Preprint Review Version 1 This version is not peer-reviewed

TiO2 for Photocatalysis and Energy Conversion: A Detailed Overview of the Synthesis, Applications, Challenges, Advances and Prospects for Sustainable Development

Version 1 : Received: 22 August 2024 / Approved: 23 August 2024 / Online: 26 August 2024 (10:57:18 CEST)

How to cite: Nematov, D.; Ashurov, A.; Umarzoda, M. TiO2 for Photocatalysis and Energy Conversion: A Detailed Overview of the Synthesis, Applications, Challenges, Advances and Prospects for Sustainable Development. Preprints 2024, 2024081733. https://doi.org/10.20944/preprints202408.1733.v1 Nematov, D.; Ashurov, A.; Umarzoda, M. TiO2 for Photocatalysis and Energy Conversion: A Detailed Overview of the Synthesis, Applications, Challenges, Advances and Prospects for Sustainable Development. Preprints 2024, 2024081733. https://doi.org/10.20944/preprints202408.1733.v1

Abstract

The term ‘photocatalysis’ has recently gained high popularity, and various products using photocatalytic functions have been commercialized. Of all the materials that may be used as photocatalysts, TiO2 is virtually the only one that is now and most likely will remain appropriate for industrial application. Water and air purification systems, sterilization, hydrogen evolution, self-cleaning surfaces, and photoelectrochemical conversion are just a few of the products and applications in the environmental and energy domains that make extensive use of TiO2 photocatalysis. This is due to the fact that TiO2 has the lowest cost, most stability, and most effective photoactivity. Furthermore, history attests to its safety for both people and the environment because it has been used as a white pigment since antiquity. This review discusses some important aspects and issues concerning different synthesis methods and their influence on the structure and properties of TiO2, as well as the concept of photocatalysis based on it as a promising biocompatible functional material that has been widely used in recent years. The advantages of TiO2 applications in various fields of science and technology are discussed, including environmental protection, photocatalysis including self-cleaning surfaces, water and air purification systems, hydrogen liberation, photovoltaic energy, cancer diagnosis and therapy, coatings and dental products, etc. Information on the structure and properties of TiO2 phases, as well as modern methods of synthesis of functional materials based on them are presented. This is followed by a detailed review of the basic principles of TiO2 photocatalysis with a brief introduction to the modern concept of TiO2 photocatalysis. Finally, the challenges and prospects of TiO2 photocatalysis for various applications are briefly discussed. Recent advances in the fundamental understanding of TiO2 photocatalysis at the atomic-molecular level are highlighted, and important recent advances in TiO2 photocatalysis are summarized in terms of the design and engineering of new materials.

Keywords

titanium dioxide; thin films; catalytic reactions; photocatalysis; photocatalyst; surface interaction; nanomaterials; water purification; sustainable development

Subject

Physical Sciences, Condensed Matter Physics

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