Preprint Article Version 1 This version is not peer-reviewed

Novel Acid-Assisted Polymerization Technique for Synthesis of Polyaniline Films at Room Temperature: Morphological Study and Supercapacitor Applications

Version 1 : Received: 24 September 2024 / Approved: 24 September 2024 / Online: 25 September 2024 (04:38:03 CEST)

How to cite: Boahene, S.; Potocký, Š.; Dragounová, K. A.; Tomšík, E.; Kromka, A. Novel Acid-Assisted Polymerization Technique for Synthesis of Polyaniline Films at Room Temperature: Morphological Study and Supercapacitor Applications. Preprints 2024, 2024091903. https://doi.org/10.20944/preprints202409.1903.v1 Boahene, S.; Potocký, Š.; Dragounová, K. A.; Tomšík, E.; Kromka, A. Novel Acid-Assisted Polymerization Technique for Synthesis of Polyaniline Films at Room Temperature: Morphological Study and Supercapacitor Applications. Preprints 2024, 2024091903. https://doi.org/10.20944/preprints202409.1903.v1

Abstract

This study presents polyaniline (PANI) synthesis and characterization using a novel acid-assisted polymerization technique. Two PANI suspensions with different ammonium peroxydisulfate (APS) concentrations were synthesized at room temperature, i.e. the ratio of aniline to APS was 10:1 for PANI1 and 5:1 for PANI2. SEM measurements revealed distinct structures: a porous nanofibrillar structure for PANI1 and a densely packed structure for PANI2. The electrochemical performance of the fabricated PANI/glassy carbon (GC) electrodes was evaluated using a three-electrode cell configuration in the scan rates of 10 mV/s and 30 mV/s. The PANI1/GC heterostructure exhibited a specific capacitance of 160 F/g, while this value increased to 407 for the PANI2/GC. This research contributes not only to the understanding of PANI synthesis at room temperature but also to its potential applications in electrochemical energy storage devices.

Keywords

polyaniline (PANI); acid-assisted polymerization; glassy carbon (GC); electrochemistry

Subject

Chemistry and Materials Science, Electrochemistry

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