Nanocrystalline La1-xNdxFeO3 powders with different concentrations of Nd3+ have been synthesized by modified Pechini method. Their structure was studied by X-ray powder diffraction (XRD). Further, La1-xNdxFeO3 nanoceramics were prepared by high pressure sintering technique. The luminescence spectra of the powders were investigated as a function of concentration of active dopant to check the possible energy transfers observed due to Nd3+ concentration changes. The electrical and magnetic properties of the powders and ceramics were investigated to determine the effect of Nd3+ doping on the dielectric permittivity and magnetization in the wide frequency range.