1. Introduction
Thermochemical treatments are alternatives for municipal solid wastes or biomass including combustion, pyrolysis, and gasification, ensuring the generation of three main products are electricity, fuels, and heat presenting each one your advantages and disadvantages [
1]. The main difference between these technologies is the oxygen inlet concentration that feeds the reactors, produces different thermal routes, and consequently changes your products including fuels and hazardous gaseous emissions in the power plants [
2].
All these alternatives need different time residence for the stability of the process and this period can determine the different generated products [
3]. In pyrolysis treatment, the reactor depends mainly on this variable and thus has a considerable influence on the products by the reaction rates, it can produce synthesis gas, bio-oil, and biochar with different concentrations on slow pyrolysis, fast pyrolysis, and flash pyrolysis reactors [
4].
Synthesis gas or syngas is a fuel constituted mainly with carbon monoxide and hydrogen that generally can be used for electricity and/or heat, having energetic potential transformations from chemical synthesis, as Fischer-Tropsch can become gasoline, methanol, kerosene, and other petrochemical derivate [
5]. Energy recovery with syngas chemical looping is an important strategy that reaching municipal solid waste or biomass from thermal or biological treatments. This solution consists of the feeding gas from steam turbine cycles, which is a feasible alternative to biogas providing anaerobic digestion or synthesis gas generated by thermal treatments such as pyrolysis or gasification, which can produce fuels in a biorefinery or electricity generation [
6].
Biological treatments are widely studied, mainly the anaerobic digestion for biogas production, organic waste production in agriculture, and livestock farming this process contributes to carbon dioxide (CO
2) emissions abatement and electricity generation [
7], it evaluated that could reach 4.5 to 6.9 GWh and avoid approximately 19.8 MtCO
2/year. This treatment generates a waste called digestate. Digestate is the matter that is not degraded in the process, generally producing 45 % of the material inserted in the biodigester, equipment that contains the microorganism responsible for the anaerobic digestion process [
8]. Pyrolysis is a thermal treatment evaluated to generate electricity with digestate due to the sustainability of this thermal treatment and lower gaseous emissions. It was estimated that symbiosis of pyrolysis and anaerobic digestion increased 42% electricity compared to stand-alone process microorganisms [
9].
Pyrolysis is a sustainable process applied to organic waste until dangerous chemical waste generates electricity, forming biochar that is a byproduct used as soil conditioning and for carbon capture system [
10]. Incineration with energy recovery in a steam cycle is the technology most popular worldwide, in small and medium plants is interesting to apply cogeneration and provide economic savings [
11]. However generally present hazardous environmental gaseous emissions such as Nitrogen Oxides and Sulfur Oxides (SOx) according to the waste inserted, lower efficiency is estimated in less than 70 % in combined heat and power in relation to gasification and toxic metal concentration in the ash process generation [
12].
Slow pyrolysis configures a process with excellent thermodynamic efficiency for the application of solid wastes or biomass, heterogeneous materials with different heating values, granulometry, and dimensions that generally reduce the power overall as in the gasification systems [
13]. For this, this technology produces as syngas as gasification, reducing the disturbs on power system and environmental impact concerning other time-residence pyrolysis allowing insertion of biomass and solid waste without limitation and prejudice [
14]. Astrup et al. [
15] identified different research, compared in a life cycle assessment of different thermal waste technologies, and noted the information lack about gas generation depending on the solid wastes in all the main thermal treatments such as incineration, gasification, and pyrolysis.
Biomass and/or solid waste power plants are extremely sensitive to the quality of fuel according to moisture content and composition mainly in thermal reactors, due to this particularities dynamic analysis simulation of the electric machine becomes an essential step for the desirable performance in the electricity market [
16]. Fast load ramps characterize this to enhance competitiveness in grid stability and work together with the process modeling of feed-stock materials [
17].
Figure 1 shows the flexibility of the biomass sources that can be treated through the so-called thermochemical routes (direct combustion, pyrolysis, and gasification), as well as the versatility of the energy obtained, ranging from liquid fuels (fuel oil and methanol), solids (coal), gases (synthesis gas), heat and electricity.
Thermochemical technologies basically use three sources of biomass: non-woody plants (aquatic and oil plants), woody plants (wood), and organic waste or waste with hydrocarbons in its composition (agricultural, urban, and agro-industrial). When it comes to municipal solid waste, it’s worth noting that the residual plastic fraction is also part of this composition, as it is made up of hydrocarbons. Pre-treatments have been developed and present possibilities to homogenize important parameters in biomass that increase the energetic and electricity potential [
18]. Those are divided into physical, thermal, chemical, and biological and allow equalized moisture, particle size, lignin, and mineral matter content contributing to the production of an equivalent and linear syngas yield to electricity generation [
19].
Research about syngas is included in current literature, the biomass potential to generate electricity by syngas of Brazil in the Rio Grande do Sul with the rice industries in Pelotas represents a capacity of 7,7 MWh with the rice husk and effluents that could become these industries self-sufficient [
20]. The energy balances of biomass or solid waste thermal treatment by slow pyrolysis plants in rotatory kilns have been applied in modeling works that study the process behavior of biomass and solid waste treatment [
21]. It evaluated that slow pyrolysis get works with low-grade pretreated biomass, becoming self-sufficient after insertion of biomass [
22]. Few variables are evaluated in one thermochemical technology and controlled by operators since have more than 100 process parameters, to improve reliability and conditions of the main challenge which are recovering energy losses and understanding the possibilities during the energy conversion to increase the efficiency as the profitability too [
23].
In slow pyrolysis power plants, there are many different applications due to syngas versatility, such as the potential to generate steam, biofuels, and electricity, and those generally conflicting simultaneously for the price markets and daily or monthly the necessity of supply chain-associated design and operation, identifying the most cost-effective and sustainable reaction pathways in the process [
24]. The versatility of this fuel (syngas) produced, is interesting to determine which application presents more advantages for determined industry depending on the objective and your supply chain applying multi-objective optimization to turn the treatment waste process rentable and feasible for different electrical systems [
25].
Carbonaceous materials of biomass treated from thermal processes such as pyrolysis can be converted and have the potential to manufacture nano-materials for gas sensors due to chemical flexibility and good electrical conductivity, however need research to be flexible and portable detectors and present advantage because of possible long-term re-usability, benefiting when use biomass waste nowadays offering a better feasibility approach for the market [
26]. Production of this carbonaceous material collaborates on the hydrogen storage capacity and chemical combination with metal hydrides being a future strategy for the export of this material contributing consequently to electricity generation from hydrogen to power in the own manufactured country too [
27].
3. Gasification
The method of gasifying renewable inputs to produce fossil fuels by chemical processes from low levels of oxidation inside different models of reactor construction presents a series of modes of operation described in the literature [
36]. Verified that the application of technologies concomitant processes aiming at higher yields and lower pollutant emissions is being widely researched as the connection by biological routes [
37]. Microalgae is an application of decarbonization in gasification technology and waste heat recovery in conjunction with the cooling of the synthesis gas. The fuel generated in the process preceding the mixture in the engine will transform mechanical energy into electrical energy, enabling greater thermal efficiencies, electrical generation, and reduction of pollutants [
38].
In addition to the joint use of biological processes, one can resort to reducing carbon dioxide emissions within the gasification of biomass through chemical activities such as capture by compounds produced at an industrial level such as calcium carbonate, and non-amine solvents [
39]. Solubilize part of a concentration of polluting gases also performing computational simulations and mathematical modeling aggregated to these, which together can present similarities. After validation with experimental tests in the collaboration of estimates mainly in energy levels and/or conservation of mass and gaseous compounds generated in thermal reactions reducing medium-term costs and collaborating in the automation of the reactor [
40].
Some residues are generated in the sludge gasification and disposed of in landfills such as tar, ash, and particulates. The toxicity of this residue, requires higher classes of landfills for disposal, demanding a higher monthly cost as an operating expense post thermal treatment and that can make the process unfeasible, impairing the environmental and electrical efficiency achieved with the energy use of the sludge that collaborates in sustainability and circular economy [
41].
In this way, research on the application of these residues promotes their economic viability, making these by-products after the application of chemical or biological treatments. Such as adsorbent material, and phosphorus recovery, among other alternatives, which will depend on the degree of investment required, plant size, and recovery period through the evaluation and demand of consumer markets [
42].
Carbon capture and storage (CCS) in incineration technology presents the most industrially accepted degree of commercial evolution [
43], considering that there are around 1200 plants in operation with high economic viability mainly in large-scale projects. Incineration reduces the efficiency of electrical generation using the types of cryogenic distillation, chemical air separation, or recirculation of fuel gases [
44]. Applying the most usual routes at an industrial level, verification and evolution of studies that present new technologies can contribute to possible gains in other characteristics of the power plants currently in operation [
45]. Mainly evaluating the integration of systems and visualization tools in real-time, sensors with process control in machine learning, and research in the use of advanced materials and catalysts [
46].
In European countries like Austria, Slovenia, Germany, Greece, Belgium Netherlands, incineration plants are the most used method of thermal treatment of municipal sewage sludge nowadays in conjunction with co-incineration in power plants that use coal as raw material in cement kilns [
47]. Technologies such as gasification and pyrolysis emerge as future possibilities mainly on smaller scales, in Portugal, the use of heat in any of the aforementioned technological options in a centralized way and at strategic points increases the electrical power output [
48]. Automatically collaborates in maintaining operations for long periods since they would have a greater geographic, social, economic, and environmental function [
49].
Check the efficiency rate and find chemical compounds that can dilute the concentration of carbon dioxide emitted and its conversion by mass transfer into a commercial or easy-to-treat by-product, reducing environmental pollution at its final disposal [
50]. Depends on the evaluation of the concept in on-site production, reuse, storage, the economic perspective of operating costs, and investment in the creation of new technologies or application of commercial routes such as separation by catalytic and non-catalytic selective reduction, and dry adsorption. It must be combined with the treatment of other pollutants generated in incineration as fly ash [
51].
The conception of new technological possibilities is important because innovation aims to reduce existing bottlenecks and promote greater environmental sustainability [
52]. With cost reduction and greater operational efficiency in the thermal treatment of municipal or industrial sewage sludge [
53], recent alternatives include the supercritical oxidation of water, microwave-assisted pyrolysis, plasma pyro-gasification [
54].
Within the equipment that performs sludge oxidation in high-pressure atmospheres, generally reaching 22 to 25 MPa and average temperatures around 400°C, there are several challenges to becoming a commercially viable technology due to its high investment costs and operating time, high oxygen consumption compared to other recent technological alternatives [
55]. As old ones, the constant incidence of corrosion and factors associated with the intensity of the process. There is a precaution with the viscosity of the sludge by transporting it in pipes and humidity that a high content increases the production of hydrogen and reduces methane, however, decreasing the calorific value of the gaseous products generated [
52].
The pyrolysis reactions via microwaves, are carried out by controlling the temperature or dielectric power, which starts with temperatures of 200°C. However, it can reach heating ranges of up to 800°C or electrical power of 1200 Watts, and the analysis in real-time temperature increases efficiency in biofuel production and the evaporation rate is a crucial parameter in the mechanism of mass transfer and absorption of consumed energy [
53]. Applying catalysts that increase the heating rate and the cracking of larger molecules collaborates in the yield of the process [
56].
The plasma has different technological aspects and can perform the treatment of organic and inert material when it combines gasification and pyrolysis by the plasma torch which inside reaches 1500°C. It can recover dangerous materials such as cadmium, Lead, Zinc, and Chromium that may exist in some types of sludge such as tanneries in which acidic reagents are applied, among them calcium and potassium oxides with water, filtered in a microfiltration system. Recovery of these chemicals allows reuse and evaluation of the reduction of costs and environmental impact [
34]. However, the technology has limitations arising from the erosion electrode by some fuels and presents a high-energy consumption to start the operation despite its versatile treatment capacity with hazardous waste [
54].
In thermochemical routes, when waste is inserted as raw material, the average energy efficiency achieved among the highlighted technologies is 30 %, in addition to electricity, other products with varied economic value such as fuels, renewable gases, and chemicals from the use of catalysts [
57]. Therefore expanding the global yield rate and possibilities for greater gains of scale in the long term according to the demand for each product generated in the plant and its need in the national or global market. In this context automation can favor operational constancy when the best efficiency range is found, reducing disturbances and losses due to inertia [
58].
The selection of the reactor as the specifications of the inserted raw material and desired products are the factors that allow evaluation of the success of the thermochemical transformation process and the automation [
44]. To continuously reproduce the same results in a way that reaches the degree of desired or required energy efficiency depends on the improvement of machine design according to experiments and multiphase simulations. For guarantee and improve longevity with advanced materials and integration with loss monitoring by sensors and automatic control in process optimization [
59].
After the selection of technology and reactor, the characterization of samples and control diagnosis carried out in each of the three categories of capture and separation of carbon dioxide produced in the thermal process which are divided into pre-filtering combustion, post-combustion and added with oxygen or fuel and catalysts [
60]. When evaluating this better relationship, automatic control favors the reduction of operator training, maximizing economic benefits, and improving process safety as it provides the greatest guarantee of reducing pollutants generated in the system [
61].
In the context of automation applications, several models depend on the desired degree of control. There are several models, that can cause variability and conjunctions, with more than one algorithm according to the strategy that can be adaptive, predictive, intelligent, and automatically coordinated, logic and mathematics to reach the desired operational conditions [
42]. Being dependent on the investments that can be made, requirements necessary and the possible manipulation of operating variables since the process settings according to its capacity, size, and material to be processed and products that aim to be generated are crucial in the favorable financial viability of the project [
60].
Sensor data in a control interface with real-time graphs and historical data provide reports that can provide information that assists in the operation of drive logic, diagnosing and predicting possible failures [
62]. They could avoid and minimize the possibility of sudden stops and adjust the air supply by limiting the formation of atmospheric, water, and soil pollutants [
63].
Platforms that carry out data analysis and processing with expected improvement in the performance of thermal processes with the increase in the calorific value of the synthesis gas that increases the generation of electricity also the temperature of the flue gas, which affects the reduction of pollutants [
64]. The calibration of sensors that measure and control through the creation of alarms and the detection of optimal ranges. It can benefit mechanisms for capturing and filtering the volume of harmful and non-combustible gases with control loops that regulate the concentration of sludge and cooling of the generated gas. This could provide automatic adjustments of the feeding system, especially if there is a recurrence of the use of centrifugal pumps in this operation [
65].
The growth in the scale of renewable energy production with sustainable gas generation by waste can provide an efficient solution in reducing costs and benefits to society within the energy demand. Acting on the supply problem, being able to guarantee safety in electrification, and reducing the transport of toxic or non-toxic sludge in remote locations such as landfills that are generally distant due to the need for ample disposal space [
66].
When automation was applied after carrying out several experimental tests and having an efficient and financially viable control diagnosis, it allowed the expansion of different operation sizes, staggering the operation of plants more easily and quickly with a lower level of technical instruction than in a non-automated and manually operated system [
58]. Avoiding the greater probability of human errors, providing greater operational safety and electricity generation with materials that are currently discarded as waste in the soil [
67].
Mechanisms for purifying and cooling the gases mixed in the engine constitute an important step in the previous improvement of electronic and controlled fuel injection since the volumetric efficiency and less mixed loads benefit the design of rotating thermal machines and the simulation of fuel models [
68].
Combustion that reduces mechanical use of parts with the automation of this flow, allied to the interconnection of the values of the sensors of electrical power, the temperature of the exit gas, and the volumetric concentration of each gas. This will transmit this information and that will allow us to prove the adjustments of the relations between electrical generation x gas cooling x gas separation in the thermal process applied mainly when aiming at the chemical fraction of hydrogen [
69].
The performance of installations that have carbon capture depends on the evaluation of the release of chemical energy during combustion and the influence on the volume and location of oxygen [
70]. According to the particular design of the combustors and the heat transfer measured, applying the statistics that will be a tool assisting in automation, it is possible to diagnose the control strategies with the highest yield, lowest oscillation, and maximum overshoot values automatically assigned in the operation [
71]. As the relationship between the automated insertion and the costs of the minerals applied in the removal of carbon dioxide [
40].
Minimizing the production of sludge and the challenges of providing treatment and quality of water, combining the capture, storage, and transformation of atmospheric pollutants with disposal of lesser environmental impact. This can occur through different mechanisms such as the use of chemical catalysts, drying, and advances in primary and secondary treatment technology in biological reactors [
72]. In addition to being able to cite techniques that promote the reduction of transport costs, which is a factor that reduces the emission of pollutants such as thickening, that is, becoming denser and reducing spacing used in vehicles that carry out the disposal or treatment of the sludge load [
73].
When moisture reduction was carried out by drying mechanical or thermal drives, the CCS improved. Since this decision depends on the demand for power and the correlation between the possibilities of energy gains and the necessary investment, in addition to the fact that in the sludge one must verify the financial economy in the disposition of this matter as the reach of all these aspects following the objectives world climate [
74].
Having evaluated the relations of the automatic control on the quality of the dehumidifying process, acting on the speed of rotation of the drying in the engine by the most efficient frequency conversion on the compound in which it wanted to improve the biological or thermal treatment [
75]. After the reduction of the water content, the release of nutrients is consequently increased and the content of heavy metals is reduced before the execution of the treatment, which through experimental tests can evaluate the level of improvement achieved in these two parameters [
76].
Due to the reduced water content in the sewage sludge, the energy spent on transporting the material decreases, as it provides greater logistical space in terms of both disposal and treatment. In a unit, that uses part of the residual heat in this drying or heat supply with biological treatment by anaerobic biodigestor or thermal such as pyrolysis, gasification or incineration. Carbon dioxide emissions were minimized in values above 50 % evaluating all the steps mentioned [
66].
An improvement in this performance should be verified regarding the economic and investment advantages and disadvantages of applying methods such as thickening, mechanical dehumidification, and conditioning that enable the moisture content in the ranges of 70 to 90 % while thermal drying. It can guarantee water contents between 5 to 10 % and the products generated in each treatment of the inserted sludge [
77].
Applying catalysts after drying the sludge depends on the selection of reactors and on verifying the performance of each adsorbent in its chemical transformation through gas-solids contact, which can be fixed, fluidized, mobile, and rotating in the reactor, in addition to evaluating the minimization of capital costs and operational with the insertion of the chosen catalyst(s). Although increasing costs, increase the generation of economic value and products refined by reforms and/or with load flexibility by a greater percentage, which makes effective the research efforts applied at an industrial level. In a way, that promotes the reduction of pollutant gas emissions after oxidation of the material and with a possible mixture of one or more combined catalysts [
68].
When this occurs in a stable moisture content ratio, that is, with this constant variable it collaborates in the automation of the advancement in rotational speed and the performance of brakes that are assigned in possible stops. It is proportional to the highest combustion and frequency of electric current generated with the drier sewage sludge. Thus, the fixed percentages of moisture lead to greater predictability in the control of these internal combustion engines adapted to synthesis gas and coupled to electric generators by different catalysts, subdividing and statistically. Verifying the emission reduction potentials of polluting gases parameterizing applied catalyst/sludge moisture, pressure, initial and average temperature along with residence time [
78].
Absorption and desorption columns constitute important structures within the existing mechanisms of carbon capture. These must be conditioned and their volumes calculated about the necessary periodic charge of chemical compounds or solvents that will be applied on an industrial or experimental scale. Storage facilities were observed, according to the level of danger, market demand research, and programmatic operational needs [
79]. Together with the load flexibility of the electric power generating plants and the energy that will be commercialized in front of the automation of the data and the machine that collaborates in the design of the strategies that will be applied [
80].
In the pyrolysis process, there are three main parameters evaluated in the percentage composition of products generated, which are the heating rate, temperature, and residence time [
81]. They are interdependent on the chemical and physical reactions of this complexity, involved, also around the geometry of the reactor and the system of supply [
82]. Secondary factors such as particle size and pressure respectively exerted to avoid corrosion in the equipment that reduces its useful life depend [
83].
The application of alkaline catalysts such as sodium hydroxide in a hydrothermal gasification reactor at temperatures of 632 to 717°C improves the performance and yield of fuel gas production and the conjugation of algae can perform sequential fixation and sequestration of pollutant carbon to increase energy recovery [
70]. However, the purification of the gas or sludge inserted must be carried out if there is a concentration of heavy metals since biological organisms cannot withstand these adverse conditions when catalysis by mineralization is carried out only in the improvement of the biochar of the pyrolysis process, it is necessary to evaluate the associated costs in the current currency in the acquisition of carbonates, silicates, phosphates, and hydroxides and this doping in the removal of carbon dioxide by the soil in CO
2/ton [
37].