Version 1
: Received: 1 August 2024 / Approved: 1 August 2024 / Online: 1 August 2024 (11:49:35 CEST)
How to cite:
Navarro-Laboulais, J.; Agrisuelas, J.; García-Jareño, J. J.; Vicente, F. Eis Behavior of Polyethylene+graphite Composite Considered as an Approximation to an Ensemble of Microelectrodes. Preprints2024, 2024080070. https://doi.org/10.20944/preprints202408.0070.v1
Navarro-Laboulais, J.; Agrisuelas, J.; García-Jareño, J. J.; Vicente, F. Eis Behavior of Polyethylene+graphite Composite Considered as an Approximation to an Ensemble of Microelectrodes. Preprints 2024, 2024080070. https://doi.org/10.20944/preprints202408.0070.v1
Navarro-Laboulais, J.; Agrisuelas, J.; García-Jareño, J. J.; Vicente, F. Eis Behavior of Polyethylene+graphite Composite Considered as an Approximation to an Ensemble of Microelectrodes. Preprints2024, 2024080070. https://doi.org/10.20944/preprints202408.0070.v1
APA Style
Navarro-Laboulais, J., Agrisuelas, J., García-Jareño, J. J., & Vicente, F. (2024). Eis Behavior of Polyethylene+graphite Composite Considered as an Approximation to an Ensemble of Microelectrodes. Preprints. https://doi.org/10.20944/preprints202408.0070.v1
Chicago/Turabian Style
Navarro-Laboulais, J., José Juan García-Jareño and Francisco Vicente. 2024 "Eis Behavior of Polyethylene+graphite Composite Considered as an Approximation to an Ensemble of Microelectrodes" Preprints. https://doi.org/10.20944/preprints202408.0070.v1
Abstract
The electrical percolation of alternating current through two-phase polyethylene/graphite composite electrodes with different contents of graphite microparticles immersed in aqueous KCl solutions has been studied. Above the graphite content of the first percolation threshold, the electrochemical impedance response of this electrode is associated with an equivalent circuit of resistance Ru in series with a constant phase element CPE. An insulator material+conductive filler model is proposed in which the electroactive surface is considered as the intersection of the percolation cluster through the solid and the cluster associated with the interfacial region. CPE is analyzed assuming a distribution of micro-capacitors of the graphite particles in contact with the dielectric solution and inside the dielectric polymeric phase.
Chemistry and Materials Science, Ceramics and Composites
Copyright:
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
