Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Enhanced Electrochemical Performance of La0.7Pr0.3Ba0.5Sr0.5Co1.5Fe0.5O5+δ Cathodes for Solid Oxide Fuel Cells by La2NiO4 impregnation

Version 1 : Received: 6 June 2024 / Approved: 7 June 2024 / Online: 7 June 2024 (14:36:12 CEST)

How to cite: Wang, C.; Li, Z.; Zheng, Z.; Zhong, J.; Xiang, J.; Wang, R.; Hou, B.; Tan, Z.; Wang, X. Enhanced Electrochemical Performance of La0.7Pr0.3Ba0.5Sr0.5Co1.5Fe0.5O5+δ Cathodes for Solid Oxide Fuel Cells by La2NiO4 impregnation. Preprints 2024, 2024060496. https://doi.org/10.20944/preprints202406.0496.v1 Wang, C.; Li, Z.; Zheng, Z.; Zhong, J.; Xiang, J.; Wang, R.; Hou, B.; Tan, Z.; Wang, X. Enhanced Electrochemical Performance of La0.7Pr0.3Ba0.5Sr0.5Co1.5Fe0.5O5+δ Cathodes for Solid Oxide Fuel Cells by La2NiO4 impregnation. Preprints 2024, 2024060496. https://doi.org/10.20944/preprints202406.0496.v1

Abstract

Three types of double perovskite La1-xPrxBa0.5Sr0.5Co1.5Fe0.5O5+δ(x=1,0.3,0) are prepared using the EDTA-citrate method and identified as solid oxide fuel cell (SOFC) cathodes. The microstructures, as well as electrochemical performances of La1-xPrxBa0.5Sr0.5Co1.5Fe0.5O5+δ (LPBSCF) and La2NiO4-impregnated LPBSCF (LN-LPBSCF) cathodes, are investigated in detail. An optimum impregnation amount of LN-LPBSCF (LN loading of 0.64 mg/cm2) electrode exhibits relatively lower electrode polarization resistance (Rp) and better stable performance as compared to that of pure LPBSCF electrode in symmetrical SOFCs. The maximum power density of LN-LPBSCF single cells is 800 mW/cm2 at 800 °C and demonstrates good stability for 100 h in short-term testing.

Keywords

Solid oxide fuel cell; solution impregnation technique; La1-xPrxBa0.5Sr0.5Co1.5Fe0.5O5+δ(LPBSCF)

Subject

Chemistry and Materials Science, Nanotechnology

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