Version 1
: Received: 25 June 2024 / Approved: 25 June 2024 / Online: 26 June 2024 (03:02:30 CEST)
How to cite:
Słojewska, M.; Czerwiński, A.; Kaczorowski, M.; Zygadło-Monikowska, E. Shear Thickening, Star-Shaped Polymer Electrolytes for Lithium-Ion Batteries. Preprints2024, 2024061801. https://doi.org/10.20944/preprints202406.1801.v1
Słojewska, M.; Czerwiński, A.; Kaczorowski, M.; Zygadło-Monikowska, E. Shear Thickening, Star-Shaped Polymer Electrolytes for Lithium-Ion Batteries. Preprints 2024, 2024061801. https://doi.org/10.20944/preprints202406.1801.v1
Słojewska, M.; Czerwiński, A.; Kaczorowski, M.; Zygadło-Monikowska, E. Shear Thickening, Star-Shaped Polymer Electrolytes for Lithium-Ion Batteries. Preprints2024, 2024061801. https://doi.org/10.20944/preprints202406.1801.v1
APA Style
Słojewska, M., Czerwiński, A., Kaczorowski, M., & Zygadło-Monikowska, E. (2024). Shear Thickening, Star-Shaped Polymer Electrolytes for Lithium-Ion Batteries. Preprints. https://doi.org/10.20944/preprints202406.1801.v1
Chicago/Turabian Style
Słojewska, M., Marcin Kaczorowski and Ewa Zygadło-Monikowska. 2024 "Shear Thickening, Star-Shaped Polymer Electrolytes for Lithium-Ion Batteries" Preprints. https://doi.org/10.20944/preprints202406.1801.v1
Abstract
The safety concerns associated with current lithium-ion batteries are a significant drawback. A short-circuit within the battery's internal components, such as those caused by a car accident, can lead to ignition or even explosion. To address this issue, a polymer shear thickening electrolyte, free from flammable solvents, has been developed. It comprises a star-shaped oligomer derived from a trimethylolpropane (TMP) core and polyether chains, along with the inclusion of 20 wt.% nanosilica. Notably, the star-shaped oligomer serves a dual function as both the solvent for the lithium salt and the continuous phase of the shear thickening fluid. The obtained electrolytes exhibit an ionic conductivity of 10-6 S cm-1 at 20 °C and 10-4 S cm-1 at 80 °C, with a high Li+ transference number (t+ = 0.79). A nearly thirtyfold increase in viscosity to a value of 1187 Pa s at 25 °C and a critical shear rate of 2 s-1 were achieved. During impact, this electrolyte could enhance cell safety by preventing electrode short-circuiting.
Chemistry and Materials Science, Materials Science and Technology
Copyright:
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
