Preprint Article Version 1 This version is not peer-reviewed

Use of Chitosan and Chitosan-Magnetite Spheres for Arsenic Groundwater Removal. Factorial Designs as Tools to Calculate the Efficiency of Removal

Version 1 : Received: 2 October 2024 / Approved: 3 October 2024 / Online: 3 October 2024 (14:53:22 CEST)

How to cite: Hernandez Trespalacios, M. A.; Mangiameli, M. F.; González, J. C.; Gribaudo, L.; Frascaroli, M. I. Use of Chitosan and Chitosan-Magnetite Spheres for Arsenic Groundwater Removal. Factorial Designs as Tools to Calculate the Efficiency of Removal. Preprints 2024, 2024100279. https://doi.org/10.20944/preprints202410.0279.v1 Hernandez Trespalacios, M. A.; Mangiameli, M. F.; González, J. C.; Gribaudo, L.; Frascaroli, M. I. Use of Chitosan and Chitosan-Magnetite Spheres for Arsenic Groundwater Removal. Factorial Designs as Tools to Calculate the Efficiency of Removal. Preprints 2024, 2024100279. https://doi.org/10.20944/preprints202410.0279.v1

Abstract

The lack of access to drinking water is a problem that affects many towns in the Province of Santa Fe. Many people affected by this situation use groundwater for consumption, cooking, and irrigation. In this work, a colorimetric analytical technique is used to quantify arsenic. It is sufficiently sensitive, simple, and economical to apply to the towns of interest. This work synthesized a hybrid sorbent in the form of magnetite-chitosan spheres (M-Q). The sorption capacity of this new sorbent for As removal was 270% greater than that of chitosan spheres (Q), which was 30%. Another advantage of this hybrid sorbent is the capability of being sep-arated by its magnetic properties. The work was done with groundwater (Andino, Province of Santa Fe) with high conductivity (12.1 µS/cm), hardness (1125 mg/L CaCO3), and an As(V) concentration of 265 µg/L. The removal capacity from groundwater was optimized using a composite factorial design, and for the conditions of mass 0.49 g, pH 5.24, and contact time of 81.23 min, it was found to be 81%.

Keywords

groundwater- hardness; magnetite; response surface factorial designs; Quantification of total arsenic-silver diethyldithiocarbamate method; Arsenic

Subject

Chemistry and Materials Science, Biomaterials

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