Preprint Article Version 1 This version is not peer-reviewed

Corrosion Resistance of TiB2 Coatings in Molten Zinc Fabricated by Electrophoretic Deposition in Molten Salts

Version 1 : Received: 26 July 2024 / Approved: 27 July 2024 / Online: 29 July 2024 (11:05:59 CEST)

How to cite: Liu, J.; Xu, J.; Ge, C.; Pang, J.; Jin, W.; Haarberg, G. M.; Xiao, S. Corrosion Resistance of TiB2 Coatings in Molten Zinc Fabricated by Electrophoretic Deposition in Molten Salts. Preprints 2024, 2024072251. https://doi.org/10.20944/preprints202407.2251.v1 Liu, J.; Xu, J.; Ge, C.; Pang, J.; Jin, W.; Haarberg, G. M.; Xiao, S. Corrosion Resistance of TiB2 Coatings in Molten Zinc Fabricated by Electrophoretic Deposition in Molten Salts. Preprints 2024, 2024072251. https://doi.org/10.20944/preprints202407.2251.v1

Abstract

Abstract:To enhance the corrosion resistance of molybdenum metal in molten zinc, this study successfully fabricated TiB2 coatings on molybdenum substrates using the molten salt electrophoretic deposition technique and investigated their corrosion resistance in molten zinc. Initially, TiB2 nanoparticles with a size ranging from 50 to 150 nm were synthesized using the borothermal reduction method in NaF-AlF3 molten salts at 1238 K. Subsequently, electrophoretic deposition experiment was conducted by applying a cell voltage of 1.2 V (corresponding to an electric field of 0.6V/cm) for 1 h in the molten salts containing TiB2 nanoparticles, resulting in a uniform, continuous, and dense TiB2 coating with a thickness of 35 μm on the molybdenum substrate. Moreover, the corrosion resistance of the TiB2 coated molybdenum metal to molten zinc was tested through continuous immersion. After 120 h of immersion, the TiB2 coating showed no signs of cracking or peeling off, successfully protecting the molybdenum metal substrate from corrosion by molten zinc. The results confirm that the molten salt electrophoretic deposition technique can be used to prepare TiB2 coatings with good resistance to molten zinc corrosion on molybdenum metal.

Keywords

Molten salt; Electrophoretic deposition; Molybdenum metal; TiB2 coating; Corrosion resistance in molten zinc

Subject

Chemistry and Materials Science, Surfaces, Coatings and Films

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