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04 November 2024

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05 November 2024

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Abstract
For many years, high-power laser technology has been divided between industrial applications, which prioritize higher average powers and repetition rates, and academic research, which focuses on achieving higher peak powers and ultrashort pulse durations. The introduction of Yb-doped crystals in laser technology has paved the way for a new generation of laser sources that bridge the gap between industrial and academic requirements, combining high average power with ultrashort pulse capabilities. These advancements enable the integration of compact, adaptable front-end stages, making such lasers versatile for scientific applications. In Lisbon, the Laboratory of Intense Lasers leverages this technology with a system that combines commercial and custom-built front-end stages to enhance operational flexibility. In this paper, we present the current status of this facility and outline upcoming upgrades. We also showcase applications enabled by these high-power laser sources, including semiconductor studies, nitrogen-vacancy generation, bi-photonics, and time-resolved spectroscopy.
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1. Introduction

Ultrafast, high-power lasers have transformed modern science, enabling groundbreaking research across a wide range of disciplines, from physics and chemistry to biology and materials engineering. The progress in this field has been largely driven by the development of Chirped Pulse Amplification (CPA) [1], a concept that allows for the amplification of femtosecond pulses to high energies without damaging the amplification medium and that has become cornerstone technology in ultrafast laser systems. Building on CPA technology, further advancements were achieved with Optical Parametric Chirped Pulse Amplification (OPCPA) [2,3,4,5], which combines the pulse stretching of CPA with optical parametric amplification, allowing for tunable output across a range of wavelengths as well as better control over pulse duration. With OPCPA, researchers can access wavelengths beyond the traditional gain bandwidth of laser crystals, expanding the scope of ultrafast experiments to previously inaccessible spectral regions. Thanks to these advancements, many modern laser facilities now house a diverse array of laser systems with the capability to deliver high peak powers, broad wavelength tunability, and femtosecond to attosecond pulses. This versatility supports a wide range of cutting-edge experiments in nonlinear optics, strong-field physics, particle acceleration, and materials processing. The availability of ultrashort, high intensity pulses has opened up new experimental regimes, allowing scientists to explore phenomena such as high-harmonic generation, relativistic electron dynamics, and laser-driven particle acceleration [5]. A recent trend within these facilities is the adoption of industrial-grade, diode-pumped Yb-lasers. Yb-based lasers, with their high efficiency, stability, and scalability, are an ideal choice for research requiring high average power with excellent beam quality. Traditionally used in industrial settings, high power, high repetition rate Yb-lasers are being increasingly introduced into laboratory environments, where they are increasingly paired with CPA and OPCPA stages to enhance both energy and versatility. This integration represents a shift towards what has been termed the "third generation" of femtosecond laser technology [6], characterized by the marriage of industrial reliability with the ultrashort-pulse capability required for scientific applications. The Laboratory of Intense Lasers (L2I) is a laser facility located in Instituto Superior Técnico, University of Lisbon. Operating since 1998, it has been devoted to the development of high-intensity lasers, ultrashort diagnostics, and high-intensity interactions such as particle acceleration, high-harmonic generation, and advanced radiation sources[7].
L2I has undergone a series of major upgrades over the past few years, envisioning high repetition-rate operation, including a new 100 W, 100 kHz, 1 ps industrial scale Yb:YAG laser. This short durations (and consequently higher peak powers) allow for the assembly of relatively compact nonlinear stages, while the high energies help compensate for the inherent low conversion efficiencies of the nonlinear processes.
This laser drives a multipass-cell (MPC) compressor to generate sub ∼100 fs 1030 nm pulses and a state-of-the-art OPCPA operating at 3000 nm. Collectively, these systems enable a range of parameters applicable to a plethora of scientific disciplines deriving from a single laser source.
In this paper, we report how a single laser source can drive the current capabilities of the L2I as a high-power, ultrashort laser facility. We start with a description of our laser source and the current nonlinear stages utilized to adapt/improve its parameters, together with the incoming upgrades to these systems further expanding the parameter range. Finally, we present some of our early experimental results.

2. Laser System Setup

The setup of the current L2I laser system, together with planned upgrades currently under development (dashed boxes) is shown in Figure 1.

2.1. Main Driving Laser

The full system is driven by a high average power, high repetition rate, diode-pumped Yb:YAG InnoSlab amplifier (AMPHOS, A2000) delivering 1 ps, 1 mJ pulses centred at 1030 nm and an adjustable repetition rate between 0.1-40 MHz. At the standard repetition rate of 100 kHz the average output power is 100 W. The spectrum and Frequency Resolved Optical Gating (FROG) trace of this system can be seen in Figure 2 and Figure 3, respectively.
At the output of this laser, a polarizer (PL1) and a half-wave plate split the beam in two. The primary output (about 75% of the energy) is used to seed a mid-infrared OPCPA, with the remaining fraction being reserved for other applications such as pulse compression or further amplification at 1 μ m.

2.2. Mid-Infrared OPCPA

The mid-infrared OPCPA (Starzz, FASTLITE) is optimized to match the output of the pump system, generating 40 fs, 65 μ J, carrier-envelope phase (CEP) stable pulses centred at 3000 nm and at the pump repetition rate of 100 kHz. The amplifier is a virtually passive device, with the only active components (excluding diagnostics) being a pair of motorized mirrors for pointing correction of the input, and an ultrafast acousto-optic programmable dispersive filter (Dazzler, Fastlite) for CEP control. The architecture of this system is mostly similar to that of Ref [8]. The output spectrum and FROG trace of this system can be seen in Figure 4 and Figure 5, respectively. The FWHM spectral bandwidth is 16.1 THz, with a corresponding time-bandwidth product of 0.63.
The operating parameters of the OPCPA system make it one of a selected few at a worldwide level capable of addressing challenging applications ranging from strong-field physics and attosecond science to pollutant tagging and cancer diagnostics[9,10].

2.3. Multipass Pulse Compression

Multipass pulse compression [11,12,13] has become increasingly important in ultrafast laser systems thanks to its ability to generate high-energy, ultrashort laser pulses with high precision. This technique involves multiple passes of a laser pulse through a nonlinear medium (gas or solid) with dispersion compensation, allowing it to compress the pulse duration progressively without compromising its energy, making it a key enabler for multiple applications. Recent advances in optical materials, dispersion control, and nonlinear compression techniques have significantly improved the efficiency and reliability of multipass pulse compression, allowing for more compact and robust laser systems[11,12,13]. Our MPC [14] was developed through a partnership with n2-Photonics and a similar model is now commercially available. The system consists of a Herrioty cell composed of two parallel concave mirrors placed inside a gas chamber filled with pressurized noble gas (currently krypton at 3 bar). Pulses are injected into the cell and undergo multple reflections between the mirrors. As they pass through the focal region, the high intensities lead to self-phase modulation (SPM) and spectral broadening. The output pulses are compressed by a pair of chirped mirrors. The MPC system can be used with an input energy up to 0.75 mJ, in which case the 1 ps pulses are compressed to below 100 fs with an efficiency of 85% while preserving or even improving the spatial profile quality. The highest compression ratio obtained with this system can be seen in Figure 6.
As the broadening is driven by SPM, the compression ratio can be adjusted by the input power of the laser. Since many applications require attenuation of the output, the interplay between input power and attenuation allow running experiments at the same energy/power levels while scanning the effects of pulse duration. This system is also fully passive and the gas chamber is able to keep the high pressure for several months without any gas intake. The output of the MPC drives several user experiments taking advantage of the higher peak powers, shorter temporal resolution, and broader spectrum, as described in Section 3.1.

2.4. Millijoule OPCPA Stage

Many experiments benefit from higher pulse energies in the mJ-range, including strong-field ionization and high-harmonic generation, molecular spectroscopy and dynamics and plasma physics. For these goals, we have designed an additional ultra-broadband OPCPA, envisaging >mJ-level, sub-50 fs pulses in the 3 µm region. The design relies on amplifying the secondary output of the A2000 in a home-built chirped pulse amplifier (Figure 1) to act as a pump, and stretching the output to the mid-infrared system for the signal. The output beam from the A2000 is redirected to this system by flipping an adjustable mirror mount (FM1). To reduce the damage threshold requirements and prevent depopulation of the gain medium in the CPA, at this stage the repetition rate of the pulse train is lowered to 10 Hz with a pulse-picker, consisting of a Pockels cell (PC), synchronized with the A2000 internal trigger, mounted between two crossed polarizers (PL2 and PL3). A Faraday rotator (FR) further prevents any back reflection into the driving laser. The beam is sent to a compact stretcher consisting of 33 mm long, 5×8 mm aperture, 26 ps/nm chirped volume Bragg grating (CVBG) (Optigrate) that increases the pulse duration from 1 ps to 240 ps. The stretched pulse is sent into a diode-pumped multipass amplifier (see Refs. [7,15,16] for details). The pulse passes 10 times through an 8 mm thick Yb:YAG crystal pumped by a 4 kW laser diode stack operating at 940 nm (Jenoptik). The pump radiation goes through a dichroic mirror (DM1) next to the gain crystal that is transmissive for the 940 nm pump but highly reflective at 1030 nm. This amplifier has been demonstrated to reach 100 mJ per pulse with ∼140 ps pulse duration. Compression will be performed with a compact Treacy compressor composed of two parallel diffraction gratings (G1 and G2), with an expected output of 75 mJ, 6 ps pulses at 10 Hz. Since the pump and signal pulses will be synchronised optically, minimizing the optical path of this system is crucial to avoid the need for long delay lines. With this upgrade, we aim to have two operational systems operating at 1030 nm: a moderate energy, high repetition rate for low-cross section interactions and a high energy, low repetition rate for low-efficiency phenomena.
The in-house built, mid-infrared OPCPA system is designed to operate at 3000 nm [17,18]. The repetition rate of the Fastlite system will be matched to the 10 Hz of the pump by first internally reducing the repetition rate to 1 kHz followed by an ultrafast shutter/chopper (US). The 40 fs pulses will be stretched up to 2 ps in a silicon slab. This corresponds to one-third of the pump pulse duration to ensure amplification without bandwidth narrowing. The OPCPA is composed of three amplification stages, the first two based on MgO:LN in a noncollinear configuration, ensuring broadband amplification, and the third one a collinear stage based on KTA crystal to achieve higher gain. The pump is split (BS1,BS2) for the three stages in a ratio 4 mJ / 16 mJ / 40 mJ, with independent delay lines to allow synchronization. The collinearity of the KTA stage is enpected OPCPA efficiency of 8 % , the amplifier is designed to reach the 3 mJ level. This system was designed to use only 60 out of the 75 mJ available for pumping, to account for any unexpected losses or underperformance of the previous systems, leaving also the possibility of further amplification with a fourth stage. Finally, the amplified pulses are sent to a bulk sapphire compressor resulting in a 5 mJ, 85 fs output. The Fourier limit is close to the original 40 fs of the Starzz system, however simulations with a simple bulk compressor demonstrate some uncompensated third order dispersion. This could be corrected with a prism pair compressor or an acousto-optic modulator, however, at the cost of energy.

2.5. YCOB-Based NOPA

The last laser source is a noncollinear optical parametric amplifier (NOPA) based on the nonlinear crystal yttrium calcium oxyborate (YCOB) and operating around 850 nm. This source builds on a previously demonstrated NOPA capable of generating microjoule level broadband (spanning from 750 to 950 nm) short pulses [19,20,21]. The output of the MPC stage is used as the pump for this amplifier with the goal of generating high-intensity broadband laser pulses (Figure 7). The 1030 nm pulse train is split into two beamlines at a thin film polariser (TFP). The signal beam line is focused on a sapphire plate for generating supercontinuum, to be used as the signal. The pump beamline is sent through a BBO crystal for second-harmonic generation and separated from the fundamental in a dichroic mirror (DM). Both beams are sent into the NOPA consisting of a 7.5 mm thick YCOB crystal, with an auxiliary delay stage for temporal synchronization. Due to the shorter output pulse duration enabled by the MPC, a broad supercontinuum is generated, motivating the choice of a NOPA geometry. It is also important to note that YCOB is a biaxial crystal and that the phase matching and noncollinear angles were thoroughly modelled and chosen outside the principal planes to enable maximum broadband capability[19,20,22]. The output spectrum is capable of supporting a compressed pulse duration of 30 fs. Finally, pulse compression will be performed via a prism pair compressor and/or a grating Treacy compressor, assisted by chirped mirrors if required.
Figure 7. Schematic of YCOB-based NOPA.
Figure 7. Schematic of YCOB-based NOPA.
Preprints 138483 g007
Table 1 summarises the laser systems at L2I, both operational and under development.

3. Applications

In this section, we summarise some of the applications demonstrated with the current capabilities of L2I.

3.1. Near-infrared studies

The following experiments were driven at 1030 nm by the output of the MPC. The advantages of using this system with regard to the A2000 include the larger spectral bandwidth, shorter durations and higher peak powers.

3.1.1. Material Study and Characterization

In solids, the process of harmonic generation has a contribution from the bulk medium and another from the entry and exit surfaces. Typically, the contribution from the medium is many times larger than that of the surfaces due to the greater interaction length. However, in centrosymmetric media (i.e. media possessing inversion symmetry) even order processes are only possible at the surfaces, where the symmetry is broken in the normal axis[23,24,25]. This research line (Figure 8) aims to characterize the ultrafast laser light response of several material surfaces using the spectrum of the emitted radiation in a reflective configuration. The pulse duration is controlled by adjusting the power input into the MPC. A half-wave plate and polarizing beamsplitter cube (BSC1) are used to select the desired energy. The position of lens L1 adjusts the beam spot size on the sample, which is measured using a CMOS sensor at the same distance from the lens as the sample. After interaction, the beam is re-collimated by lens L2. The polarization of the incident beam is set by a second λ / 2 , and the sample holder allows for the precise rotation of the sample along its surface normal. The P and S components of the polarization are separated using another polarizing beamsplitter cube (BSC2) and measured individually, selected with a flip mirror (FM2). The detection system consists of an infrared filter (F1), a monochromator (MC), and a photomultiplier tube (PMT). The control of the monochromator and the measurements with the PMT were automated using an Arduino, which is managed via custom computer software. The system was benchmarked with a Si(111) sample, and both second and third harmonic generation was observed (Figure 9), where we confirm a scaling factor of 2 and 3 , respectively. We also observed the spectral broadening of the harmonics.

3.1.2. Time-Resolved Infrared Spectroscopy

Time-resolved infrared (TRIR) spectroscopy, a type of ultrafast transient absorption spectroscopy, utilizes a pump-probe geometry to explore molecular dynamics. In this technique, a pump pulse excites a fraction of the molecules in the sample, while the temporal evolution of this excited state is monitored using an infrared probe pulse delayed with respect to the pump. To prevent unwanted multiphoton or multistep processes, the probe pulse is kept at a relatively low intensity.
Our goal is to establish and benchmark a TRIR spectroscopy workstation at the L2I. As a proof of principle, initial tests are being conducted using rhodamine 6G, with the 1030 nm laser from the MPC serving as the pump and its second harmonic at 515 nm, generated in a BBO crystal, as the probe (Figure 10). The advantage of using the MPC output is the shorter pulse durations, contributing to a higher temporal resolution of the system.

3.2. Mid-Infrared Studies

The 3 µm output from the mid-infrared OPCPA opens the doors to the study of new phenomena that cannot be observed in the near-infrared. Below we provide a few examples of experiments that have been conducted using this system.

3.2.1. Visible Spectral Wings by Supercontinuum Generation

Most materials demonstrate normal dispersion in the visible and near-infrared, but anomalous dispersion for longer wavelengths. During spectral broadening, self-phase modulation combined with anomalous dispersion can lead to self-compression, potentiating larger spectra than those generated in normal dispersion[26].
We used the 3000 nm pulses to drive supercontinuum generation that included isolated spectral wings in the visible and near infrared range[27]. Figure 11 shows a selection of these wings. This phenomenon associated with the anomalous dispersion regime was also reported in Refs. [28,29,30].

3.2.2. Harmonic Generation in Solids

Generation of harmonics in solids in the mid-infrared is of particular importance, as driving harmonics at higher wavelengths imposes lower damage thresholds as well as higher absorption of the high energy harmonics[31,32]. In fact, the first observation of high harmonics in bulk was done with a 3.25 μ m laser[31].
Figure 12 and Figure 13 shows a selection of harmonics generated in proof of principle experiments using standard samples[27]. Figure 12 shows the observed harmonics in a 1 mm thick sample of calcium fluoride, where we reached up to the ninth order. In thicker samples we observed the existence of spectral fringes (Figure 13), which are related to the generation of two second harmonic components propagating at different group velocities due to phase mismatch[33,34]. The experimental fringe spacing Δ λ is in good agreement with the theoretical values given by [35,36]
Δ λ t h e o = λ H 2 d n g ( λ 0 ) n g ( λ H ) ,
where λ 0 = 3 μ m is the central wavelength of the fundamental, λ H = the central wavelength of the harmonic, d is the sample’s thickness, and n g ( λ ) = n ( λ ) λ d n ( λ ) d λ is the group index of the sample for the wavelength λ . The refractive index of the medium, n ( λ ) , was obtained from the Sellmeier equations[37].
A more in-depth set of experiments were performed with thin samples of β -gallium oxide with different dopping levels. These generated both odd and even harmonics up to the ninth order, and we also observed fringe generation as well as high anisotropic polarization response. These results were integrated in a collaborative work which used multiple lasers sources to study this material[36].

4. Discussion

The experiments presented in the previous section showcase the feasibility of exploring several scientifics fields driven by a single laser source. Currently, we are in the process of preparing and acquiring further samples for more detailed studies, as well as developing additional experimental stations for further applications.
In conclusion, we have described the current and planned capabilities of L2I, with special attention to the potential of combining new generation laser sources with nonlinear stages for the development of a multidisciplinary laser facility. The diversity of pulse parameters enables performing experiments in a variety of scientific areas covering a broad range of wavelengths, energies and pulse durations.

Author Contributions

Conceptualization, H.P. and G.F.; formal analysis and investigation, G.V., J.A., V.H., C.P.J., J.M., D.C., H.G, C.P., P.P. and H.P.; writing—original draft preparation, G.V.; writing—review and editing, G.V., H.P. and G.F.; visualization, G.V., J.A., V.H., C.P.J, J.M., D.C., H.G, C.P., P.P. and M.S.; supervision, H.P. and G.F.; project administration, H.P. and G.F.; funding acquisition, H.P. and G.F. All authors have read and agreed to the published version of the manuscript.

Funding

IPFN activities were supported by FCT - Fundação para a Ciência e Tecnologia, I.P. by project reference UIDB/50010/2020 and DOI identifier 10.54499/UIDB/50010/2020 (https://doi.org/10.54499/UIDB/50010/2020), by project reference UIDP/50010/2020 and DOI identifier DOI 10.54499/UIDP/50010/2020 (https://doi.org/10.54499/UIDP/50010/2020) and by project reference LA/P/0061/202 and DOI 10.54499/LA/P/0061/2020 (https://doi.org/10.54499/LA/P/0061/2020). This work has received funding from Fundação para a Ciência e Tecnologia under grant Laserlab Portugal (National Roadmap of Research Infrastructures, PINFRA/22124/2016); European Union’s Horizon 2020 research and innovation programme under grant agreement no. 871124 Laserlab-Europe. This work was carried out in the framework of the Advanced Programin Plasma Scienceand Engineering (sponsored by Fundação para a Ciência e Tecnologia under grant No.UI/BD/153733/2022).

Conflicts of Interest

The authors declare no conflicts of interest.

Abbreviations

The following abbreviations are used in this manuscript:
CPA Chirped Pulse Amplifier
FROG Frequency Resolved Optical Gating
L2I Laboratory of Intense Lasers
MPC Multipass Cell
NOPA Noncolinear Optical Parametric Amplifier
OPCPA Optical Parametric Chirped Pulse Amplifier
SPM Self-phase Modulatioon
TRIR Time-Resolved Infrared
YCOB Yttrium calcium oxyborate

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Figure 1. Schematic of the laser capabilities at the L2I facility. The CPA, NOPA, and 5 mJ OPCPA systems are currently under development. The current progress of the NOPA system can be seen in Figure 7. λ / 2 : half-wave plates; λ / 4 : quarter-wave plates; PL1-4: polarizers; FM1-2: flip mirrors; BS1-2: beam splitters; DM1-2: dichroic mirrors; PC: Pockel Cell; FR: Faraday rotator; CVBG: chirped volume Bragg grating; G1-2 diffraction gratings; US- ultrafast shutter.
Figure 1. Schematic of the laser capabilities at the L2I facility. The CPA, NOPA, and 5 mJ OPCPA systems are currently under development. The current progress of the NOPA system can be seen in Figure 7. λ / 2 : half-wave plates; λ / 4 : quarter-wave plates; PL1-4: polarizers; FM1-2: flip mirrors; BS1-2: beam splitters; DM1-2: dichroic mirrors; PC: Pockel Cell; FR: Faraday rotator; CVBG: chirped volume Bragg grating; G1-2 diffraction gratings; US- ultrafast shutter.
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Figure 2. Output spectrum of the A2000 systeam.
Figure 2. Output spectrum of the A2000 systeam.
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Figure 3. FROG measurement of the shortest possible pulses generated by the A2000 system.
Figure 3. FROG measurement of the shortest possible pulses generated by the A2000 system.
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Figure 4. Output spectrum of the mid-IR OPCPA.
Figure 4. Output spectrum of the mid-IR OPCPA.
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Figure 5. FROG measurement of the pulses generated by the mid-IR OPCPA system.
Figure 5. FROG measurement of the pulses generated by the mid-IR OPCPA system.
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Figure 6. a) Input (dark green area) and output (light green area) pulse spectrum for 1 mJ input energy using 3 bars of krypton inside the MPC. The red line shows the corresponding simulation. b) Input (red line) and output (green area) pulse profile, together with Gaussian fit (green line). The FWHM pulse duration is 89 fs with a Fourier-transform limit of 82 fs. From Ref. [14].
Figure 6. a) Input (dark green area) and output (light green area) pulse spectrum for 1 mJ input energy using 3 bars of krypton inside the MPC. The red line shows the corresponding simulation. b) Input (red line) and output (green area) pulse profile, together with Gaussian fit (green line). The FWHM pulse duration is 89 fs with a Fourier-transform limit of 82 fs. From Ref. [14].
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Figure 8. Experimental setup for the characterization of the surface nonlinear response of materials.
Figure 8. Experimental setup for the characterization of the surface nonlinear response of materials.
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Figure 9. Spectrum of the (a) third harmonic with a peak at 344 nm, and (b) second harmonic with a peak at 514 nm. Power scaling for (c) the second harmonic, and (d) the third harmonic.
Figure 9. Spectrum of the (a) third harmonic with a peak at 344 nm, and (b) second harmonic with a peak at 514 nm. Power scaling for (c) the second harmonic, and (d) the third harmonic.
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Figure 10. Schematic of the experimental setup for transient absorption spectroscopy. The setup utilizes a pump-probe geometry, with the time delay controlled via a translation stage. Detection is carried out by measuring both the probe pulse and a reference pulse which are separated in a wedge.
Figure 10. Schematic of the experimental setup for transient absorption spectroscopy. The setup utilizes a pump-probe geometry, with the time delay controlled via a translation stage. Detection is carried out by measuring both the probe pulse and a reference pulse which are separated in a wedge.
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Figure 11. Visible spectral wing of supercontinuum generated in a) in a 3 mm calcium fluoride and b) YAG windows with the respective length in the legend. From Ref [27].
Figure 11. Visible spectral wing of supercontinuum generated in a) in a 3 mm calcium fluoride and b) YAG windows with the respective length in the legend. From Ref [27].
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Figure 12. Smoothed spectra of all harmonics obtained with a calcium fluoride sample of 1 mm. Spectra expressed in count rate of the spectrometer. From Ref. [27].
Figure 12. Smoothed spectra of all harmonics obtained with a calcium fluoride sample of 1 mm. Spectra expressed in count rate of the spectrometer. From Ref. [27].
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Figure 13. Smoothed spectra of the third harmonic with spectral fringes, obtained by propagation in a C-cut sapphire sample of 2 mm. Δ λ was calculated for the raw data and a smoothed/filtered version to reduce the effect of noise. From Ref. [27].
Figure 13. Smoothed spectra of the third harmonic with spectral fringes, obtained by propagation in a C-cut sapphire sample of 2 mm. Δ λ was calculated for the raw data and a smoothed/filtered version to reduce the effect of noise. From Ref. [27].
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Table 1. Current and future laser capabilities of the L2I.
Table 1. Current and future laser capabilities of the L2I.
System NIR 100 kHz MPC Mid-IR OPCPA YCOB OPA* CPA* 3OPA*
Parameter
Wavelength (nm) 1030 1030 3000 1030 1030 3000
Energy ( μ J) 1000 600 65 1-10 75000 5000
Duration (fs) 1000 <100 40 <100 6000 85
Rep. rate (kHz) 100 100 100 100 0.01 0.01
* Under development.
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