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Non-isocyanate Synthesis of Aliphatic Polyurethane by BiCl3-Catalyzed Transurethanization Polycondensation
Version 1
: Received: 1 April 2024 / Approved: 1 April 2024 / Online: 2 April 2024 (02:37:09 CEST)
A peer-reviewed article of this Preprint also exists.
Ochiai, B.; Kobayashi, Y. Non-Isocyanate Synthesis of Aliphatic Polyurethane by BiCl3-Catalyzed Transurethanization Polycondensation. Polymers 2024, 16, 1136. Ochiai, B.; Kobayashi, Y. Non-Isocyanate Synthesis of Aliphatic Polyurethane by BiCl3-Catalyzed Transurethanization Polycondensation. Polymers 2024, 16, 1136.
Abstract
Non-isocyanate polyurethane synthesis by non-Sn catalysis is an essential challenge toward green polyurethane synthesis. Bismuth compounds are attractive candidates due to their low cost, low toxicity, and availability to urethane chemistry. We applied various Bi catalysts to the self-polycondensation of a bishydroxyurethane monomer and found BiCl3 to be an excellent catalyst through optimization. The catalytic activity and price of BiCl3 are comparable to those of Bu2SnO, while its toxicity is significantly low. BiCl3 is, therefore, a promising alternative to Sn-based catalysts in non-isocyanate polyurethane synthesis.
Keywords
polyurethane; bismuth; polycondensation; non-isocyanate
Subject
Chemistry and Materials Science, Polymers and Plastics
Copyright: This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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