
129]. Liquid metals can be 3D-printed to produce interconnects in stretchable electronics [
130].
MXenes. MXenes are two-dimensional inorganic nanomaterials consisting of atomically thin layers of transition metal carbides, nitrides, or carbonitrides. Due to their excellent electrical conductivity, enriched surface functionalities, and large surface area, MXenes have been used as building blocks for next-generation wearable electronics, flexible electronics, and, in combination with fibres, yarns, and fabrics, smart textiles. MXenes enable wearable smart textiles for energy storage, power generation, strain and humidity sensing, EMI shielding, Joule heating, healthcare, and biomedical applications [
7,
131].
Textile electronics. Textile electronics contain fibres or fibre assemblies with electronic functions for the generation, transmission, modulation, and detection of electrons. Their characteristics include high performance, light weight, handiness, flexibility, comfort, and low strain under severe deformation [
132]. A new generation of 1D fibre-shaped electronics has been applied in devices for energy harvesting, energy storage, light emission, and sensing. They are small in diameter, lightweight, flexible, and can be fabricated into soft textile electronics [
133].
Self-powered. One of the great challenges for smart textiles research and development are sustained self-powered textile-based devices that can also be used as elements of the Internet of Things and the Metaverse as its emerging successor. Mechanical energy harvesting technologies such as triboelectric nanogenerators, piezoelectric nanogenerators, and electrochemical mechanical generators have been used to convert mechanical energy directly into electrical power [
14]. Other energy sources have also been considered for conversion into electricity, such as photovoltaics, thermoelectric generators, electromagnetic generators, magnetoelastic generators, pyroelectric and hydrovoltaic systems [
21,
40,
134]. Examples of achievements include highly integrated composite core/shell fibres for weaving triboelectric nanogenerators, that can be used in self-powered smart textiles; these fibres are stretchable, conductive, with good pliability and high resistance-strain sensitivity [
135]; washable smart textiles based on triboelectric nanogenerator arrays used as bedsheet for real-time and self-powered sleep behaviour monitoring [
136]; self-powered smart gloves based on the triboelectric effect and electrostatic induction, that can be used for a variety of purposes, including gesture recognition, sign language translation, human-machine interfaces, advanced robotic control, user identification, and object recognition [
137].
EMI shielding. Digital and electronic devices cause interference of electromagnetic waves that negatively affect nearby electronic devices, communication signals, and human health. Textile materials, such as cotton, silk, polyester, nylon, spandex, polyethylene terephthalate, etc. can be modified by various methods and techniques with conductive materials such as silver nanowires, liquid metals, Cu nanoparticles, CNTs, graphene, graphene oxide, MXene, polypyrrole, or PEDOT to perform the function of protection from EM waves - to provide EMI shielding [
138].
Self-powered sensors. Self-powered sensors constitute an important sub-class of self-powered products. Based on innovative self-powering technologies, they are harvesting energy directly from the working environment to ensure long-term sustainable operation. In addition, their output voltage and current are additional readout signals so they can simultaneously serve as self-powered sensors for content creating and for energy supplying [
21]. Examples of smart textiles as self-powered sensing platforms include a textile thermoelectric generator for monitoring body temperature [
139], and a smart bedsheet for monitoring human sleep [
140], smart textile socks as a human-computer interface in a virtual reality space [
141], a smart textile glove for human sign language recognition [
142], a textile magnetoelastic generator for monitoring cardiovascular parameters [
143], piezoelectric smart textile for sensing heart beats and speech [
144], a textile biofuel cell that can generate electricity from swear enzymes to monitor the concentration of ions in sweat [
145].
Silver nanoparticles. In functional textiles and in older generations of smart textiles, silver nanoparticles have been traditionally used for antibacterial, antifungal, antistatic, free-radical scavenging, catalytic, electronic, water treatment, sun protection, and air treatment purposes [
10,
146]. Solution immersion, layer-by-layer deposition, and sonochemical processes are established methods to deposit silver nanoparticles on various textile materials [
146]. In the third generation of smart textiles, silver nanoparticles offer new functions, such as the production of smart stimuli-responsive textiles with simultaneous moisture management and controlled antimicrobial activity by embedding silver nanoparticles into a temperature- and pH-responsive microgels applied to cotton fabrics [
147]; conductive inks for e-textiles and screen printing of silver inks for the production of washable, electrically conductive materials for printed circuit boards and RFID tags [
22], production of conductive fabrics by the dip and dry coating with silver nanoparticles for applications in EMI shielding, lightweight batteries, and molecular electronic devices [
148], use of PVDF nanofibres coated with nonpolar silver nanoparticles as electrodes for piezoelectric sensors [
149], and fabrication of textile-based triboelectric nanogenerators consisting of an active layer of graphite carbon nitride nanosheets loaded with silver nanoparticles on carbon fibres for use as wearable power sources [
150].
Strain sensing. Mechanisms for detecting mechanical deformation in strain sensing are based on resistive, capacitive, piezoelectric, as well as electrical time-domain reflectometry and triboelectric effects [
151]. Signal transmission in new flexible strain sensors is structurally dependent on the conductive material deposited on the substrate material. Flexible base substrates are synthetic or natural textile polymers, while the conductive materials can be metallic (silver nanoparticles), carbon (CNTs, graphene, carbon black nanoparticles) or conductive polymeric materials (PANI, polypyrrole (PPy), polythiophene (PTH), such as PEDOT or PEDOT:PSS, MXenes, ionic gels or hydrogel fibres) [
20,
151,
152,
153,
154]. Desirable properties of strain sensors include flexibility, stretchability, minimal hysteresis, high sensitivity, wide sensing range, fast response, reliability, light weight, long-term stability and durability, comfort and industrial mass production capability [
20,
151]. Moreover, they can be self-powered, [
152] or self-healing [
153]. Strain sensing technologies are used in wearable sensors for personal healthcare (ECG, respiration, pulse, blood pressure, gait measurement, motion monitoring), physiological monitoring, sign-to-speech translation, and human-machine interaction [
20,
151,
152].
Sustainability. The issue of sustainability in the context of smart textiles is addressed from two perspectives. First, it addresses the issue of sustainability in the production, recycling, and waste treatment of smart textile products. The sustainability of smart textiles depends on the choice of materials used, the manufacturing processes, and the end-of-life options for the textiles [
23]. Second, numerous positive contributions of smart textiles to sustainability are highlighted in the following areas: environmental monitoring (temperature and humidity sensors, gas sensors); fresh water purification and harvesting (filtering, mist collection, collection by coalescence or mechanical squeezing); personal protection (warming, cooling, electromagnetic protection, EMI shielding, protection against UV radiation, toxic substances and microorganisms); power supply on the body with energy harvesting and storage (triboelectric nanogenerators, thermoelectric generators, photovoltaic textiles, textiles with perovskite solar cells, dry batteries, flexible electrodes, and wearable all-in-one power sources that integrate energy harvesting and storage capability into one textile [
155].
Artificial muscles. Artificial muscles refer to fibrous materials and devices that can contract, expand, or rotate reversibly in response to external stimuli such as magnetic fields, electricity, irradiation, heat, and atmosphere [
156]. Materials that convert electrical, chemical, or thermal energy into a shape change can be used to form artificial muscles. Conductive CNT fibres have been used to create artificial muscles [
157]. More recent inventions are based on sheath-run artificial muscles, in which the material that drives actuation is a sheath on a twisted or coiled core, which may be a low-cost yarn [
158,
159]. Other examples include woven hydraulic artificial muscles [
160], aerogel fibres [
161], printed hydrogel artificial muscles [
162], and artificial muscles made from hierarchically patterned helically wound yarns that are self-adaptive to ambient humidity and temperature changes and exhibit plant-like tropisms [
163]. Artificial muscles can be creatively used in wearable electronics, soft robotics, and medical applications.
Joule heating. The concept of Joule heating, a physical effect in which the passage of current through an electrical conductor generates thermal energy, is used in smart textiles for active warming. Actively heating textiles are made by modifying, coating, or embedding the textile fibre with electroactive materials such as CNTs, graphene, silver nanoparticles, MXene, or PEDOT:PSS [
164,
165,
166,
167,
168,
169,
170]. The application of Joule heating in smart textiles has applications in personal warming in cold environments and medical thermotherapy.
Washable. Washing is one of the most important processes to ensure the hygiene of textiles and thus protect people's health. Therefore, smart garments should be washable. The first studies and produced electronic textiles were based on rigid conventional electronics integrated in textiles, which did not correspond to the stretchability, flexibility and washability of textiles, so the removal of electronic devices before washing was strongly recommended. Nowadays, new technologies and new materials allow researchers to develop flexible, stretchable and washable electronics integrated into textiles without losing comfort and wearability. The latest studies show that coating thread material with poydimethylsiloxane [
171], filling hollow silicon fibres, including conductive yarn, with a mixture of silicone rubber and curing agent [
140], coating triboelectric yarn containing conductive CNTs with PVDF fibres deposited by a tailored electrospinning process [
172], increase the washability of smart textiles. It can thus be said that encapsulating conductive yarns with polymers or coating textile sensors with superhydrophobic compounds makes smart textiles washable.
Thermoelectrics. Thermoelectric materials generate electricity through the thermoelectric effect when a temperature gradient is applied. In new smart textiles, thermoelectric generators are used as flexible, self-powered solid-state modules that passively harvest energy from the heat of the human body. They operate on three principles: the Seebeck coefficient, the Peltier effect, and the Thomson effect [
134]. Examples of inorganic thermoelectrics include metals (silver, copper), chalcogenides (bismuth telluride, antimony telluride), and metal oxides (zinc oxide), while among organic materials conductive polymers are used, such as polyacetylene, polypyrrole, PANI, PEDOT, and PEDOT:PSS [
40,
134]. Dopants can be incorporated into a base material such as graphene, graphene oxide, and CNTs to dope conductive polymers and increase the overall electrical conductivity of the system [
134].
Triboelectric nanogenerators. Triboelectric energy harvesting is based on mechanical rubbing and electron transfer [
40]. Triboelectric nanogenerators are nanodevices that harvest biomechanical energy from human body movement [
173]; they couple the triboelectric effect and electrostatic induction to convert mechanical energy into electricity [
41]. Proper choice of materials and structures enhances performance [
173]. Many designs and combinations of materials have been developed and fabricated. In general, triboelectric nanogenerators consist of substrates, electrode layers, and triboelectric layers [
174]. Flexible substrates for triboelectric nanogenerators can be selected from polyimide, polydimethylsiloxane (PDMS), polyurethane, polyethylene terephthalate, or silk fibres. The electrode layer is a conductive material selected from carbon-containing materials (carbon particles, CNTs, graphene, carbon fibres), conductive polymers (polypyrrole, PANI, poly(P-pheylene-vinylene), polyetheretherketone (PEEK), PEDOT:PSS), metallic nanowires (silver, gold, copper nanowires), or conductive fibres, yarns, or fabrics. Negative triboelectric layers include PVDF, polytetrafluoroethylene (PTFE), polyethylene terephthalate (PET), and PDMS, while positive triboelectric materials are mainly nylon 66, silk, and cellulose [
40,
174]. The main principle of the design of textile triboelectric nanogenerators is to suitably fit two friction surfaces with different properties into a textile. Therefore, triboelectric nanogenerators can have different structures, such as (a) a thread with a tubular structure, e.g., elastomeric material and a spiral inner electrode adhered to a tube with the dielectric layer and the outer electrode; (b) a modified fabric containing surfaces with microstructures of different materials; (c) a fibre with core-shell structure with a conductive core and an insulated shell, e.g. a silicone rubber coated stainless- steel thread, sewn onto an elastic textile with a serpentine shape, (d) a triboelectric nanogenerator based on a three-dimensional textile [
41]. Textile triboelectric nanogenerators basic modes of operation include single-electrode mode, lateral-sliding mode, vertical contact-separation mode, and free-standing triboelectric layer mode, each of which has its application possibilities and ranges[
15]. Potential approaches to improve mechanical-to-electrical conversion and increase power output of textile triboelectric nanogenerators include surface/interface physical treatments, chemical modifications at the atomic level, structural optimization, control of the working environment, and integrated energy management [
42].
Gait analysis. Gait analysis is the systematic study of locomotion, analysing parameters such as body movements, body mechanics, and muscle activity. Soft wearable electronic technologies used for gait analysis consist of flexible sensors, microcontrollers, and power supply units. Flexible, stretchable, lightweight, mechanically and temperature stable, and body compatible materials are used, such as textile polymers, conductive organic polymers, inorganic MXenes, nanomaterials, metals, ionic liquids, and hydrogels [
175]. Smart textiles for gait analysis include smart socks, smart shoes and shoe insoles, smart trousers, exosuits, knee pads, skin-mounted textile sensors, and whole-body networks [
120,
141,
175,
176,
177,
178,
179,
180,
181,
182]. Gait analysis is essential in medicine (medical diagnostics, rehabilitation or prevention in orthopaedics, physiotherapy, neurology, psychiatry, gerontology), sports (performance improvement, rehabilitation after injuries), biometrics (identification, authentication, surveillance of persons, criminal investigation), virtual reality and game controllers [
141,
176,
179,
180,
183].
Self-cleaning. The term self-cleaning in smart textiles refers to coatings that work with two mechanisms [
184]. The first mechanism is based on the lotus effect, which is achieved by alkyl- and fluoroalkyl-substituted silanes and fluorine in the form of fluorocarbon polymers. This type of self-cleaning surface is based on the superhydrophobic properties of coated surfaces, which can be achieved by introducing micro-nanostructures on a surface together with the use of low surface energy materials. The lotus leaf has a low surface free energy due to its specific surface structure and composition, which translates into low adhesion between the surface and water droplets. On such a surface, the water forms spherical droplets with a contact angle of more than 150°. In this case, the water droplet rolls down the surface, picks up dirt from the surface and cleans it. It should be emphasised that fluorinated compounds are being used less and less in coating systems due to possible risks to human health and the environment. Therefore, fluorine-free coatings have been synthesised, such as PDMS, hexadecyltrimethoxysilane (HDTMS), noctyltriethoxysilane (OTES), octadecyltrimethoxysilane (ODTMS), trichloro(octadecyl)silane (OTS), aminosilicone emulsions and polyvinylsilsesquioxane (PVSQ) [
185]. The second mechanism is based on photocatalysis, in which the oxidative decomposition of organic dirt and contaminants adsorbed on the surface of textiles takes place under electromagnetic radiation. The residues are then removed by washing. Photocatalytic activity is demonstrated by coatings with nanoparticles of TiO
2, ZrO
2 nanocomposite, TiO
2/SiO
2 composite, ZnO, etc., applied to textiles using sol-gel technology [
185]. Fluorocarbon resin coated phase change conductive fibres show excellent hydrophobic and self-cleaning properties [
186].
Fabrication. The term fabrication refers to the production or invention of individual components that make up larger assemblies or end products. In the case of smart textiles, the term is often used in the context of smart textiles that contain miniature parts, such as elements for wearable electronic textiles [
187], sensors [
188,
189], textile-based triboelectric nanogenerators [
39], miniaturized energy storage systems composed of micro-flexible supercapacitors [
190], miniaturized platforms for autonomous and interconnected textiles applied in personalized healthcare [
13], twisted coiled polymer actuators for artificial muscles [
191], or embedding optical fibre technology in textile fabrics [
192].
Soft robotics. Soft robots aim to be as flexible as living organisms [
193]. Soft robotics is inspired by the movement of living organisms and features excellent adaptability and accuracy in performing tasks [
194]. Textiles are used in soft robotics either as passive or active soft materials. Passive robust textile auxiliary materials in the form of fibres, yarns, and fabrics reinforce the conventional soft materials to transmit forces and improve anisotropy [
193], while active smart textiles in soft robotics in the form of fibres, yarns, or fabrics are used as soft actuators, sensors, or self-powered elements [
193,
194]. Soft actuators can be actuated by mechanisms such as changes in electricity - voltage, charge, current (electrical actuation), light (optical actuation), temperature (thermal actuation), humidity (solvent and vapour actuation), magnetism (magnetic actuation), or pressure (pneumatic actuation) [
194,
195]. Reversible deformation (e.g., elongation, contraction, bending or rotation) is based on changes in the volume, distance or order of the material [
193,
194]. Soft robotics with flexible actuators can be used in medical robots (surgery, drug delivery, motion assistance, rehabilitation), actively deformable garments (functional compression), soft human-machine interfaces (wearable manipulation devices, haptic feedback), bioinspired robots (humanoid, animal or plant-like soft robots), and technical robots for remote sensing and manipulation [
193,
194,
195].