Preprint Article Version 1 This version is not peer-reviewed

New Piezoceramic SrBi2Nb2-2xWxSnxO9: Crystal Structure, Microstructure and Dielectric Properties

Version 1 : Received: 29 July 2024 / Approved: 29 July 2024 / Online: 29 July 2024 (13:50:41 CEST)

How to cite: Zubkov, S. V.; Parinov, I. A.; Nazarenko, A. V. New Piezoceramic SrBi2Nb2-2xWxSnxO9: Crystal Structure, Microstructure and Dielectric Properties. Preprints 2024, 2024072319. https://doi.org/10.20944/preprints202407.2319.v1 Zubkov, S. V.; Parinov, I. A.; Nazarenko, A. V. New Piezoceramic SrBi2Nb2-2xWxSnxO9: Crystal Structure, Microstructure and Dielectric Properties. Preprints 2024, 2024072319. https://doi.org/10.20944/preprints202407.2319.v1

Abstract

By using the method of high-temperature solid-phase reaction, the new piezoceramic SrBi2Nb2-2xWxSnxO9 was obtained, in which partial substitution of niobium (Nb) atoms with Sn4+ and W6+ atoms in the compound SrBi2Nb2O9 took place in the octahedra of the perovskite layer (B-position). X-ray diffraction studies have shown that these compounds are single-phase SrBi2Nb2-2xWxSnxO9 (x = 0.1, 0.2) and two-phase SrBi2Nb2-2xWxSnxO9 (x = 0.3, 0.4), but they all had the structure of Aurivillius – Smolensky phases (ASPs) with similar parameters of orthorhombic elementary cells, corresponding to the spatial group A21am. The dependences on temperature of the relative permittivity ε/ε0 and the tangent of the loss angle tan d at different frequencies were measured.

Keywords

Aurivillius – Smolensky phase; SrBi2Nb2-2xWxSnxO9 (x = 0.1, 0.2, 0.3, 0.4); activation energy Ea; Curie temperature TC, relative permittivity ε/ε0

Subject

Chemistry and Materials Science, Electronic, Optical and Magnetic Materials

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