Free-standing ferroelectric films have emerged as a transformative technology in the field of flexible electronics, offering unique properties that enable a wide range of applications, including sensors, actuators, and energy-harvesting devices. This review paper explores recent advancements in the fabrication, characterization, and application of free-standing ferroelectric films, highlighting innovative techniques such as multilayer structures and van der Waals epitaxy that enhance their performance while maintaining mechanical flexibility. We discuss the critical role of these films in next-generation devices, emphasizing their potential for integration into multifunctional systems that combine energy harvesting and sensing capabilities. Additionally, we address challenges related to leakage currents, polarization stability, and scalability that must be overcome to facilitate commercialization. By synthesizing current research findings and identifying future directions, this paper aims to provide a comprehensive overview of the state-of-the-art in free-standing ferroelectric films and their impact on the development of sustainable and efficient flexible electronic technologies.