Wang, C., Li, Z., Zheng, Z., Zhong, J., Xiang, J., Wang, R., Hou, B., Tan, Z., & Wang, X. (2024). Enhanced Electrochemical Performance of La0.7Pr0.3Ba0.5Sr0.5Co1.5Fe0.5O5+δ Cathodes for Solid Oxide Fuel Cells by La2NiO4 impregnation. Preprints. https://doi.org/10.20944/preprints202406.0496.v1
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Wang, C., Zanxiong Tan and Xintao Wang. 2024 "Enhanced Electrochemical Performance of La0.7Pr0.3Ba0.5Sr0.5Co1.5Fe0.5O5+δ Cathodes for Solid Oxide Fuel Cells by La2NiO4 impregnation" Preprints. https://doi.org/10.20944/preprints202406.0496.v1
Abstract
Three types of double perovskite La1-xPrxBa0.5Sr0.5Co1.5Fe0.5O5+δ(x=1,0.3,0) are prepared using the EDTA-citrate method and identified as solid oxide fuel cell (SOFC) cathodes. The microstructures, as well as electrochemical performances of La1-xPrxBa0.5Sr0.5Co1.5Fe0.5O5+δ (LPBSCF) and La2NiO4-impregnated LPBSCF (LN-LPBSCF) cathodes, are investigated in detail. An optimum impregnation amount of LN-LPBSCF (LN loading of 0.64 mg/cm2) electrode exhibits relatively lower electrode polarization resistance (Rp) and better stable performance as compared to that of pure LPBSCF electrode in symmetrical SOFCs. The maximum power density of LN-LPBSCF single cells is 800 mW/cm2 at 800 °C and demonstrates good stability for 100 h in short-term testing.
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