Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Biochar/Biopolymer Composites for In-Situ Groundwater Remediation

Version 1 : Received: 19 June 2024 / Approved: 20 June 2024 / Online: 20 June 2024 (09:32:17 CEST)

How to cite: Petrangeli Papini, M.; Cerra, S.; Feriaud, D.; Pettiti, I.; Lorini, L.; Fratoddi, I. Biochar/Biopolymer Composites for In-Situ Groundwater Remediation. Preprints 2024, 2024061407. https://doi.org/10.20944/preprints202406.1407.v1 Petrangeli Papini, M.; Cerra, S.; Feriaud, D.; Pettiti, I.; Lorini, L.; Fratoddi, I. Biochar/Biopolymer Composites for In-Situ Groundwater Remediation. Preprints 2024, 2024061407. https://doi.org/10.20944/preprints202406.1407.v1

Abstract

(max 200 words): The contamination of groundwater is a serious concern for ecosystems and human health. In this regard, biochar represents a promising low-cost and sustainable material for in-situ groundwater remediation. Herein, biochar waste of biomass energy production process derived from pine wood gasification at 950°C was used as active carbonaceous material in combination with different biopolymers: chitosan (CS), alginate (ALG), potato starch (PST), and carboxymethylcellulose (CMC) to produce BC@biopolymer composite materials. Different concentrations of biochar (0.3–1.0 g·L-1) and biopolymers (0.2–20.0 g·L-1) were tested and blending mode was used as simple and straightforward strategy to obtain BC composites. Scanning electron microscopy (FE-SEM), UV-Visible, infrared (FT-IR) spectroscopy, specific surface area (BET method), pore volume, and pore size distribution (textural parameters), dynamic light scattering (DLS), and ζ-potential were used to investigate the composite chemical structure, stability, and to assess the interaction among counterparts. On optimized formulations, breakthrough tests and batch adsorption isotherms on trichloroethylene (TCE) as a model contaminant were performed to evaluate the capability of composites to be delivered through a porous medium determining the transport properties, (hydrodynamic dispersion retention percentage, and adsorption capacity). This biopolymer-modified biochar holds significant promise as a sustainable and effective solution to address various groundwater pollution challenges.

Keywords

colloidal biochar; biopolymers; chitosan; alginate; potato starch; carboxymethylcellulose; composite material; trichloroethylene (TCE); in-situ remediation; groundwater remediation

Subject

Environmental and Earth Sciences, Pollution

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