Preprint Short Note Version 1 This version is not peer-reviewed

2-(2,6-Diisopropylphenyl)-1-methylimidazo[1,5-a]quinolin-2-ium tetrafluoroborate

Version 1 : Received: 2 August 2024 / Approved: 5 August 2024 / Online: 6 August 2024 (03:30:39 CEST)

How to cite: Borislavov, L.; Koleva, I. Z.; Lozanova, V.; Ivanova, M.; Lyapchev, R. 2-(2,6-Diisopropylphenyl)-1-methylimidazo[1,5-a]quinolin-2-ium tetrafluoroborate. Preprints 2024, 2024080304. https://doi.org/10.20944/preprints202408.0304.v1 Borislavov, L.; Koleva, I. Z.; Lozanova, V.; Ivanova, M.; Lyapchev, R. 2-(2,6-Diisopropylphenyl)-1-methylimidazo[1,5-a]quinolin-2-ium tetrafluoroborate. Preprints 2024, 2024080304. https://doi.org/10.20944/preprints202408.0304.v1

Abstract

A new heterocyclic compound, 2-(2,6-diisopropylphenyl)-1-methylimidazo[1,5-a]quinolin-2-ium tetrafluoroborate 1 was obtained from its precursor, N-(2,6-diisopropylphenyl)-N-(quinolin-2-ylmethyl)acetamide 2, by POCl3-mediated cyclization. For the first time – the tertiary acetamide 2, precursor of 1, was synthesized by using commercially available starting materials. The structure of 1 was unquestionably confirmed by 1H-, 13C-, 2D-NMR-, IR- spectroscopy and mass-spectrometry. Its optical properties were also studied.

Keywords

heterocyclic compounds; imidazolium salts; abnormal N-heterocyclic carbenes; cationic heterocycles

Subject

Chemistry and Materials Science, Organic Chemistry

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