A new methodology on the determination of the surface properties of solid surfaces was recently proposed. Our new approach consisted in the accurate quantification of the London dispersive surface energy of materials using the two-dimensional inverse gas chromatography technique at infinite dilution. the notion of the net retention volume of adsorbed molecules The Hamieh thermal model proving the temperature effect on the surface area of organic molecules adsorbed on H--zeolite / rhodium catalysts at different rhodium percentages, was used to determine the accurate values of the London dispersive surface energy of solid surfaces at different temperatures. Whereas, the new method allowing a precise evaluation of dispersive adhesion work, dispersive surface enthalpy and entropy of adsorption of n-alkanes adsorbed on the catalysts. In this paper, the London dispersive surface energy and adhesion work of H--zeolite supported rhodium catalysts using the free energy of adsorbed molecules obtained from the two-dimensional inverse gas chromatography technique at infinite dilution. It was proved that the London dispersive surface energy depended on the temperature and the rhodium coefficient while the dispersive adhesion work of n-alkanes adsorbed on H--zeolite/rhodium catalysts was function of the temperature, rhodium percentage, and the carbon atom number of n-alkanes.