Version 1
: Received: 2 September 2024 / Approved: 2 October 2024 / Online: 2 October 2024 (15:17:04 CEST)
How to cite:
Zhakina, A. K.; Vassilets, Y. P.; Arnt, O. V.; Zhakin, A. M. Synthesis and Study of Sorption Properties of Zinc-Imprinted Polymer. Preprints2024, 2024100197. https://doi.org/10.20944/preprints202410.0197.v1
Zhakina, A. K.; Vassilets, Y. P.; Arnt, O. V.; Zhakin, A. M. Synthesis and Study of Sorption Properties of Zinc-Imprinted Polymer. Preprints 2024, 2024100197. https://doi.org/10.20944/preprints202410.0197.v1
Zhakina, A. K.; Vassilets, Y. P.; Arnt, O. V.; Zhakin, A. M. Synthesis and Study of Sorption Properties of Zinc-Imprinted Polymer. Preprints2024, 2024100197. https://doi.org/10.20944/preprints202410.0197.v1
APA Style
Zhakina, A. K., Vassilets, Y. P., Arnt, O. V., & Zhakin, A. M. (2024). Synthesis and Study of Sorption Properties of Zinc-Imprinted Polymer. Preprints. https://doi.org/10.20944/preprints202410.0197.v1
Chicago/Turabian Style
Zhakina, A. K., Oxana Vasilievna Arnt and Almat Maulenuly Zhakin. 2024 "Synthesis and Study of Sorption Properties of Zinc-Imprinted Polymer" Preprints. https://doi.org/10.20944/preprints202410.0197.v1
Abstract
Imprinted polymers with imprints of Zn2+ ions (ZnIP) and reference polymers without imprints (NIP) were synthesized based on humic and methacrylic acids. Comparative studies of the physical parameters of ZnIP and NIP were carried out using elemental analysis, IR spectroscopy and electron microscopy. Kinetic parameters of Zn2+ ion sorption on ZnIP and NIP were determined. It was found that the sorption kinetics on both ZnIP and NIP are approximated by a pseudo-first-order equation. The sorption rate constant for ZnIP is higher than that of NIP, indicating a higher adsorption rate of Zn2+ ions onto the surface of ZnIP. This may be due to more accessible sites on ZnIP. Adsorption of Zn2+ ions is best described by the Langmuir model, indicating monolayer adsorption on a homogeneous surface. The Langmuir model also shows that ZnIP is effective at low adsorbate concentrations. The Freundlich model describes the adsorption with less accuracy, which may indicate monolayer adsorption and less surface homogeneity. ZnIP shows better adsorption capacity and higher efficiency compared to NIP and can be proposed as a selective sorption material for Zn2+ ions.
Chemistry and Materials Science, Applied Chemistry
Copyright:
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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