Preprint Article Version 1 This version is not peer-reviewed

Kelvin Probe Force Microscopy, Current Mapping, and Optical Properties of Hybrid ZnO Nanorods /Ag Nanoparticles

Version 1 : Received: 29 July 2024 / Approved: 29 July 2024 / Online: 30 July 2024 (07:35:48 CEST)

How to cite: Musa, I. Kelvin Probe Force Microscopy, Current Mapping, and Optical Properties of Hybrid ZnO Nanorods /Ag Nanoparticles. Preprints 2024, 2024072377. https://doi.org/10.20944/preprints202407.2377.v1 Musa, I. Kelvin Probe Force Microscopy, Current Mapping, and Optical Properties of Hybrid ZnO Nanorods /Ag Nanoparticles. Preprints 2024, 2024072377. https://doi.org/10.20944/preprints202407.2377.v1

Abstract

The optical characteristics and electrical behavior of zinc oxide nanorods (ZnO-NR) and silver nanoparticles (Ag-NP) were investigated using advanced scanning probe microscopy and spectroscopy techniques. The study revealed that the ZnO nanorods have a length of about 350 nm, while the Ag nanoparticles are spherical with heights ranging from 5 to 14 nm. Measurements with Kelvin Probe Force Microscopy (KPFM) showed that the work functions of ZnO nanorods are approximately 4.55 eV, higher than that of bulk ZnO, and the work function of Ag nanoparticles ranges from 4.54 to 4.56 eV. The electrical characterization of ZnO nanorods, silver nanoparticles, and their hybrid was also conducted using conductive atomic force microscopy (C-AFM) to determine the local current-voltage (I-V) characteristics, which revealed a characteristic similar to that of a Schottky diode. The current-voltage characteristic curves of ZnO nanorods and Ag nanoparticles both show an increase in current at around 1V, and the hybrid ZnONRs/AgNP exhibits an increase in turn-on voltage at around 2.5 Volts. This suggests that the presence of Ag nanoparticles enhances the electrical properties of ZnO nanorods, improving charge carrier mobility and conduction mechanisms through a Schottky junction. The investigation also explored the optical properties of ZnO-NR, AgNP, and their hybrid, revealing absorption bands at 3.11 eV and 3.18 eV for ZnO-NR and AgNP, respectively. The hybrid material showed absorption at 3.13 eV, indicating enhanced absorption, and the presence of AgNP affected the optical properties of ZnO-NR, resulting in increased photoluminescence intensity and slightly changes in peak positions.

Keywords

KPFM; ZnO-NR; Ag- NP ; Schottky diode; Absorption; Photoluminescence

Subject

Physical Sciences, Condensed Matter Physics

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