Green manure could improve soil nutrients and crop production, playing a significant role in sustainable agriculture. However, the impacts of green manure on crop health and the roles soil microbial communities play in the process haven’t been clarified clearly yet. In this study, we investigated soil microbial community composition and structure in four tobacco farmlands, which were treated with different green manure (control, ryegrass, pea and rape), using 16S rRNA gene amplicons sequencing. Results showed that green manure had significant impacts on soil properties, microbial communities and tobacco health. First, soil total C, N and Ca content increased significantly in groups treated with green manure than control. Second, soil community diversity was significantly higher in groups treated with green manure. Third, green manure especially ryegrass, decreased tobacco disease (bacterial wilt) rate dramatically, and the process might be mediated by soil microbial communities. On the one hand, several microbial populations were found to be potentially disease inducible or suppressive. For example, the abundances of Dokdonella and Rhodanobacter were positively correlated to tobacco disease rate, while Acidobacteira_Gp4 and Gp6 had negative correlations with tobacco disease. On the other hand, soil microbial communities were shaped by soil properties (e.g., pH, C and N content). In conclusion, our research showed that green manure could increase soil nutrients directly, and further improve tobacco health mediated by soil microorganisms, which may shed light on revealing interactions among soil properties, microorganisms and plants.

A homogenization of billets from Al-Cu-Li-Mg-Sc-Zr alloys should be accomplished at high annealing temperatures exceeding 500 °C. This type of aluminum alloy is susceptible to the depletion of surface layers from Li. Therefore, choosing a suitable homogenization temperature and duration is a crucial step in assuring a homogeneous distribution of alloying elements and optimal exploitation of the potential of the alloy. In-situ heating in an electron microscope was performed on a twin-roll cast Al-Cu-Li-Mg-Sc-Zr alloy to understand the peculiarities of the homogenization process. Four types of primary phase particles rich in Cu, Li, Mg, and Fe were identified in the as-cast material. They appear as coarse particles at the boundaries of eutectic cells. Their partial dissolution occurs at temperatures above 450 °C. They are almost fully dissolved at 550 °C, except for complex phases containing Fe and Cu. Small dimensions of eutectic cells in the range of 10 µm assure a homogeneous distribution of main alloying elements within the matrix after 20 min of annealing. Direct comparison with the same material prepared by mold-casting indicates that such short annealing times result in the dissolution of main primary phase particles but do not assure a homogeneous distribution of alloying elements in the whole volume of the specimen.

This study investigated defect formation and strain distribution in high Mg content Al-Mg alloys during normal rolling and cross-rolling processes. The finite element analysis (FEA) revealed the presence of wave defects and strain localization-induced zipper cracks in normal cold rolling, which were confirmed by experimental results. The concentration of shear strain played a significant role in crack formation and propagation. However, the influence of wave defects was minimal in the cross-rolling process, which exhibited a relatively uniform strain distribution. Nonetheless, strain concentration at the edge and center regions led to the formation of zipper cracks and edge cracks, with more pronounced propagation observed in the experiments compared to FEA predictions. Furthermore, texture evolution was found to be a crucial factor affecting crack propagation, particularly with the development of the Goss texture component which is observed by electron backscattered diffraction analysis at bending points. The Goss texture hindered crack propagation, while the Brass texture allowed cracks to pass through. This phenomenon was consistent with both FEA and experimental observations. To mitigate edge crack formation and propagation, potential strategies involve promoting the formation of the Goss texture at the edge through alloy and process conditions, as well as implementing intermediate annealing to alleviate stress accumulation. These measures can enhance the overall quality and reliability of Al-Mg alloys during cross-rolling processes. In summary, understanding the mechanisms of defect formation and strain distribution in Al-Mg alloys during rolling processes is crucial for optimizing their mechanical properties. The findings of this study provide insights into the challenges associated with wave defects, strain localization, and crack propagation. Future research and optimization efforts should focus on implementing strategies to minimize defects and improve the overall quality of Al-Mg alloys in industrial applications.

Air pollution is a critical issue impacting urban environments, leading to severe health problems and environmental degradation. This comprehensive review examines the potential of green systems—specifically green walls, active green walls, and urban greenery systems—to mitigate atmospheric pollutants such as particulate matter (PM), volatile organic compounds (VOCs), and carbon dioxide (CO2). By systematically analyzing 44 recent studies, the review highlights the pollutant capture efficiency of various green technologies and plant species in both indoor and outdoor settings. Active green walls, particularly those utilizing plant species such as Chlorophytum comosum and Sansevieria trifasciata, were found to be highly effective, with VOC reduction efficiencies up to 96.34%, PM reductions by 65.42%, and CO2 reduction rates reaching 4.8% under optimal conditions. The review identifies key strengths in current research, including diverse experimental setups and the use of sophisticated measurement techniques, but also notes significant limitations such as variability in experimental conditions and a lack of long-term performance data. The study underscores the importance of proper maintenance to sustain green systems' efficacy and highlights the potential issue of pollutant resuspension, which remains under-researched. Practical implications for urban planning are discussed, advocating for the integration of effective green systems into urban infrastructure to enhance air quality and public health. Recommendations for future research include the need for standardized metrics, long-term studies, economic feasibility analyses, and real-world validation of simulation models to better understand and optimize green systems for urban air pollution mitigation.

This review is dedicated to sustainable practices in liquid chromatography. HPLC and UHPLC methods contribute significantly to routine analytical techniques. Therefore, the transfer of classical liquid chromatographic methods into sustainable ones is of utmost importance in moving toward sustainable development goals. Among other principles to render a liquid chromatographic method green, substitution of the organic solvent component in the mobile phase with a greener one received great attention. This review concentrates on choosing the best alternative green organic solvent to replace the classical solvent in the mobile phase for easy rapid transfer to a more sustainable normal phase or reversed-phase liquid chromatography. The main focus of this review will be on describing the transfer of non-green to green and white chromatographic methods in an effort to elevate the sustainability best practice in analytical chemistry. The greenness properties and greenness ranking in addition to the chromatographic suitability of seventeen organic solvents for liquid chromatography are mentioned to have a clear insight into the issue of rapidly choosing the appropriate solvent to transfer a classical HPLC or UHPLC method into a more sustainable one. A simple guide is proposed for making the liquid chromatographic method more sustainable.

A two-fold integrated research study was conducted; firstly, to understand effects of copper (Cu) and zinc (Zn) on the growth and oxidative stress in Nile tilapia, Oreochromis niloticus; secondly, to study the beneficial effects of the duckweed Lemna minor L. as a heavy metal remover from wastewater. Experiments were conducted in mesocosms with and without duckweed. Tilapia fingerlings were exposed to Cu (0.004 and 0.02 mg/L) and Zn (0.5 and 1.5 mg/L) and fish fed for four weeks. We evaluated the fish growth performance, the hepatic DNA structure using comet assay, the expression of antioxidative genes (superoxide dismutase, SOD; catalase, CAT; glutathione peroxidase, GPx and glutathione-S-transferase, GST) and GPx and GST enzymatic activity. The results showed that Zn exhibited more pronounced toxic effects than Cu. Low dose of Cu did not influence the growth whereas higher doses of Cu and Zn significantly reduced the growth rate of tilapia compared to control, but addition of duckweed prevented weight loss. Further, in the presence of a high dose of Cu and Zn, DNA damage decreased, antioxidant gene expressions and enzymatic activities increased. In conclusion, results suggest that duckweed and Nile tilapia can be suitable candidates in metal remediation wastewater assessment programs.

Hydroxytyrosol (HT) is a nutraceutic compound, mainly found in the fruit, leaves and waste from the olive oil industry, that shows one of the highest antioxidant activities among molecules of natural origin. To harness this bioactivity in cosmetics, pharmaceuticals, and the food industry, it is essential to modify the hydrophilicity of HT to enhance its compatibility with lipid-based mixtures. This chemical modification must be done with high selectivity to avoid compromising its radical scavenging activity. This work presents a highly efficient and selective approach to perform the biocatalytic esterification of free fatty acids (FFAs) of different alkyl chain length with HT in a reaction medium based on the SLIL [C12mim][NTf2]. By using a 1:2 (mol/mol) HT:FFA mixture of substrates, the HT monoester derivative was obtained up to 77% yield after 2 h at 80 oC. The adjusted molar ratio of substrates, combined with the ability to recover the SLIL for further reuse, significantly reduces waste accumulation compared to other reported strategies and results in a more sustainable approach as demonstrated by different green metrics. Furthermore, it was demonstrated by a DPPH test how the HT monoester products retain the same antioxidant activity as free HT, being superior to vitamin C.

Seaports are critical hubs in global trade, facing increasing pressure to accelerate green transi-tions while navigating evolving economic and environmental landscapes. This research analyses the intricate relationship between port organizational ecosystem resilience and the successful implementation of green transitions, highlighting the challenges and opportunities in moving towards a more sustainable future. The research employed a combined focus group interview and participatory observation methodology to gather insights from experts. Analysis revealed that while technological advancements are a primary driver for greening port operations, a lack of managerial capacity is a significant impediment to the successful integration of these innova-tions. It was identified several challenges, including outdated infrastructure, cybersecurity threats, and the need for ongoing investments in new technologies, along with the need to foster a sustainable behaviour culture. Experts emphasized the importance of developing managerial competencies and continuous learning. The research also highlights the role of strong stake-holder partnerships, including collaboration with government agencies, industry associations, and environmental organizations. This research provides valuable insights for policymakers, port managers, and other stakeholders seeking to navigate the challenges for ensuring a sus-tainable future for the maritime sport organizational ecosystems and maritime industry.

In light of the accelerated pace of economic growth and urbanisation, the transformation of green buildings has emerged as a prominent area of re-search. A considerable number of existing buildings have been constructed and are still in use. However, the energy consumption and environmental impact throughout the entire life cycle of these buildings are not adequately considered in the renovation design. This results in high energy consumption and poor indoor comfort. In this work, we include improving the thermal insulation of buildings, such as thickening the insulation of external walls and replacing energy-efficient windows to reduce energy losses caused by temperature differences between in-door and outdoor buildings; Adopt energy-efficient HVAC systems to reduce en-ergy consumption and improve indoor air quality by upgrading equipment effi-ciency, optimizing duct design, and intelligent control systems; At the same time, we will introduce renewable energy sources such as solar energy, and we will not only install solar photovoltaic panels to generate electricity, but also use solar thermal collector systems to provide hot water and heating, so as to achieve di-versified and sustainable use of energy. Combined, these measures can effec-tively reduce the overall energy consumption of the building, reduce carbon emissions, and improve the comfort and health of the indoor environment. During the experimental analysis, the energy consumption and indoor comfort before and after the renovation were evaluated, and the results showed that the energy consumption was significantly reduced and living comfort was improved.

Green leaf volatiles (GLV) are important signaling compounds that help to regulate plant defenses against pests and pathogens. Made through the hydroperoxide lyase (HPL) pathway, they are rapidly produced upon damage and can signal this to other parts of the same plant or even plants nearby, where they can induce rapid defense responses directly or prime them against the impending danger. In this primed state plants can respond faster and/or stronger should pests or pathogens attack. However, while all proteins and genes involved in the biosynthesis of GLV have been identified, little is still known about how the first two steps in the pathway, e.g., oxygenation by a lipoxygenase (LOX) and subsequent cleavage by HPL are facilitated within the damaged tissue, resulting in the production of Z-3-hexenal (Z3al) as the first committed product of the pathway. Here, we provide evidence that several factors might be involved in the production of Z3al including pH, Ca2+, and an environment that is highly hydrophobic. We present a model in which the extraordinary circumstances that are present at the site of Z3al production are considered and shine new light on potential regulatory mechanisms.

The wastewater problem is becoming an increasingly significant environmental issue affecting various aspects of human activities. The generation of reactive oxygen species (ROS) in water through certain physicochemical processes, which can oxidize or degrade various organic and chemical compounds, offers an effective purification method. The main advantage of these methods is the elimination of chemical reagents. Aim of this work is to investigate the possibility of regulating the ROS content in water by altering the characteristics of the plasma discharge that occurs under hydrodynamic cavitation in the water flow. ROS concentration was determined using the permanganate oxidation titration technique. It was found that the content of various reactive oxygen species in water after treatment can be controlled by varying the power of the electrical pulses applied. Additionally, the study obtained the dependence of ROS concentration in treated water samples on storage time, indicating a prolonged effect of sonoplasma treatment on the antibacterial properties of water. Analysis of water samples using a biological test culture of Salmonella typhimurium revealed bacteriostatic properties of the water for at least 48 hours after sonoplasma discharge treatment.

The new digital infrastructure has become an important basis for the green development of agriculture. This paper selects provincial sample data from 2006 to 2022, constructs an indicator system to measure new digital infrastructure and agricultural green total factor productivity, and explores how new digital infrastructure can promote agricultural green development. The results show that: (1) the new digital infrastructure has a significant role in promoting the green development of agriculture, and this conclusion is still valid after processing endogeneity and heteroscedasticity; (2) Technology and land factors play an intermediary role in the promotion of green agricultural development by the new digital infrastructure, that is, the new digital infrastructure helps to improve the quality and technical level of cultivated land and thus promote green agricultural development; (3) Labor force factors optimize the mediating role of technology factors, that is, the higher the quality of labor force, the stronger the role of the new digital infrastructure in promoting the green development of agriculture through the technological path; (4) The effect of new digital infrastructure on the green development of agriculture is obviously heterogeneous, and the effect is more obvious in northwest China and the regions with lower marketization level, higher environmental regulation level. This study is helpful to clarify the relationship between new digital infrastructure and agricultural green development in China, and provide corresponding policy suggestions for promoting regional agricultural green development.

This study seeks to comprehend the complex and diverse dynamics of women's encounters with urban green areas in the specific setting of Jordan. The utilization of the focus group methodology facilitated the organization of unstructured talks involving a cohort of twenty-seven female participants, which yielded intricate and perceptive perspectives on their opinions. This study revealed a widespread pattern of stigmatization and unfavorable assessment of women who utilize public areas, which is strongly ingrained in cultural norms and gender expectations. Women were also concerned about the potential harm to their reputation and the censure of society, which ultimately deterred women from participating in public spheres. The research thus centers on the close proximity and insufficiency of urban green areas in Jordan, which is worsened by high urban density. Insufficient lighting and security measures are responsible for further limiting women's access to areas like these, which also raises concerns about safety. Recent evidence has revealed deficiencies in infrastructure designed to accommodate the needs of women, particularly in public restroom facilities. This study emphasizes the immediate necessity for a fundamental change in urban policy and planning, towards more inclusive approaches. Within this strategic framework for urban policy, there is a strong emphasis on incorporating aesthetics, comfort, and safety elements to enhance the whole urban experience for women. Consequently, addressing this issue necessitates using gender-responsive strategies in urban design and planning. This includes enhancing the quality, cleanliness, and privacy aspects of facilities to cater to the specific needs of women and improve their overall well-being. This study contends that any ongoing discussion on sustainable urban development in Jordan must take into account the interaction between urbanization, accessibility to public spaces, and the well-being of women. Therefore, it is necessary to implement a worldwide effort to advocate for urban policies that include both genders. This program aims to propose innovative approaches to governance, security measures, and municipal infrastructures that are sensitive to gender-related issues.

Scholars in the field of environmental economics have extensively examined the relationship between foreign direct investment (FDI) and economic growth. However, they have often failed to consider the crucial roles played by technological innovation and financial development in determining environmental costs. The rapid economic growth and urbanization witnessed in BRICS countries have led to a substantial increase in energy demands, resulting in significant environmental degradation. This study aims to investigate the impact of financial development (including measures such as broad money, domestic credit to the private sector, FDI, and green technological innovation) on carbon emissions in BRICS countries using data from 2001 to 2023. The results of the study demonstrate a strong cross-sectional dependence among the countries in the panel. The Augmented Mean Group (AMG) estimator reveals a negative and statistically significant long-term relationship between broad money, FDI, green technological innovation, and CO2 emissions. On the other hand, domestic credit to the private sector shows a positive and significant association with carbon emissions. To determine the direction of causality, the study utilizes the Dumitrescu and Hurlin panel causality test. The findings indicate a non-directional long-term causality between financial development and CO2 emissions. However, a unidirectional causality is observed between green technological innovation and carbon emissions. Based on these findings, the study suggests that the development of industries, financial institutions, and technological innovation is crucial for attracting high-quality FDI in BRICS countries. However, it also highlights the significant contribution of these developments to environmental degradation, necessitating urgent policy responses.

The application of AI technology in urban planning covers multiple levels, such as data analysis, decision support, and automated planning. Urban research relies on AI technology to understand and summarize the law of urban growth and improve the analysis of the evolution trend of urban space. Planning and design use AI technology to explore the relevant factors affecting urban development and their weights and discuss the critical role of green building technology in the sustainable development of the construction industry. With the increase in global energy consumption and carbon emissions, traditional building methods can no longer meet environmental protection requirements and efficient use of resources. As a sustainable development solution, green building technology has been paid more and more attention to and adopted by people. These technologies focus not only on the energy efficiency and environmental impact of buildings but also on the resource utilization and environmental load of green buildings over their entire life cycle driven by machine learning. This paper details the basic principles and applications of green building technologies, including AI-driven reduction of negative environmental impacts, improvement of occupant health, efficient use of resources, and optimization of indoor environmental quality. This paper focuses on the critical role of the LEED assessment system developed by the U.S. Green Building Council in advancing green building practices. In addition, the paper analyzes vital points such as water use in green building design, machine learning-driven wind environment optimization, solar technology application, and practical application cases of these technologies on a global scale.

Aloe vera is well known for its biological properties as a bioflavonoid-anti-inflammatory, antibacterial agent. It has been used frequently in the food sector as food coating for its hygroscopic properties and as an ingredient in the lucrative industry. Studies have also included Aloe vera as an eco-friendly green solution based on these properties. The current research focuses on the use of Aloe vera gel in printing pastes as an alternative sustainable solution to synthetic thickeners, evaluating its wet performance and ease of fabric stitching, and has been inspired by studies that similarly used this substance measuring its effect on the fabric's coefficient of friction and antimicrobial action. In the current study, printing pastes with natural colourants and Aloe vera gel thickener derived from natural leaves from Crete increased the fabric's mechanical resistance to abrasion compared to the untreated pastes. The measured performance did not differ substantially from prints with traditional synthetic pastes, hence tolerating the substitution with the non-contaminant variant. The enhanced resistance to abrasion and wear prolongates the fabric's serviceable life and resulting garments, decreasing the need for high industry processing volumes and, as a result, reducing pollution. The resistance to wear was evaluated using the dominant method in textile testing of the Martindale apparatus, which measured the cycles to failure, weight loss, and general appearance deterioration using the official photographic standards.

Manufacturing enterprises are increasingly compelled to pursue innovative solutions to environmental issues. Addressing such issues requires mindful leadership to support employees and organizations in maintaining awareness during complex situations, thereby promoting environmental sustainability. Drawing on social information processing theory, this study theorizes and tests the relationships mindfulness leadership, employee moral reflectiveness, environmental passion, and employee green creativity. To test the model, we utilize a two-wave multi-source dataset comprising 215 workers from manufacturing firms in China. The findings demonstrate that mindful leadership is positively related to employee green creativity. Additionally, our research reveals that both moral reflectiveness and environmental passion serve as mediators in linking mindful leadership to employee green creativity. Crucially, our empirical analysis suggests a serial mediation model, examining the sequential role of moral reflectiveness and environmental passion in the relationship between mindful leadership and employee green creativity. The findings provide a new viewpoint on employees' eco-friendly behaviors and have practical implications for improving environmental sustainability within organizations.

This research analyzes the phenomenon of the reduction of urban green spaces in the post-socialist city. Belgrade was selected as a post-socialist city of the former Yugoslavia. The article analyses the views of urban planners on the reasons for the reduction of urban green areas in the post-socialist city based on semi-structured interviews with representative samples for urban areas. This result research confirms the hypothesis that post-socialist city planning reduces urban green areas due to the lack of new mechanisms in documents for the planning of urban green space. The concept of sustainability should connect and balance the skills of urban planners and focus on how urban planners develop and apply standards and protect them in market-democratic systems. In other words, a new mechanism of post-socialist city planning implies a balance between the private and public sectors. In the planning document, urban planners should find a common denominator between the public interest, citizens, investors, and spheres determined by the sustainable principles of the development. City institutions should provide opportunities for the application of those standards. With the new approach, planning would imply work in the service of citizens in the concepts of a sustainable and green city.

The intensification of modern farming methods in developed nations has exacerbated the issue of soil degradation and over-utilization of naturally available resources, hence, tinkering negatively with the health and productive capacity of soil. Chemical fertilizers, while increasing crop yields, have resulted in environmental pollution and health hazards. Green manuring presents a sustainable alternative by enriching soil fertility and reducing reliance on chemical fertilizers. This paper reviews the impact of green manuring on soil properties, crop yield, and farm economies. In-situ green manuring involves growing and incorporating the crops within the field, while ex-situ green manuring incorporates plant material from external sources. Leguminous green manures are particularly effective owing to nitrogen fixation capability and rapid decomposition. The inclusion of green manure improves the availability of nutrients, microbial count and carbon content of the soil, thereby, enhancing the overall health of soil and crop productivity. Additionally, green manures reduce pests and diseases, suppress weeds, and provide supplementary forage. Despite the benefits, challenges such as limited water resources, seed availability, and farmer reluctance hinder widespread adoption. Future research should focus on raising awareness, quantifying benefits, and developing location-specific cropping systems to optimize green manuring practices.

Indocyanine Green (ICG) has significantly advanced minimally invasive surgery. It is widely recognized for its ability to visualize blood vessel patency in real-time across various surgical specialties. While its primary use in colorectal surgery is to evaluate anastomoses for leaks, nu-merous other applications have been documented in the literature. In this review, we aim to explore both established and emerging applications of ICG fluorescence in colorectal surgery, with the goal of improving patient outcomes. This includes preoperative tumor marking and the detection of metastatic disease. Some applications, such as lymphatic mapping, require further research to determine their impact on clinical practices. Conversely, oth-ers, like the intraoperative localizations of ureters, necessitate additional procedures and are not yet widely accepted by the surgical community. However, the development of alternative com-pounds could offer better solutions. Future research should focus on areas like quantitative ICG and protocol standardization in prospective multicenter studies.

This study draws on both the theory of resource-based view and the theory of stakeholders to investigate the effects of Green Human Resource Management (Green HRM) practices on Sustainability and Employee Health Orientation (EHO) through the mediating effect of Environmental Performance (EP). Based on a cross-sectional survey questionnaire, the data were collected from 318 service and manufacturing firms across India. Partial least squares structural equation modeling (PLS-SEM) was applied to determine the link among constructs. The findings of the empirical evidence reveal that Green HRM practices have positive and significant effects on EP, Sustainability and EHO. Also, the findings demonstrate that EP partially mediates the link between Green HRM practices and Sustainability. Similarly, the findings establish that EP partially mediates the link between Green HRM practices and EHO. Finally, the potential implications of this research and future research for practitioners and scholars are addressed.

Vegetable oils contain fatty acids, phenolic compounds, natural antioxidants, and fat-soluble vitamins, which are beneficial against different diseases. Oil extraction methods can, however, affect their composition. This study aims to characterize the chemical composition of oils from two Andean seeds, cañihua (Chenopodium pallidicaule) and tarwi (Lupinus mutabilis), extracted with different organic solvents, petroleum ether, hexane, and ethanol. This study compares these oils with commercial sunflower, rapeseed, and olive oils. Results showed that oils extracted with hexane had the highest yield, while those extracted with ethanol had higher antioxidant activity and total phenolic compound content. Additionally, using ethanol makes the process more sustainable than non-green solvents. The composition of tarwi and cañahua oils extracted with ethanol includes fatty acids, tocopherols, antioxidants, and phenolic compounds associated with health benefits.

Recent climate change and water pollution has affected algal diversity resulting in emergence of more tolerant species. They can be the indicators of water quality, pollution and seasonal changes. Present study revealed the green algal diversity and distribution pattern according to water parameters and season in the Lucknow City, India. The water sample were collected from seven sites within Lucknow and outskirts. The occurrence of a total of 36 taxa of green algae belonging to 11 genera are recorded. It has been observed that less polluted water is dominated by Spirogyra; where conductivity, TDS and salinity of water were low. Whereas the more polluted water was dominated by desmids. Dominance index was found highest in site 4 (0.61), where only three taxa were identified; whereas the lowest (0.13) was measured in site 1, where nine taxa were identified. This study also recorded several algal taxa for the first time from Lucknow.

China is experiencing rapid urbanization. The focus on health issues has shifted from the treatment of diseases to passive or active prevention. Diseases caused by the deterioration of the urban environment, such as cardiovascular disease, diabetes, obesity and other chronic diseases and mental illness, have gradually become the main threat to public health. Studies have confirmed that urban green spaces (UGS) can help residents relieve mental stress, improve mood, reduce mental fatigue and restore attention, which has a positive effect on people's physical and mental health. In this study, the relationship between the quantity and quality factors of UGS and the physical and mental health of urban residents in Xihu District of Hangzhou is examined, and on this basis, UGS design strategies are proposed to promote the physical and mental health of residents. This study is of great significance for the future construction of UGS that are beneficial to the health of residents and the promotion of a healthy China and healthy city construction.

In this paper, we investigate the Green measure for a class of non-Gaussian processes in $\mathbb{R}^{d}$. These measures are associated with the family of generalized grey Brownian motions $B_{\beta,\alpha}$, $0

Promoting green development has become an important way to optimize the ecological and economic structure and promote sustainable development. The Yangtze River Economic Belt is an important economic corridor in China, and it remains to be examined whether the implementation of environmental regulations has enhanced the green total factor productivity (GTFP) of cities. This paper calculates the green total factor productivity of 107 cities within the Yangtze River Economic Belt by using the super-efficient SBM model and the GML index with Chinese city panel data from 2007-2019 and measures the intensity of environmental regulations through textual analysis. The bidirectional fixed-effects model constructed in this paper suggests an inverted U-shaped relationship between environmental regulation and GTFP, which is confirmed by a series of robustness tests. Green technology innovation and advanced industrial structure play a mechanism role in this. In regions with lower levels of green technology and industrial structure, the inverted U-shaped relationship between environmental regulation and green total factor productivity is more significant. In addition, the phenomenon of GTFP rising and then falling because of environmental regulation is more obvious in cities in the middle and upper reaches of the Yangtze River and outside the urban agglomerations. Therefore, when formulating environmental regulation policies, it is necessary to balance the relationship between economic development and environmental protection and harmonize the environment and economic development of the entire Yangtze River Basin.

Hydrogen has a leading role in accomplishing a net zero green-house gas emission future. Today’s challenge is producing green hydrogen to cover the fuel demand of transportation and industry, to gain independence from fossil fuels. This review’s goal is to demonstrate critically the existing methods of biomass treatment and assess their ability to scale up. Biomass is an excellent hydrogen carrier and biomass-derived processes are the main target for hydrogen production as it is an innovative pathway to green hydrogen production. Comparing the existing processes, thermochemical treatment is found to be far more evolved than biological or electrochemical treatment especially with regard to scaling prospects.

Green open spaces (GOS) are well known to be vital to enhancing the standard of living conditions in urban environments. The World Health Organization (WHO) says it is important to have at least nine square meters per citizen. The European Environment Agency (EEA) stipulates that 5000 square meters of green space will be reachable within 300 meters to residents. GOS pattern in Kyrenia Region is not adequate or successful in that regard. The process of urban planning has been neglected in the Kyrenia region and these areas have lost their significance and value. This research evaluates the level of accessibility of green spaces in Kyrenia Region. Three urban areas, Kyrenia, Karavas and Agios Epiktitos have been analyzed within this framework. In order to do that, GOS areas and their pattern are researched by deploying geographical information analysis. Accessibility to these areas is measured by using Euclidean and network distance analysis based on 300, 800 and 5000 meters. Mainly, Euclidean distance and network distance methods are measured from building units and results showing accessibility values are constructed. According to the results, network accessibility is very low within the study region. Additionally, Kyrenia, Karavas and Agios Epiktitos have shortage in GOS per capita. To offer effective strategies for urban planning, the factors influencing the accessibility and also the usage of GOS are addressed.

Lyme disease, the leading vector-borne ailment in the U.S., annually affects an estimated 476,000 individuals, predominantly in the Northeast and Upper Midwest. Despite its increasing incidence, the evaluation of risk within U.S. cities, including natural public lands, remains inadequate. This study focuses on blacklegged tick occurrences and Borrelia burgdorferi infection prevalence in 24 Staten Island parks, aiming to assess Lyme disease exposure risk. Monthly acarological risk index (ARI) calculations from 2019 to 2022 revealed elevated values (0.16-0.53) in specific parks, notably Wolfe’s Pond Park, High Rock Park, Clay Pit Pond Park, Clove Lake Park, and Fair View Park. June (0.36) and November (0.21) consistently exhibited heightened ARIs, aligning with peak tick collection months. Despite stable yearly infection rates at 28.97%, tick densities varied significantly between parks and years. Identifying a high transmission risk in specific parks in Staten Island, a highly urbanized part of New York City, emphasizes the continuous necessity for Lyme disease risk management, even within the greenspaces of large cities.

Green leaf volatiles (GLVs) are important in giving grape a fresh and green aroma. But the changes in GLVs during the phenological development of grapevines are not well known. This study analysed the GLVs and transcription levels of associated biosynthetic genes in six grape species from the Loess Plateau region at five stages of maturation. Thirteen GLVs were detected, showing unique patterns for each grape type at various growth phases. The primary components in six grapes were (E)-2-Hexenal, (E)-2-Hexen-1-ol, and Hexanal. With the exception of Cabernet Franc in 2019, the overall GLV contents of the six types generally increased during growth and development, peaking or stabilizing at harvest. And Sauvignon Blanc, Cabernet Gernischt, and Cabernet Sauvignon exhibited higher total contents among the varieties. Correlation analysis revealed a strong positive correlation between the levels of Hexanal, 1-Hexanol, (E)-2-Hexen-1-ol, (Z)-3-Hexenyl acetate, Nonanal, and (E, E)-2,6-Nonadienal and the expression of VvHPL and VvAAT genes in the LOX-HPL pathway. Specifically, VvHPL emerges as a potential candidate gene responsible for species-specific differences in GLV compounds. Comprehending the changing patterns in the biosynthesis and accumulation of GLVs offers viticulturists and enologists the opportunity to devise targeted strategies for improving the aromatic profile of grapes and wines.

Green synthesis of silver nanoparticles (AgNPs) using raw Whey has never been reported. Silver nanoparticle formation involves a reduction reaction of silver salt solution with Whey extract. Extract and metal salt concentrations, and temperature can control this reaction. In this work, incubation period, extract, AgNO3, and NaOH concentrations were used as the independent factors using central composite design under response surface methodology. The aim was to elucidate the influence these factors have on the measured UV-Vis absorption spectra fitted with a Voigt function, and to optimize the conditions for nanoparticle formation. The fitting parameters, peak wavelength (λ0), peak area (A), and Full Width at Half Maximum (FWHM), were the responses. Silver nanoparticle formation was only possible in an alkaline environment (pH 10). The peak wavelength and the FWHM are influenced mainly by extract and AgNO3 concentrations. In contrast, the peak area is influenced by a total of 33.54 % from the interaction terms of AgNO3 and extract concentrations with NaOH. Metallic AgNPs were formed for the following parameter ranges: a) Whey (0.4 – 1.6 % v/v), b) AgNO3 (0.15 – 0.6 mM), c) NaOH (10 – 50 mM), and d) Time (20 – 60 min). Silver oxide nanoparticles were also observed.

In the last decade, with the increased concerns about the global environmental situation, attempts have been made to promote the replacement of fossil fuels with sustainable sources. For transport, which accounts for around a quarter of total greenhouse gas emissions, meeting climate neutrality goals will require replacing existing fleets with electric or hydrogen propelled vehicles. This research addresses the problem of transport fleet renewal by proposing a multi-criteria decision-making approach, taking into account the multiple propulsion technologies currently available and the objectives of the EU Green Deal, as well as the uncertainty related to the technological scenario, in a generalized Life Cycle framework. The proposed approach, based on the TOPSIS model, demonstrates how the optimality of the choice is related to the different technological scenarios and to the risky attitude of the decision maker. The proposed methodology is finally validated against a practical case referred the strategic fleet renewal decision process, and the results obtained demonstrate how the decision maker’s perception about the technological evolution of the propulsion technologies influences the decision process, thus leading to different optimal choices.

The study provide insights into the technological characteristics of green practices adoption and the potential benefits they offer in terms of socio-economic development, environmental and public health. The study adopted a cross-sectional research design. A structured questionnaire was developed to collect quantitative data from the participants. The questionnaire include closed-ended questions, Likert scale items, and demographic questions. Both stratified and simple random sampling techniques were employed to select the study participants (government officials, employees, managers, and community members). A total of 321 copies of questionnaires were duly filled and returned. The collected data were analyze using descriptive statistics, such as frequencies, percentages, mean, and standard deviation, were used to summarize the data and provide an overview of the key variables related to green practices adoption. The findings indicate that the manufacturing company in Ogun State, Nigeria, has shown moderate commitment to adopting green practices. While there is room for improvement in certain areas, such as waste-to-energy technologies and green building practices. Additionally, green practices have positively influenced employee well-being and community health, while aligning with the company's commitment to safeguarding the environment and public health.

Novel antibacterial silver nanomaterials have become promising substitutes for traditional antibiotics, because pathogens do not develop resistance to them. However, it is necessary to produce silver nanoparticles with appropriate size and better performance through a green and simple synthesis process. In the present study, Fructus mori-composite silver nanoparticles (M-AgNPs) were greenly synthesized using medicinal plant mulberry fruits (Fructus mori), with silver nitrate (AgNO3) as a precursor. UV-Vis spectroscopy and X-ray diffraction (XRD) indicated the formation of silver nanoparticles with face centered cubic structure. Fourier transform infrared (FTIR) spectroscopy confirmed the reducing and capping effects of mulberry fruits' active components (polyphenols, flavonoids, etc.) on M-AgNPs. The reaction parameters including temperature, time, pH, and concentration of AgNO3 were gradually optimized. The particle size and morphology of M-AgNPs were measured by dynamic light scattering (DLS) and transmission electron microscopy (TEM) techniques. The minimum particle size of M-AgNPs was about 30 nm, and they were approximately spherical and equably distributed. The excellent stability of M-AgNPs ensured that no agglomeration occurred for up to 60 days. The antioxidant activity of M-AgNPs was evaluated by 1,1-diphenyl-2-trinitrophenylhydrazine (DPPH) assay, and the DPPH radical clearance rate of M-AgNPs was up to about 79%. Greenly synthesized M-AgNPs exhibited better antibacterial activity than chemically synthesized commercial silver nanoparticles (C-AgNPs), due to the active molecules attached to their surfaces. The inhibition zone diameters of M-AgNPs against P.aeruginosa, E.coli and S.aureus were 13.9±0.4、12.2±0.3、12.8±0.7 mm, respectively. Such greenly synthesized AgNPs from medicinal plants have good prospects in the field of biomedicine.

Abstract: Marine eutrophication is a pervasive and growing threat to global sustainability. Thereby nutrient discharges to the marine environment should be reduced to a minimum. When fertilizers are loaded to vessels in ports, a significant amount of nutrients are released into the sea, but so far these actions have received little attention. Here, we employed the Boosted Regression Trees modeling (BRT) to define relationships between fertilizer loading, loading area, rain intensity and nutrient discharge to the marine environment and then used the established relationships to predict daily nutrient discharge due to fertilizer loading. The studied subject was a port in the Gulf of Finland, where significant amount of both nitrogen and phosphorus are loaded to vessels. BRT models accounted for a significant proportion of the variability of nutrient discharge. As expected, the nutrient discharge increased with the amounts of fertilizers loaded and the intensity of rain. On the other hand, with increasing loading area the amounts of total nitrogen discharge increased, but phosphorus discharge decreased. The latter result may be due to different char-acteristics of the loading areas of different terminals. The model predicted that at the studied port the total nitrogen and phosphorus discharge into the marine environment due to fertilizer loading was 272,906 and 196 kg per year, respectively. Im-portantly, the developed model can be used to predict nutrient loads for different future scenarios to propose the best mitigation methods for nutrient discharges to the sea.

The rapid growth of urban areas has led to a decline in the amount of green space available to residents. This has a number of negative consequences for human health and well-- being. Green spaces provide a number of benefits for human health, including improved physical, mental, and social health. They also have a number of economic benefits, such as increased property values and reduced crime rates. Given the many benefits of green spaces, it is clear that they are essential for the health and well-being of urban residents. Policymakers and planners should prioritize the creation and preservation of green spaces in urban areas.

The adoption of a fully battery-based Electric Vehicles (EVs) in Kuwait apparently seems to be less than one percent and hence Kuwait has the lowest indexed-rank among countries around the globe. The absence of fast-charging stations for fully-battery-based EVs and landlords' reluctance to install home fast-charging plugs are the primary reasons for extremely low adoption rates in this country. Because the government of Kuwait is reluctant to give permission for expatriates to own property in Kuwait, fully battery-based EV ownership is restricted to Kuwaiti nationals who reside in their private properties. To accomplish the present objectives, a quantitative de-scriptive method (closed-ended questions) was used to collect data from a sample of 227 Kuwaiti nationals who owned gasoline cars. The finding of the present study indicates that more than half of the participants stated that they preferred to purchase an EVs within the next three years if certain criteria were met, inclusive of government-controlled pricing policies and charging stations availability, fast-driving lanes, and free of charge parking spaces. Furthermore, more than 40 percent of respondents stated that they would contemplate purchasing an electric vehicle if the price of gasoline or diesel increased by 19 to 50 percent. The finding also indicates that more than forty percent of respondents said that believed that EVs are fire- and crash-safe and roughly half of the participants would pay between 6 and 20% more for an EVs because they be-lieve that EVs are environmentally friendly and significantly faster than gasoline vehicles. In addition, participants rewarded EVs with an excellent mark for their environmental, economic, and technological attributes and benefits.

Offshore Wind Turbines (OWT) with increasingly higher energy output are being developed to meet energy demand, posing challenges for their foundation design. Several foundation types are used to support these turbines with monopiles (MP) accounting for 80% of the installed capacity. In this study, three-dimensional (3D) nonlinear finite element models (FEM) were employed to investigate the behaviour of monopile foundation supporting a 5MW wind turbine when subjected to lateral loading. Results indicate that the MP behavior depending on the pile length to diameter (L/D) ratio and the soil shear strength. Inspection of bending moment profiles at the lateral ultimate capacity indicated the monopiles can behave in flexible manner even with low L/D ratio. The L/D ratio affected the MP normalized lateral ultimate capacity at varying degrees and the biggest effect was for soft clays, amounting to around 5 folds increase for L/D values of 3.33 to 13.33. Lesser effects were found for stiff clays.

The current organisation is facing intensifying competition in the global business world with loads of challenges and tries to sustain itself in the market through innovation and cost-cutting. The scientific community has a growing interest in management to make a niche in the global competitive era. They have started focusing on the expediency of green human resource management (GHRM) to steer the way to excel the organizations and their employees for sustainability. Green HRM tries to build an organization that encourages employees to adopt environmentally friendly workplace behaviours and minimize costs. The aim of this study is to identify and analyse the comprehensive research advances made in the field of green human resource management through bibliometric analysis. The Scopus database has been used to conduct the research. A total of 551 documents were inferred from Scopus, considering the department time period, 2004 to 2023. The outcomes of the study shed light on the eminence of green HRM research, identifying prolific authors and co-authorship patterns, commonly used keywords, country-wise and organization-wise analysis, research themes, theoretical foundations and simple statistics. This comprehensive exploration has provided valuable insights into the concept of green HRM, its objectives, and its potential benefits for businesses and society as a whole.

Due to urban warming, energy demand for cooling buildings is rising. The current study used CitySim to estimate the cooling energy requirements for 40 buildings in Downtown, Dubai using high-resolution climate data from weather research and forecasting (WRF) coupled with single layer urban canopy model (SLUCM). Simulating the four mitigation scenarios allowed for the examination of the reduction in cooling load caused by the addition of greenery at a rate ranging from 25% to 100%. The insulated building's cooling demand reduced by a maximum of 13.89% under 100% GI (M4). Scenario M4 resulted in a reduction of 4.6 kWh/m2 and 3.1 kWh/m2 for the non-insulated and insulated low-rise residential buildings, respectively, while the high-rise buildings saw a reduction of 3.09-4.91 kWh/m2 for the non-insulated and 2.07-3.09 kWh/m2 for insulated buildings. This study offered a potential remedy to deal with the problem of urban heating in subtropical environments.

Background. Green spaces contribute to a significant life quality and maintain the sustainability of cities. In Benin, despite the political greening willingness, municipalities are experiencing technical issues in finding suitable spaces to achieve this goal. This study should serve many other towns. It aims at identifying suitable areas for green spaces to integrate landscaping into urban planning in Abomey-Calavi district. Methods. The multi-criteria analysis combining GIS and the hierarchical classification approach were performed. Six factors (land use, altitude, slope, distance from main roads, proximity to urban centres and distance from flood zones, water bodies) were combined using the ArcGIS "Spatial Analysis" extension to generate a map of green space suitability. Results. large areas of land, of which 23.27% are very suitable and 26.06% are suitable for landscaping in this municipality. The ranking of the factors revealed altitude, proximity to road networks, large conurbations and distance from wetlands accounting for 18%, compared with 14% for the other factors regarding the study environment. However, the use of these results must take into account the existing inhabited areas for a good site selection. Conclusion. These outputs guidance to decision-makers in choosing suitable sites for green spaces there and integrating them into sustainable development.

The impacts of climate change are already felt across the globe, and (SIDS) are at the forefront. Small Islands Developing States (SIDS) are extremely vulnerable to climate change and adaptation is crucial, however they often lack funding or the fiscal capacity to make the necessary invest-ments and require support from climate finance instruments. The Green Climate Fund (GCF) was designed with the objective of achieving a “paradigm shift” towards low-carbon and climate resilient country-driven development pathway. Despite the amounts invested, assessing the impacts of climate finance on adaptation and adaptive capacity, particularly at the institutional level remains a challenge. Researchers identified two key components for more efficient adapta-tion policies at the national level: the degree of adaptation mainstreaming and institutional adaptive capacity. In SIDS, institutional capacity at the national level is seen as a key component to achieve the objectives of climate change strategies, and is supported by several programmes, including the Green Climate Fund Readiness Preparatory Support Programmes. However, to date few studies have analysed the linkages between climate finance, adaptation mainstreaming and adaptive institutional capacity. Through the review of the Readiness Grants and semi-structured interviews in three Caribbean SIDS, this research assess how climate finance may promote in-stitutional change through the mainstreaming of adaptation policies at the national level and contribute to more institutional adaptive capacity. It shows that the grants had a positive impact, which can be limited to by the strength of the institutions in place. These results demonstrate that access to climate finance can create a window of opportunity for countries to accelerate institu-tional change and allow to make recommendations on how to maximise the impacts adaptation funds. More in-depth studies would be needed to examine the complementary influence of the different climate finance flows (multilateral or bilateral) and their interplay with national institu-tional mechanisms.

As traditional supply chains face increasingly severe environmental issues and countries promote green development and sustainable development policy concepts, cultivating green supply chain operation models is gradually being highly valued by current governments and enterprises. Generally speaking, the production of green products incurs higher additional costs and thus their total production costs also increase. In this work, the product green level is related to the random demand. Under the green supply chain buy-back contract with the green product R&D cost sharing between the manufacturer and the retailer, both the product green level and the order quantity need to be decided to maximize the channel profit. In order to coordinate the green supply chain, the manufacturer needs to share both the risk of good salvage and the green product R&D cost with the retailer. We find that both the wholesale price and buy-back price increase in the manufacturer’s proposition of the green product R&D cost, but decrease in emission reduction efficiency coefficient or carbon trading price. In addition, the product green level, the optimal order quantity and the channel profit increase in emission reduction efficiency coefficient, but decrease in the R&D cost coefficient of the product green level. Interestingly, we find that if the carbon trading price is low, the manufacturer will set a low product green level and the product carbon emission trading is a cost for the supply chain. The increment of the carbon trading price leads to a higher cost such that the channel profit is decreased. However, if the carbon trading price is high, the manufacturer will set a high product green level and the product carbon emission trading is a revenue for the supply chain. The increment of the carbon trading price leads to a higher revenue such that the channel profit is increased.

Introduction: Successful R0 resection is crucial for the survival of patients with primary liver cancer (PLC) or liver metastases. Up to date, surgical resection lacks a sensitive, real-time intraoperative imaging modality to determine R0 resection. Real-time intraoperative visualization with near-infrared light fluorescence (NIRF) using indocyanine green (ICG) may have the potential to meet this demand. This study evaluates the value of ICG visualization in PLC and liver metastases surgery regarding R0 resection rates. Materials and Methods Patients with PLC or liver metastases were included in this prospective cohort study. ICG 10mg was administered intravenously 24 hours before surgery. Real-time intraoperative NIRF visualization was made with the SpectrumTM Fluorescence Imaging Camera System. First, all liver segments were inspected with the fluorescence imaging system and intraoperative ultrasound for identification of the known tumor as well as additional lesions, compared to preoperative MRI. PLC, liver metastases, and additional lesions were then resected according to oncological principles. Of all resected specimens the resection margins were analyzed with the fluorescence imaging system for ICG positive spots right after resection. Histology of additional detected lesions as well as ICG fluorescence compared to histological resection margins were assessed. Results Of the 66 included patients median age was 65.5 years (IQR 58.7 - 73.9), 27 (40.9%) were female and 18 (27.3%) were operated laparoscopically. Additional ICG positive lesions were detected in 23 (35.4%) patients of which nine (29%) were malignant. In patients with no fluorescent signal at the resection margin, R0 rate was 93.9%, R1 rate was 6.1%, and R2 rate was 0% compared to a ICG positive resection margin with a R0 rate of 64.3%, R1 rate of 21.4%, and R2 rate of 14.3% (p=0.005). One and two year overall survival were 95.2% and 88.4%, respectively. Conclusion The here presented study provides significant evidence that ICG NIRF guidance helps to identify R0 resection intraoperatively. This offers a true potential to verify radical resection and improve patients´ outcome. Furthermore, implementation of NIRF guided imaging in liver tumor surgery allows to detect a considerable amount of additional malignant lesions.

Tree ordinances can be an effective means of preserving urban forests in the face of development pressures. Despite this, they also have the potential to be divisive among the public - especially when applied to privately-owned land. In this study we surveyed 1,716 Florida urban residents to understand how they value regulation and management of the urban forest. Specifically, we asked about: tree protection ordinances, incentive programs to manage or plant trees, justification for tree removal, and development. Most respondents supported tree protections, even when applied to trees on their own property or when they had the potential to limit development activities. Additionally, there was limited support for removing healthy trees for development. Respondents supported the use of funds for urban forestry efforts – particularly at the local or state level.

The Green Deal for Europe aims to achieve climate neutrality by 2050 and sets a binding EU target of a 55% reduction in greenhouse gas emissions by 2030 compared to 1990 levels. The contributions of EU Member States to this target will be partly determined by the market through the EU Emissions Trading Scheme. For the remaining part of greenhouse gas emissions outside the EU Emissions Trading Scheme, the Effort Sharing Regulation sets binding national reduction targets. The paper applies an energy optimization model to analyze the ability of the Czech Republic to meet the climate targets. Given the high level of GHG emissions in 1990 and the significant reduction of GHG emissions in the 1990s, Czechia could achieve a 55% reduction by 2030. However, further decarbonization will be quite challenging.

The management of urban water has evolved from single-function systems to more sustainable designs promoting society and nature as inputs to engineer novel infrastructure. In transdisciplinary research, co-design refers to a design thinking strategy in which people jointly frame a problem-solution. This article presents a conceptual framework to assess a case study focusing on the process of co-design and implementation of green infrastructure as a prototype for stormwater management. The evaluation is carried out from a self-reflective post-implementation perspective. Research activities are translated into the framework to evaluate conditions shaping the trajectory of the prototype. As a result, key aspects driving the research regarding levels of stakeholder participation and dimensions of power are identified. Planning resilient co-design strategies to retrofit urban spaces is necessary to avoid unintended consequences, especially at the initial experimental stages. This study aims to contribute to the continuous improvement of pilot strategies in urban spaces by providing a framework for a structured evaluation of research experiences.

With increasing constraints on energy and resource markets and the non-decreasing trend in energy demand, the need for relevant clean energy generation and storage solutions is growing and is gradually reaching the individual home. But small-scale energy storage is still an expensive investment in 2022 and the risk/reward ratio is not yet attractive enough for individual homeowners. One solution is for homeowners not to store excess clean energy individually but to produce hydrogen for mutual use. In this paper a collective production of hydrogen for a daily filling of a bus is considered. Following our previous work on the subject, the investigation consists of finding an optimal buy/sell rule to the grid, and the use of the energy with an additional objective: mobility. The dominant technique in the energy community is reinforcement learning, which is however difficult to use when the learning data is limited as in our study. We chose a less data-intensive and yet technically well-documented approach. Our results show that rulebooks, different but more interesting than the usual robust rule, exist and can be cost-effective. But they require fine-tuning as to not deteriorate system performance. In some cases, it is worth missing the H2 production requirement in exchange for higher economic performance.

Reaching the land-related UN-Sustainable Development Goals (SDGs) and similar goals articulated by the EU-Green Deal (GD) by 2030 presents a major challenge and requires a pragmatic approach to be focused on joint learning by land users (mostly farmers), researchers and other stakeholders in “Living Labs” and system experiments at experimental farms of research organizations. Defining specific indicators and thresholds for ecosystem services in line with land-related SDGs, are crucial to establish: “Lighthouses” that can act as inspiring examples if they meet the various thresholds. This exploratory paper discusses indicators and thresholds for an arable farm operating on marine, calcareous light clay soils in the Netherlands. Studies of a system experiment are used to discuss and test operational methodology to be widely applied when characterizing many “Living Labs” in future as planned by the European Union. The important role of soils, contributing to ecosystem services, is discussed in terms of soil health. Recommendations are made for innovative methodology to be associated with all land-related SDGs. Satisfying thresholds of ecosystem services, that will vary by soil type, region and farm-type, can be the basis for farm subsidies such as the Common Agricultural Policy (CAP). Research on Living Labs and in system experiments has to be judged by different criteria than those associated with traditional linear research. Important contributions by soils to achieve ecosystem services are framed in terms of soil health and are the most effective way to promote soil science in a by now widely desired inter- and transdisciplinary context.

Global temperature rise due to hydrocarbon gases emission that are produced by generating the electrical power has a great attention by the researchers to reduce it till zero emission is successfully achieved. Sustainable energy source such as solar energy, wind, hydro-energy and sea wave energy are focal areas to replace the fossil fuel by clean energy. In this article, daylight is used to minimize the power consumption that required for indoor lighting using electric roller blind. Smart controller is designed to adjust the position of the roller blind stepper motor, and hence, adjust the roller blind opening, based on the preset light intensity, to achieve precise utilization of daylight inside the room. If the desired Lux is not achieved for any reason, the smart controller adjusts the LED circuit current to boost the light intensity to achieve precisely the desired Lux. Comprehensive test cases using MATLAB-Simulink is carried out to verify the performance of the proposed smart controller. Techno-economic analysis is introduced to evaluate the benefits of installing the controller. Summary and recommendation are given at the end.

Graphene is a remarkable material with numerous applications. Due to its thin and lightweight design, it is ideal for a variety of applications. The synthesis of high-quality graphene in a cost-effective and environmentally friendly manner continues to be a significant challenge. Chemical reduction is considered to be the most advantageous method for preparing reduced graphene oxide (rGO). However, this process necessitates the use of toxic and harmful substances, which can have a detrimental effect on the environment and human health. Thus, to accomplish the objective, the green synthesis principle has prompted researchers worldwide to develop a simple method for green reduction of graphene oxide (GO), which is readily accessible, sustainable, economical, renewable, and environmentally friendly in nature. For example, the use of natural materials such as plants is generally considered safe. Furthermore, plants contain reducing and capping agents. The current review will focus on the discovery and application of rGO synthesis using extracts from a variety of different parts of the plant. The review aims to aid current and future researchers in their search for a novel plant extract that acts as a reductant in the green synthesis of rGO. The review aims to assist current and future researchers in their research for a novel plant extract that acts as a reductant in the green synthesis of rGO as well as their potential applications in a variety of industries.

As urban development increases in density, the space to grow urban trees becomes more constrained. In heavily developed areas, small stature trees can be planted to reduce both above- and below-ground conflicts with infrastructure elements. However, even these species have their limits when placed in extremely confining conditions. In this study, we build on past work to determine the minimum planting widths of small stature urban trees. We found that species, stem diameter, and the height at which stem diameter measurements occurred were all strong predictors of trunk flare diameter (adjusted R² of 0.843). Additionally, we modelled the relationship between planting space and the presence or absence of hardscape conflicts – using the predictions derived from this effort to project the potential cost savings in two United States cities. Study results provide a guideline to create sufficient space for urban trees and minimize infrastructure damage and associated cost savings.

This study investigates optimal decisions in a green supply chain consisting of a manufacturer and a leading retailer considering the green marketing and fairness preferences of member firms. Four Stackelberg game decision models are constructed in which the manufacturer and the re-tailer engage in green marketing separately when the manufacturer has no and has fairness preferences. The impacts of fairness preferences and green marketing on the optimal decision in the green supply chain are comparatively analyzed. The study finds that member firms perform green marketing regardless of the presence or absence of fairness preferences and that such be-havior increases the wholesale price, retail price, and market demand of low-carbon products as well as the profits of member firms and the supply chain. A more interesting finding is that the profit growth of member firms and the supply chain due to the manufacturer’s green marketing is more pronounced than that due to the retailer’s green marketing. When the retailer and the manufacturer engage in conduct green marketing, the manufacturer's fairness preferences have different effects on the wholesale price, retail price, market demand, level of green marketing efforts, member enterprises and profits of supply chain. Therefore, firms should consider the impact of green marketing and fairness preferences to make pricing and performance decisions, so as to achieve efficient operation of the whole supply chain and avoid double marginal effects. Finally, the above conclusions are verified through numerical simulation, providing a reference for the decision-making of member firms in the green supply chain.

Removing one key barrier to the industrial uptake of green chemistry and nanocatalysis in the fine and specialty chemical industry requires to fill an ongoing “talent shortage” via expanded chemistry education. In this study we show how the use of hybrid sol-gel catalysts to synthesize fine chemicals and active pharmaceutical ingredients in flow chemistry reactors illustrates new ideas to reshape chemistry education based on recent research outcomes, visualization and digital tools. Several lessons learned from the industrial and academic utilization of these materials in continuous-flow conversions conclude the study.

In recent years, many researchers have begun to shift their focus onto the synthesis of nanomaterials as this field possesses immense potential that may provide incredible technological advances in the near future. The downside of conventional synthesis techniques, such as co-precipitation, sol-gel and hydrothermal methods, is that they necessitate the use of toxic chemicals, produce harmful by-products and require a considerable amount of energy; therefore, more sustainable fabrication routes are sought after. Biological molecules have been previously utilised as precursors to nanoparticle synthesis, thus eliminating the negative factors involved in traditional methods. In addition, transition-metal nanoparticles possess a wide scope of applications due to their multiple oxidation states and large surface areas; thereby allowing for a higher reactivity when compared to their bulk counterpart and rendering them an interesting research topic. However, this field is still relatively unknown and unpredictable. Therefore, this review aims to obtain a better understanding on the plant-mediated synthesis process of the major transition-metal and transition-metal oxide nanoparticles, and how different parameters affect their unique properties.

A renewable cyclic monoterpene obtained from citrus peel, limonene is widely used as a fra-grance, nutraceutical ingredient, antibacterial, biopesticide, and green extraction solvent. Indus-trial demand largely exceeds supply. After reviewing recent advances in the recovery of limonene from citrus peel and residues with a particular attention to benign-by-design extractive processes, we focus on the latest results in its dehydrogenation to p-cymene via heterogeneous catalysis.

This scoping study aims to explore the relationships between urban green spaces (UGSs) and cancer. We followed the PRISMA extension for scoping reviews (protocol published in 2018). Eligibility criteria for papers were: 1) to be concerned with UGSs, 2) reporting effects of UGSs on cancer-related outcomes including direct or indirect measures, 3) reporting randomized controlled trials, prospective cohort studies, case studies, observational studies, non-comparative studies, 4) in English or French. The search covered primary studies in the published and unpublished (grey) literatures searching by hand and electronic databases (MEDLINE, Green File, CINAHL and ScienceDirect). Among 1703 records screened by two reviewers independently, 29 were included for qualitative synthesis. We classify the cancers concerned and the effects reported i.e. protective effect, risk or without association. The most investigated cancers are bladder, breast and lung cancer. Our study also identified contributing factors and their mediating effects between UGSs and cancer. Results highlight the wide variety of possible mediating factors between the use of green spaces and cancer occurrence, remission and/or prevention. Knowledge gaps and future research perspectives should be oriented to qualitative research on protective factors, the role of mental health in recovering from cancer and health inequalities.

In this changing world, we all are surrounded by the surmountable risk of getting injured. Amongst various risk factors, major burns are the most distressing and catastrophic. Burn wounds are not easy to heal via natural healing process and ultimately ended up with scar formation. If the degree of burn is high then the loss of tissue and its function is very common. To fasten-up the natural burn wound healing; zinc, an essential trace element is found to be very much effective. But due to its’ particle size limitation, less contact with wounded cells and tissues, and high inherent toxicity restrict its use. Needlessly, zinc is an element with dual action i.e. both antimicrobial and wound healing it is a prime choice to apply its aptitude in burn wound healing. To overcome the documented limitations zinc has converted to nanoparticle form. Zinc oxide nanoparticles, in particular, have attained ample of interest due to their unique properties and potential antimicrobial activity along with wound healing activity which makes it promising for the healing of topical burn wounds. Plant mediated green synthesis of nano-metal oxide particles is gaining a lot of significance due to its simplicity, eco-friendliness and extensive antimicrobial activity and recommended as an appealing substitute to not only physical methods but also chemical methods avoiding the use of the high rate of toxic chemicals and extreme surroundings. This study includes ZnO NPs role in burn wound healing with Phyto-mediated synthesis methods to provide evidence of their potential applications. Additionally, it provides an overview of traditional methods used for the synthesis of ZnO nanoparticles and characterization techniques to obtain information concerning the size, shape and optical properties along with toxicity and safety concern of ZnO NPs and its biomedical applications.

The paper presents a synthesis of deep eutectic solvents (DESs) based on choline chloride (ChCl) as hydrogen bond acceptor and phenol (Ph), glycol ethylene (EG), and levulinic acid (Lev) as hydrogen bond donors in 1:2 molar ratio. DESs were successfully used as absorption solvents for removal of dimethyl disulfide from (DMDS) from model biogas steam. Several parameters affecting the absorption capacity and absorption rate has been optimized including kind of DES, temperature, the volume of absorbent, model biogas flow rate, and initial concentration of DMDS. Furthermore, reusability and regeneration of DESs by means of adsorption and nitrogen barbotage followed by the mechanism of absorptive desulfurization by means of density functional theory (DFT) as well as FT-IR analysis were investigated. Experimental results indicate that the most promising DES for biogas purification is ChCl:Ph, due to high absorption capacity, relatively long absorption rate, and easy regeneration. The research on the absorption mechanism revealed that van der Waal interaction is the main driving force for DMDS removal from model biogas.

Phloem-feeding insects strive to offset the disadvantageous effects of stressors to sustain their offspring and survive. Adaptive responses to environmental stress are not well understood under complex influences of companion planting, natural enemies, and host gradient. In this study, under predation by lacewing Chrysoperla carnea Stephens (Neuroptera: Chrysopidae), we survey the responses of green peach aphid Myzus persicae Sulzer (Hemiptera: Aphididae), reared on different densities of cabbage Brassica oleracea L. (Brassicales: Brassicaceae) to its shallot companion Allium cepa (L.) var. aggregatum G. Don (Asparagales: Amaryllidaceae). Firstly, aphid aggregative abundance was strongly influenced by shallot perturbation, predator presence and changes in cabbage-host biomass, altering aphid phenotypic plasticity. Interestingly, the shallot and predation negative impacts can be of similar magnitudes. Secondly, changes in the cabbage-host availability and biomass, especially under predation, had a strong impact on aphid traits. Our study underscores the benefits of including shallots as crop-companions in augmenting pest control, but also suggests that the outcome of coupling companion planting with natural enemies is context-dependent and thus should be empirically applied. At the confluence of ecology and agronomy, this work provides insights on how manipulated functional biodiversity may function as an alternative strategy for pestilent herbivory management in model and green-house systems.

In the year 2017, about 89 percent of the total energy consumed in the US was produced using non-renewable energy sources, and about 43 percent of tenant households were cost-burdened. Local governments are in a unique position to facilitate green affordable housing that could reduce cost burdens, environmental degradation, and environmental injustice. Nonetheless, limited studies have made progress on costs and benefits of green affordable housing to guide decision-making, particularly in small communities. This study investigates density bonus options for green affordable housing by analyzing construction costs, sale prices, and spillover effects for green certifications and affordable housing units. The authors employ construction costs and sale data from 422 Low-Income Housing Tax Credit (LIHTC) projects and 11,418 Multiple Listing Service (MLS) transactions in Virginia. Using hedonic regression analyses controlling for mediating factors, we find that the new construction of market-rate green certified houses is associated with small upfront costs but large and statistically significant price premiums. The construction of market-rate green certified houses has large and statistically significant spillover effects on existing non-certified houses. Existing non-certified affordable housing units show small and statistically insignificant negative price impacts on transactions of surrounding properties. The magnitude of social benefits associated with green building justifies the local provision of voluntary programs for green affordable housing where housing is expensive relative to its basic costs of production to promote sustainable development.

The exploitation and use of alternative synthetic methods, in the face of classical procedures that do not conform to the ethics of Green Chemistry, represent an ever present problem in pharmaceutical industry. The procedures for the synthesis of benzimidazoles have become a focus in synthetic organic chemistry, as they are building blocks of strong interest for the development of compounds with pharmacological activity. Various benzimidazole derivatives exhibit important activities such as antimicrobial, antiviral, anti-inflammatory and analgesic and some of the already synthesized compounds have found very strong application in medicine praxis. Here we report a selective and sustainable method for the synthesis of 1,2-disubstituted or 2-substituted benzimidazoles, starting from o-phenylenediamine in the presence of different aldehydes. The use of deep eutectic solvent (DES) both as reaction medium and reagent without any external solvent provides advantages in terms of yields as well as in the work up procedure of the reaction.

Sustainable development (SD) is essential to reduce and mitigate climate change impacts, environmental deterioration and to increase social sustainability. SD is therefore highly relevant for the engineering profession and is today found integrated with the higher education of specific engineering programs. This paper investigated the knowledge of SD for students entering the master’s program in Sustainable Building Information Management (BIM) by comparing levels of knowledge at the start and end of the first course Sustainability, Analyses and Simulations. The level of knowledge of SD was analyzed by classifying students’ conceptions of sustainability using SOLO taxonomy and the spectrum of liminality and the threshold concept. Students written responses to the question “What do you know about sustainability?” and written group project reports were used for analyzing levels of knowledge of SD. Levels of knowledge of SD was classified as pre (pre-liminal or pre-structural); uni-structural, multi-structural, relational and post-stages (extended abstract or post-liminal). In total, 68% of the students entering the master’s program in 2017 and 88% in 2018 showed a pre-structural, uni-structural and multi-structural SD knowledge. In general, few students entering the program showed relational and post-stages of SD knowledge, 32% and 12% of the students in 2017 and 2018, respectively. The students at the post-stage were able to express themselves more individually and creatively compared to previous levels in that they could connect the dimensions of SD to the context of SD of buildings, but also argue why SD of buildings was important and they could also suggest actions or tools for improved SD that engineers should use. Only one group of five (in 2017) showed a post-stage level of knowledge in the group project report. It is likely that the student’s general approach to the work with the reports was to mainly cope with the course requirements which is a sign of surface approach to learning. It, therefore, seems reasonable that future developments of the course should ensure that the students use the scientific literature in their group project reports to make it easier for them to understand the relationship between software use and the connection to green buildings certificate systems and SD of buildings. By making it mandatory to include scientific literature in the reports the students will be encouraged to read and think critically, and deeper, and to put the practical implementation of the software analysis results into a scientific context of SD and BIM.

Global waste generation keeps increasing over the year and requires innovative solutions to minimize their impacts on environmental quality and public health. Predicted 2.2 billion tonnes per year of global municipal waste generation in the year 2025 which 1.6 fold is higher than in 2012. Hence, a strategic plan must be ascertained to overcome the future challenges of MSW locally and globally. Universiti Putra Malaysia (UPM) coined an initiative to demonstrate a showcase pilot plant for green energy production from MSW. Therefore, the data was obtained from the survey and actual sampling within the UPM compound to estimate the MSW generated and it's potentially used for green energy production. It is estimated that 5.0 – 7.0 tonne per day of MSW generated which about 30 - 35% is an organic fraction. Upon separation, the organic fractions were digested into biogas through anaerobic. At the maximum conversion of organic fraction, about 775 kWh of electricity may able to generate from the waste. In this study, the complete biorefinery setup and utilize organic components from the MSW generated in UPM was proposed that the biogas subsequently will be used to produce green energy in the form of electricity or cooking fuel.

The number of green buildings has increased to address the global environmental crisis. However, green buildings face risks resulting from new materials and methods. In addition, these buildings are expected to perform at higher levels than traditional ones. The objectives of this study are to identify the possible risk factors for architects developing green building projects in South Korea and to assess risk mitigation measures. To attain this goal, fourteen risk factors and twelve mitigation measures were identified from a comprehensive literature review. A questionnaire survey was administered to architects practicing green building design. Findings revealed the ‘adoption of new technology and processes’ was the largest difference between green and traditional building projects. This study identified ‘financial risk,’ ‘design changes,’ and ‘client’s goal uncertainty’ as the top three risk factors in green building design. Additionally, the survey proposed the four most effective risk mitigation measures for green building projects: (1) ‘contract indicating each party’s roles, liabilities and limitations clearly’; (2) ‘utilizing integrated design process’; (3) ‘understanding client’s goal in green building projects’; and (4) ‘improving communication and coordination among stakeholders.’ There are a few studies focusing on the architects’ perceived risk concerning green building projects; however, this study expands the knowledge and fills the literature gap. Additionally, this study provides a comprehensive understanding of critical risks and mitigation measures that can benefit South Korea’s green building design practice through better risk management.

Green Tea Catechins (GTCs) are a family of chemically related compounds usually classified as antioxidant molecules. Epidemiological evidences, supported by interventional studies, highlighted a more than promising role for GTCs in human Prostate Cancer (PCa) chemoprevention.In the last decades many efforts have been made to gain new insights into the mechanism of action of GTCs. Now it is clear that GTCs anticancer action can no longer be simplistically limited to their direct antioxidant/pro-oxidant properties. Recent contributions to the advancement of knowledge in this field have shown that GTCs specifically interact with cellular targets including, cell surface receptors, lipid rafts and endoplasmic reticulum, modulate gene expression through direct effect on transcription factors or indirect epigenetic mechanisms, interfere with intracellular proteostasis at various levels. Many of the effects observed in vitro are dose and cell context dependent and take place at concentration that cannot be achieved in vivo.Poor intestinal absorption together with an extensive systemic and enteric metabolism influence GTCs bioavailability through still poor understood mechanisms. Recent efforts to develop delivery systems that increase GTCs overall bioavailability, by mean of biopolymeric nanoparticles, represent the main way to translate preclinical results in a real clinical scenario for PCa chemoprevention.

Exposure to malachite green (MG) may pose great health risks to humans, thus it is of prime importance to develop fast and robust methods to quantitatively screen the presence malachite green in environment. Herein application of extractive electrospray ionization mass spectrometry (EESI-MS) has been extended to the trace detection of MG within lake water and aquiculture water, due to the intensive use of MG as biocide in fisheries. This method has the advantage of obviating offline liquid-liquid extraction or tedious matrix separation prior to the measurement of malachite green in native aqueous medium. The experimental results indicate that the extrapolated detection limit for MG was ~3.8 ug L-1 (S/N=3) in lake water samples and ~ 0.5 ug L-1 in ultrapure water under optimized experimental conditions. The signal intensity of MG showed good linearity over the concentration range of 10–5000 ug L-1. Measurement of practical water samples fortified with MG at 0.01 and 0.1 mg L-1 gave a good validation of the established calibration curve. The average recoveries of malachite green in lake water and Carassius carassius fish farm effluent water were 114.9% (6.6% RSD) and 85.4% (9.2% RSD), respectively. Overall, the established EESI-MS/MS method has been demonstrated suitable for sensitive and rapid (<2 min per sample) quantitative detection of malachite green in various aqueous media, indicating its potential for online real-time monitoring of real life samples.

Thin twin-roll cast strips from a model Al-Cu-Mg-Li-Zr alloy with a small addition of Sc were prepared. A combination of a fast solidification rate and a favorable effect of Sc microalloying impacts the size and distribution of primary phase particles and the dimension of eutectic cells. Small interdendritic spacing in the range of 10-15 um enables substitution of the initial long-term homogenization annealing by a two-step annealing at 300 and 450 °C and a short solution treatment at 530 °C before quenching and the final age-hardening procedure. A dense dispersion of small Al3(Sc,Zr) precipitates intensively inhibiting recrystallization forms during this treatment. Further refining and fragmentation of the structure were performed using constrained groove pressing before the solution treatment. Small pre-straining of quenched specimens and subsequent age-hardening simulating T8 temper were used to promote the formation of a homogeneous distribution of strengthening particles and to suppress preferential heterogeneous precipitation on subgrain and grain boundaries. Microstructural features and microhardness evolution during annealing were critically examined and confronted with microstructural characteristics observed on reference mold cast alloy or alloys without Sc alloying. The proposed treatment represents a model near net shape procedure for manufacturing thicker sheets for the aerospace industry.

Zinc cobalt oxide-zinc hydroxide (ZnCo2O4-Zn(OH)2) microspheres were successfully fabricated on carbon cloth via a sample hydrothermal method. The surface morphology of these microspheres and their efficacy in degrading methyl violet were further modulated by varying the thermal annealing temperatures. The manipulation of thermal annealing temperatures was pivotal in adjusting the porosity of ZnCo2O4-Zn(OH)2 microspheres to amplify their photocatalytic performance. Various analytical techniques were utilized to evaluate the physical and chemical properties of the ZnCo2O4-Zn(OH)2 microspheres, including field-emission scanning electron microscopy, energy-dispersive spectroscopy, X-ray diffraction, field-emission transmission electron microscopy, X-ray photoelectron spectroscopy, and UV-vis spectroscopy. Compared to untreated ZnCo2O4-Zn(OH)2 microspheres, those subjected to thermal annealing exhibited increased specific surface area and light absorption capacity, rendering them highly effective photocatalysts under UVC light exposure. Subsequent studies have confirmed the superior performance of ZnCo2O4-Zn(OH)2 microspheres as a reusable photocatalyst for degrading methyl violet and tetracycline. Additionally, trapping experiments during the photodegradation process involving ZnCo2O4-Zn(OH)2 microspheres have identified hydroxyl radicals (·OH) and superoxide radicals (·O2–) as the primary reactive species.

Sustainable urban drainage systems (SuDS) such as swales are designed to collect, store and infiltrate a large amount of surface runoff water during heavy rainfall. Stormwater is known to transport pollutants, such as particle-bound Potential Toxic Elements (PTE), which are known to often accumulate in the topsoil. A portable XRF instrument (pXRF) is used to provide in situ spatial characterization of soil pollutants, specifically lead (Pb), zink (Zn) and copper (Cu). The method uses pXRF measurements of PTE along profiles with set intervals (1 meter) to cover the swale with cross-sections, across the inlet, the deepest point and the outlet. Soil samples are collected, and the In-Situ measurements are verified by the results from laboratory analyses. Stormwater is here shown to be the transporting media for the pollutants, so it is of importance to investigate areas most prone to flooding and infiltration. This quick scan method is time and cost-efficient, easy to execute and the results are comparable to any known (inter)national threshold criteria for polluted soils. The results are of great importance for all stakeholders in cities that are involved in climate adaptation and implementing green infrastructure in urban areas. However, too little is still known about the long-term functioning of the soil-based SuDS facilities.

Deep Learning (DL) and Machine Learning (ML) are widely used in many fields, but rarely used in Frequency Estimation (FE) and Slope Estimation (SE) of signals. Frequency and slope estimation for Frequency-Modulated (FM) and single-tone sinusoidal signals are essential in various applications, such as wireless communications, sonar, and radar measurements. In this work, artificial neural network (ANN) and convolutional neural network (CNN) are used in frequency and slope estimation for FM signals under Additive White Gaussian Noise (AWGN) and Additive Symmetric alpha Stable Noise (SαSN). SαS distributions are impulsive noise disturbances found in many communication environments like marine systems; their distribution lacks a closed-form Probability Density Function (PDF), except for specific cases, and infinite second-order statistic, hence Geometric SNR (GSNR) is used in this work to determine the impulsiveness of noise in a mixture of Gaussian and SαS noise processes. ANN is a machine learning classifier, designed with few layers for reducing FE and SE complexity while getting higher accuracy as compared with classical techniques. CNN is a deep learning classifier, designed with many layers for FE and SE, and proved to be more accurate than ANN when dealing with big data and finding optimal features. Simulation results show that SαS noise can be much more harmful for FE and SE of FM signals than Gaussian noise. DL and ML can significantly reduce FE complexity, memory cost, and power consumption, which is important in many systems such as some Internet of Things (IoT) sensor applications. After training DCNN for frequency and slope estimation of LFM signals, the performance of DCNN (in terms of accuracy) can give acceptable results at very low signal-to-noise ratios where TFD fails, giving more than 20dB difference in the GSNR working range.

We present a general theory of estimation of analysis error covariances based on cross-validation as well as a geometric interpretation of the method. In particular we use the variance of passive observation–minus-analysis residuals and show that the true analysis error variance can be estimated, without relying on the optimality assumption. This approach is used to obtain near optimal analyses that are then used to evaluate the air quality analysis error using several different methods at active and passive observation sites. We compare the estimates according to the method of Hollingsworth-Lönnberg, Desroziers et al., a new diagnostic we developed, and the perceived analysis error computed from the analysis scheme, to conclude that, as long as the analysis is near optimal, all estimates agree within a certain error margin.

This study investigates user behavior in urban green spaces (UGS) in downtown Shanghai prior to the COVID-19 pandemic. UGS are essential public infrastructure, contributing to urban sustainability, quality of life, and social cohesion. Although widely studied, there remains a gap in urban studies and environmental behavior research regarding UGS use from the perspective of space appropriation. This study addresses this by analyzing user demographics, frequency, and spatial activity patterns to assess how different forms of space use can be evaluated across varying levels of appropriation. Using a mixed-methods design, non-participant observation and behavior mapping were conducted across three comprehensive parks in Shanghai, divided into nine observation zones. Data were analyzed using the Pandas library in Python 3.6, descriptive statistics, and qualitative coding. Findings revealed sixty distinct activity types, predominance of elderly male users, absence of teenagers, and activity peaks in the early morning and late after-noon. Structured patterns of engagement suggest a soft to moderate level of appropriation. This research underscores the effectiveness of observational methods, validates appropriation as an analytical category, and emphasizes the importance of structured classification systems for improving understanding of UGS use and its societal role.

There is a growing awareness of the detrimental environmental impact of the construction industry, primarily due to the utilization of building materials that necessitate energy-intensive processes for their production. The objective of this paper is to explore whether mixing wood and cement could serve as a viable solution to mitigate this adverse environmental effect. The data was obtained by extensively investigating the Clarivate Web of Science database, adhering to the PRISMA technique guidelines, and subsequently processed using Bibliometrix and VOSviewer software. An in-depth critical analysis of the literature revealed a heightened interest in this subject matter in recent years, with the focal points evolving from initial experimental endeavors aimed at understanding the behavior of the innovative wood cement composites, primarily in terms of their mechanical properties, to assessing their environmental impact and the advantages associated with their use. The researchers suggest that optimal results can be achieved by treating the wood with tetraethyl orthosilicate, incorporating cellulose nanocrystal particles or wollastonite into the mixture, and utilizing wood from the Pinus species. Furthermore, it was discovered that a noticeable improvement in strength is only attainable if a low percentage of wood, up to 30%, when wood ash is employed. Ongoing research concerning wood and cement composites continues to progress, with regular advancements and breakthroughs, thus offering promising prospects for the development of superior and eco-friendly building materials.

Pd EnCat™ 30 is a palladium catalyst broadly used in several hydrogenation and cross-coupling reactions. It is known for its numerous beneficial features, which include high-yielding performance, easy recovery, and reusability. However, the available data regarding its recyclability in Suzuki coupling reactions are limited to a few reaction cycles and, therefore, fail to explore its full potential. Our work focuses on investigating the extent of Pd EnCat™ 30 reusability in Suzuki cross-coupling reactions by measuring its performance according to isolated yields of product. Our findings demonstrate that Pd EnCat™ 30 can be reused over a minimum of 30 reaction cycles, which is advantageous in terms of cost reduction and more sustainable chemical production.

AbstractLarge numbers of urban lakes are facing issues related to cyanobacteria, commonly known as blue-green algae, resulting in significant threats to humans and animal health due to their production of microtoxins and Anatoxin-A. These toxins induce acute effects including gastrointestinal distress, and respiratory problems, underscoring the need to protect urban lakes to safeguard community health and ecosystem well-being. A comprehensive monitoring program is a critical step to address cyanobacteria-related issues. Monitoring results of dissolved phosphorous, nitrates(N), Total Kjeldahl Nitrogen (TKN), total phosphorous (TP), TSS, and Escherichia coli (E. coli) concentrations, are used to understand the importance of different pathways events during dry conditions (no prior rainfall) and wet events (rainfall during or proceeding monitoring events) plus a microbial source tracking procedure, to understand impacts on growth characteristics of cyanobacteria and microtoxins. The Mann-Kendall Trend Test is used to characterize trends of various parameters (using transitions of ‘wet’ and ‘dry’ to the Lake and within the Lake), to identify the impact of various management strategies and/or the impact of various sources from overland land uses for a) wet events to the Lake, b) dry events to the Lake, c) wet events in the Lake, and d) dry events within the Lake. Microbial source tracking methods are used along the shoreline of Fairy Lake to interpret elevated levels of fecal pollution and E. coli bacteria in water samples, aiding in the identification of pollution sources. Blue-green algae have been observed at least once each year from 2018 to 2023. Microtoxins and Anatoxin-A were present in nine samples with a maximum of 1.72 mg/L and 0.02 mg/L, respectively. Frequent beach closures have occurred every year, raising public concerns regarding both ecological and recreational aspects for Fairy Lake.

Green finance in the context of sustainable development sits within the broader discourse of environmental economics and sustainable finance. Their integration has become imperative in addressing global challenges, aiming to understand how financial mechanisms can be aligned with sustainability goals, investigating the role of green finance in promoting environmentally friendly investments and fostering sustainable development. This bibliometric analysis explores the evolution, trends, and challenges in green finance research. It examines 436 articles published between 2016 and 2024, revealing insights into influential publications, authors, journals, institutions, and countries engaged in green finance for sustainability. The study identifies China, the UK, and Pakistan as leaders in research output and citation impact. Furthermore, it highlights the interdisciplinary nature of green finance, reflected in diverse publication outlets spanning environmental, social, and economic domains. The analysis underscores the increasing global interest in green finance, as evidenced by the growing citation rates over time. Key findings include the pivotal role of green finance in energy efficiency, renewable energy development, and the promotion of sustainable economic growth. Overall, this research provides valuable insights for policymakers, researchers, and practitioners, emphasizing the importance of interdisciplinary collaboration and continued research efforts in advancing sustainable finance agendas.

Recently, environmental degradation has become an international issue due to the extensive economic activities around the globe. This aspect demands the policymakers' and new researchers’ emphasis. Hence, the present article examines the impact of corporate social responsibilities (CSR) to community and environment on the environmental performance (ENP) of the manufacturing industry in China. The article also investigates the mediating role of green innovation and environmental strategy among CSR to community, CSR to environment and ENP of manufacturing industry in China. The article gets the primary data from the selected employees of the manufacturing industry using questionnaires. The article also tests the data's validity and reliability, and association among variables using smart-PLS. The outcomes indicated that CSR to environment has a positive association with ENP. The outcomes also revealed that green innovation and environmental strategy significantly mediate among CSR to community, CSR to environment and ENP. The article guides the policymakers in making policies related to improve ENP using CSR to environment and green innovation.

Green and low-carbon development has become an important embodiment of China's path to becoming a strong agricultural country. How to enable agricultural enterprises to better adopt green technologies and conduct production and operation with the concept of sustainable development has become a key link. This article utilizes a structural equation model (SEM) to analyze the role paths and mediating effects of organizational learning ability and policy orientation in agricultural enterprises' market orientation and willingness to adopt green technologies[ The definition of green technology in this paper refers to Guo Kesha, Tian Xiaoxiao. Green technology and green transformation of industrial development mode [J]. Tianjin Social Sciences, 2024 (02) :99-107, including green manufacturing (production) technology and green service technology.]. The results show that market orientation, organizational learning ability, and policy effectiveness have significant direct positive impacts on the willingness to adopt; market orientation has a significant positive impact on agricultural enterprises' organizational learning ability, organizational learning ability has a significant positive impact on policy orientation, and market orientation has a significant positive impact on policy effectiveness; the results of mediation analysis also indicate that learning ability has a significant mediating effect between market orientation and willingness to adopt, and policy effectiveness has a significant mediating effect between market orientation and willingness to adopt. Through difference analysis, it is believed that the mediating effects of the three paths are equally important, and organizational learning ability and policy effectiveness play a partial mediating role in agricultural enterprises' willingness to adopt green technologies. Based on this, policy suggestions are proposed to improve enterprises' own organizational learning ability, increase the promotion of policies related to green technologies, improve relevant policies for the application of green technologies, and increase research and development efforts for green technologies.

The spatial segregation is a characteristic of Latin American cities, resulting in distinct dynamics of social inclusion and exclusion at both spatial and identity levels. Then, specific green spaces may convert into appreciated and contested territories, where various actors negotiate their uses and regulations. Considering a case-study in a green icon of the metropolitan city of Santiago de Chile, the main objective of the present study was to describe and comprehend the uses and meanings of the Quebrada Macul park among different social groups over the past two decades. We employed qualitative methods including six in-depth interviews with key informants (social and ecological leaders, historical neighbors, and park workers), five participant observations in the park, and statistical analysis of visitors. Results reveal that (1) the transition of being a popularly used hill to a metropolitan park rises tensions between public and private statuses of place; (2) conflicts emerge regarding who uses the space and how, reflecting power dynamics among different social groups; (3) the park, beyond being a public space, holds significant identity value for its historical residents, both for those who fought for its recovery and those who have lived closely, so processes of forgetfulness might be resentful. We conclude on enduring meanings of the park associated with the struggle for the place among different groups, highlighting the role of memory for the social integration of groups among natural spaces.

In politics and society, organic farming is widely seen as the ideal way to address the many challenges facing agriculture and food security. In order to examine the extent to which this view is realistic, the impact of organic and conventional farming is compared on the basis of relevant criteria such as land requirements, greenhouse gas emissions, biodiversity, food quality, production and environmental costs, reduced meat consumption, the need for agricultural imports and the global expansion of arable land. Land is considered to be a central factor. Such a comprehensive analysis is necessary to assess the impact of different influencing factors and to provide important suggestions for targeted decision making. Although organic farming has a positive impact on land use in many ways, it quickly reaches its limits. The low yields and high production costs resulting from the limited choice of means of production make organic farming an unsuitable model for the future in a world with limited arable land, a high and growing demand for food, and low incomes for large sections of the population. It can, however, provide significant impetus and contribute important technological knowledge for the further development of agriculture as a whole to meet the complex objectives of sustainability, greenhouse gas mitigation, biodiversity and global food security by incorporating all available technologies. Based on this, a model for responsible, sustainable intensive agriculture is outlined and proposals for an eco-social framework to support this model are put forward.

The European Green Deal is the policy established by the EU against global environmental problems. However, it is closely concerned with the countries carrying import and export activities with the EU. Because it is planned to impose an obligation to declare greenhouse gas emission inventories of products imported into the EU, the EU will soon begin to assess the CBAM on imports from carbon-intensive industries. This regulation is expected to affect Turkey-EU trade relations. One of the industries that Turkey has export relations with the EU is the building materials industry. For this reason, it will have had necessary to provide sustainability criteria for the export of building materials. However, there is no database in Turkey where the inventory data of building materials is declared. In Turkey, within the scope of EU Green Deal action plans, it is aimed to create different structures for environmental information of building materials in the medium and long term. In light of such information, within the scope of this study it is aimed to create reference information for building material databases to be developed in Turkey. The study recommends weight and normalization reference values following the life cycle assessment methodology defined by ISO 14040 and ISO 14044 international standards. Twelve environmental impact categories accepted in the literature, including greenhouse gas emissions, have been considered as the environmental impacts of building materials. Semi-structured interviews were held with twenty-one industry stakeholders in Tur-key to determine the weight reference values. The results obtained from the semi-structured interviews were combined using the AHP method. An extensive research study was conducted on Turkey’s national inventory data to determine normalization reference values. Environmental impact calculations were carried out for different building materials in a case study to present the importance of regional adaptation of the determined reference values. The recommended reference information may be used in greenhouse gas emission declarations under the EU Green Deal and other potential environmental impact declarations from building materials.

The growth of the wind power sector has been marked by environmental, economic, and political drivers. Its starring role is also visible in the emergence of the so-called “green jobs”. Notwithstanding, its evolution ought not to compromise issues related to occupational risks. This exploratory study examines psychosocial risks in the operation and maintenance of onshore wind turbines in a leading Portuguese company. We conducted interviews with main stakeholders (Human Resources, OHS professionals, and team leaders); developed an “activity diary” for the operation and maintenance technicians to describe their activity and perceived impacts on health, complemented with collective interviews; and applied the Work and Health Survey. The results revealed particular risks and health impacts: working under adverse weather conditions; working at heights and in confined spaces; spending long work hours inside of the nacelles to achieve an optimum balance between favorable wind slots to intervene and avoiding additional trips up and down the wind turbines without lifts (70m-120m); and the feeling of early ageing. At a time when these workers are striving for recognition of their profession as a “rapid wear profession”, it is a key moment to discuss these results to guarantee sustainable conditions for future generations of workers.

The objective of this study is to evaluate how two varying amounts of sepiolite-based powder, infused with indigo extract, affect the appearance and durability of a water-based white primer. To examine the influence of this eco-friendly pigment on the coatings' overall appearance, assessments were performed for color, gloss, and surface roughness. Additionally, the coatings were investigated through optical and electron microscopic observations, to evaluate the distribution of the pigment within the polymer matrix. The effect of the pigment on the coating's durability was assessed through accelerated tests, including exposure in a salt spray chamber and a UV-B chamber. These tests aimed to evaluate the emergence of defects and changes in the appearance of the samples over time. Furthermore, the impact of different quantities of sepiolite-based powder on the coating's ability to act as a barrier was assessed using liquid resistance tests and contact angle measurements. These evaluations aimed to understand how the coating responded to various liquids and its surface properties concerning repellency or absorption. In essence, this study underscores the considerable influence of the eco-friendly pigment, demonstrating its capacity to introduce unique color and texture variations to the paint. Moreover, the inclusion of the pigment has enhanced the coating's color stability, its ability to act as a barrier, and overall durability when exposed to harsh environments.

Wound healing is rarely seen as a problem in healthy individuals; however, under certain pathophysiological conditions, this process can be impaired, leading to the emergence of chronic wounds, which are themselves a serious public health problem. This work aimed to review the most important and recent literature on the use of metallic nanoparticles, in this case those produced from plant extracts, and their application as healing agents. For this, we firstly provided an insight into the pathophysiology of the wound healing process and then the main routes for obtaining metallic nanoparticles. The methodology of synthesis, which is part of the so-called green synthesis, has been the subject of several studies reporting the use of medicinal plants as subtracts for the production of different nanoparticles (of silver, gold, and zinc). Additionally, their use as wound healing agents is close related with biological properties such as antimicrobial, anti-inflammatory, and healing. Finally, we addressed in vitro and in vivo studies reporting the efficiency of metallic nanoparticles synthesized with plant extracts and applied in different pharmaceutical forms on the wound healing process. Based on these satisfactory results, we verified that metallic nanoparticles are potential therapeutic alternatives when compared to the traditional synthetic healing agents, thus foreseeing the production of new drugs in the pharmaceutical market.

Accelerating the green transformation of the economic development mode and promoting high-quality economic development is an international trend and the general direction. This article utilizes data from manufacturing companies listed on the Shanghai and Shenzhen stock exchanges from 2011 to 2021, based on dynamic capability theory, to explore the impact of enterprise digital transformation on green technological innovation. Furthermore, dynamic capabilities are further subdivided into absorptive capacity, innovative capacity, and adaptive capacity to investigate their mediating role. The research findings demonstrate that enterprise digital transformation has a significant positive impact on green technological innovation. Moreover, enterprise digital transformation positively influences the absorptive capacity, innovative capacity, and adaptive capacity, with these three factors playing a mediating role in the impact of enterprise digital transformation on green technological innovation. The results of the bootstrap test confirm this mediating effect. The conclusions of this study are validated through a series of robustness tests. This research not only provides theoretical support for the impact mechanism of digital transformation on green technological innovation but also offers practical insights for enterprises to achieve sustainable development.

The energy crisis is currently a major topic in scientific and managerial discussions in the building and construction industry. While employing low-cost strategies for reducing energy usage is beneficial for principals and decision-makers, the primary purpose of this study is to recommend the use of phase change materials (PCM) to improve cooling and heating load management in buildings. In order to accomplish this, the study applies design-builder simulations to a developing country case study. The results indicate that integrating PCM in buildings can reduce energy usage by around 6 percent. Although this value may be lower than other techniques, it is nevertheless important for reaching green building goals in both developed and developing nations. The case study, which takes place in a four-season region, demonstrates the significant potential of the PCM system for both cooling and heating energy management. In addition, the reciprocal performance improvement of PCMs is a remarkable characteristic, especially when contrasted to some conventional systems that focus on a single energy management objective in buildings. Lastly, it should be underlined that the suggested platform is consistent with Sustainable Development Goal 7 (Affordable and Clean Energy Targets).

Green synthesis using plant extracts has emerged as an eco-friendly, clean, and viable strategy alternative to chemical and physical approaches. The leaf, stem, and root extracts of Lannea discolor was utilized as a reducing and stabilizing agent in the synthesis of gold (AuNPs) and copper (CuNPs) nanoparticles. The formation of AuNPs and CuNPs confirmed by their color change, was characterised by UV–Vis Spectroscopy (UV- Vis), Scanning electron microscopy analysis and energy dispersive x-ray (SEM-EDX), Transmission Electron Microscopy (TEM), and Fourier Transform Infrared Spectroscopy (FTIR), coupled with minimum concentration inhibitory (MIC) antibacterial assays. AuNFs, NPs and CuNPs peaked at wavelengths in the ranges of 316, 544 and 564 nm respectively. TEM showed unexpected nanoflowers (30 – 97 nm) in the leaf extracts and spherical NPs (10 -33 nm; 9.3 – 37.5) from stem and root extracts, while spherical CuNPs (20 – 104 nm), were observed from all the extracts. EDX was able to confirm the presence of metal salts and FTIR revealed stable capping agents. AuNPs and NFs from L. discolor extracts showed appreciable antibacterial activity against Staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, Klebsiella pneumoniae and Bacillus subtilis, when compared to the plant extracts, while none was observed from the CuNPs. These AuNPs and CuNPs are particularly appealing in a variety of applications in the biomedical as well as conductivity manufacturing, due to their shapes and sizes and economical and environmentally friendly production.

A novel chemically cross-linked hydrogel was prepared through the utilization of the nor-bornene (Nb)-methyl tetrazine (mTz) click reaction, derived from carboxymethyl cellulose (CMC) and alginate (Alg). The hydrogel was designed to generate reactive oxygen species (ROS) from NIR-dye, indocyanine green (ICG) for a combined photothermal and photodynamic ther-apy (PTT/PDT). The cross-linking of Nb and mTz moieties occurred via an inverse elec-tron-demand Diels-Alder reaction under physiological conditions avoiding the need for a cata-lyst. The resulting hydrogels exhibited viscoelastic properties (G′ ~ 492-270 Pa) and high porosi-ty. The hydrogels were found to be injectable with tunable mechanical characteristics. The ICG encapsulated hydrogels demonstrated ROS generation ability under NIR exposure. The ROS production was investigated through DPBF assays to access photodynamic effect (with NIR irra-diation at 1-2W for 5-15 min). The temperature of the ICG-loaded hydrogels was also raised up-on the NIR irradiation to eradicate tumor cells photothermally. In vitro cytocompatibility as-sessments revealed the non-toxic nature of CMC-Nb and Alg-mTz towards HEK-293 cells. Fur-thermore, the ICG-loaded hydrogels effectively inhibited the metabolic activity of Hela cells following NIR exposure. This innovative hydrogel system holds promise for applications in combined PTT and PDT.

The article was devoted to topics related to the courier market, electromobility and renewable energy sources. This is the direction in which the car market is currently heading. The current situation of transport in Poland and the electrification trends of the courier market in Poland and beyond were presented and discussed. The article presents the conducted research and analyzes it for a selected company, which at the same time constituted the achievement of the goal and the solution of the research problem. Much attention was focused on conducting AHP analysis and simulating route changes for selected regions. The study contains an introduction and a summary discussing the most important conclusions.

Spatiotemporal climate variability is a leading environmental constraint to the rain-fed agricultural productivity and food security of communities in the Abbay basin and elsewhere in Ethiopia. The previous one-size-fits-all approach to soil and water management technology targeting did not effectively address climate-induced risks to rain-fed agriculture. This study, therefore, delineates homogenous climatic regions and identifies climate-induced risks to rain-fed agriculture that are important to guide decisions and selection of site-specific technologies for green water management in the Abbay basin. The k-means spatial clustering method was employed to identify homogenous climatic regions in the study area, while the Elbow method was used to determine an optimum number of the climate clusters. The k-mean clustering used the Enhancing National Climate Services (ENACTS) daily rainfall, minimum and maximum temperatures, and other derived climate variables that include daily rainfall amount, length of growing period (LGP), rainfall onset and cessation dates, and rainfall intensity, temperature, potential evapotranspiration (PET), soil moisture and AsterDEM to define climate regions. Accordingly, 12 climate clusters or regions were identified and mapped for the basin. Clustering a given geographic region into homogenous climate classes is useful to accurately identify and target locally relevant green water management technologies to effectively address local-scale climate-induced risks. The study has also provides a methodological framework that can be used in the other river basins of Ethiopia and indeed elsewhere.

Following on from work already carried out in our laboratory on a new biomass-derived green solvent, eucalyptol, we are now turning our attention to sabinene as a new green solvent. Sabinene is also derived from biomass. We have shown that it can be used as such or distilled to synthesize thiazolo[5,4-b]pyridine heterocycles by thermal or microwave activation. This new solvent was compared with various conventional and green solvents. The conditions were optimized to enable us to carry out the syntheses in good yields, and we were able to show that sabinene, a natural bicyclic monoterpene, could be used effectively as a solvent.

The objective of this investigation was to enhance the sensory appeal of Cerasus humilis (C. humilis) juice and ascertain potential interactions among bioactive compounds within a functional juice matrix. Sensory attributes, color, antioxidant potential, polyphenol and vitamin C (VC) concentrations, and sugar levels were assessed. Diverse dosage combinations were examined to determine their impact on the quality of both C. humilis and Green grape juices. Among the formulations, CG5 exhibited elevated antioxidant activit y and polyphenol content (455.02 mg TE/100 ml and 173.1 mg/100 ml, respectively), coupled with favorable consumer preference. Notable variations in compound content were observed across the seven analyzed juices. In the blended juices (CG1–CG5), interactions between distinct juices influenced VC and sugar levels, with other bioactives contributing to beneficial modifications, displaying a progressive rise. This study innovatively crafted delectable and convenient C. humilis juice, upholding its intrinsic high antioxidant activity, thereby presenting a novel avenue for marketable functional juice offerings.

Background: Recently the role of nutraceutical compounds in the prevention of human diseases is rapidly increasing. Here, we aim to evaluate the beneficial effect of dietary supplementation with seven active principles, lycopene, sulphoraphane, silymarin, glutathione, escin, tryptophan, green tea catechins, on human health. Methods: An extensive search of PubMed and Medline database was performed with the following keywords: “silymarin”, “sulforaphane”, “lycopene”, “green tea catechins”, “tryptophan”, “glutathione” and “escin” accompanied by the keywords “supplement”, “supplementation”, “nutraceutics”. All pre-clinical and clinical trials have been considered for this review. Results: One-hundred and eighteen full-text articles were eligible for inclusion in this review. The papers examined presented considerable variability due to the wide heterogeneity of dosages administered, population involved and outcomes pursued. Conclusion: Nutritional supplementation with lycopene, sulphoraphane, silymarin, glutathione, escin, tryptophan and green tea catechins appears to exert a wide range of benefits on human health, ranging from mood and cognition to cardiovascular health, fertility, metabolism, antioxidant and anti-inflammatory capabilities, potential anti-cancer effects. Further studies are required to better define the potential synergic effect, optimal dosage, mechanism of action and tolerability profile of these substances.

The energy production market based on hydrogen technologies is to be an innovative solution that will allow the industry to achieve climate neutrality in the future in Poland and in the world. The paper presents the idea of using hydrogen as a modern energy carrier, and devices that, in cooperation with renewable energy sources, produce the so-called green hydrogen and the applicable legal acts that allow for the implementation of the new technology were analysed. Energy transformation is inevitable, and according to reports on good practices in European Union countries, hydrogen and the hydrogen value chain (production, transport and transmission, storage, use in transport and energy) have a wide potential. Thanks to joint projects and subsidies from the EU, initiatives supporting hydrogen technologies are created, such as: hydrogen clusters, hydrogen valleys, and EU and national strategic programs set the main goals. As noted in this article, Poland is one of the leaders in hydrogen production both in the world and in Europe. Domestic tycoons from the energy, refining and chemical industries are involved in the projects. Eight hydrogen valleys that have recently been created in Poland successfully implement the assumptions of the "Polish Hydrogen Strategy until 2030 with a perspective until 2040", "Energy Policy of Poland until 2040", which are in line with the assumptions of the most important legal acts of the EU , including: the European Union's energy and climate policy, the Green Deal, the Fit for 55 Package.

The affordable production of valuable antioxidant extracts from plant resources depends on the availability of enabling technologies, such as hydrodynamic cavitation (HC), characterized by unrivalled effectiveness, efficiency, and scalability in the extraction of natural products. As sources of phytochemicals showing biological effects on human health, including anti-cancer properties, pomegranate (Punica granatum L.) fruits were processed using HC. Fractions collected during the process (M1-M5) were lyophilized (L), filtered (A), or used as such (C), for identifying their best conservation practice. Biochemical profile and in vitro antioxidant power were investi-gated by spectrophotometric and chromatographic assays. The antiproliferative effect of L-M3, resulting from just 15 minutes of extraction, was tested on human breast cancer line (AU565-PAR) and peripheral blood mononuclear (PBMCs) cells from healthy donors. M3-M4 fractions from L and C series revealed the highest antiradical activity and phenolic content. Cell growth, death, and redox state were assessed, showing that the pomegranate extract M3 significantly reduced tumor cell proliferation and intracellular oxygen reactive species. No effect on PBMCs was de-tected. Thus, the use of antioxidants isolated using HC as adjuvants in anticancer therapies might be advantageous and affordable; moreover, since oxidative stress contributes to cancer devel-opment, its reduction might be the leading mechanism.

Artemisia absinthium (A. absinthium) leaf extract was successfully used to create zinc oxide nanoparticles (ZnO NPs), and their properties were investigated via several techniques, including X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), Fourier transform infrared (FTIR), and UV–Vis spectroscopy. SEM analysis confirmed the spherical and elliptical shapes of the particles. Three different zinc peaks were observed via EDX at energies of 1, 8.7, and 9.8 keV, together with a single oxygen peak at 0.5 keV. XRD analysis identified ZnO NPs as having a hexagonal wurtzite structure with a particle size that decreased from 24.39 to 18.77 nm, and with an increasing surface area (BET) from 4.003 to 6.032 m2/g for the ZnO (without extract) and green ZnO NPs, respectively. FTIR analysis confirmed the groups of molecules that were accountable for stabilizing and minimizing the ZnO NPs, which was apparent at 3400 cm. Using UV–Vis spectroscopy, the band gap energies (Egs) for the green ZnO and ZnO (without extract) NPs were estimated, and the values were 2.65 and 2.79 eV, respectively.

In this paper, we propose a novel approach to the development of green public policies. We emphasize the significance of the System of Systems (SoSs) methodology, which concentrates on understanding and managing complex systems by contemplating their interdependencies and interactions as a single integrated system. Based on this perspective, we view green public policy as a system interacting with the energy, health, pollutants, and economic systems of the SoSs. We employ both Decision-Making Trial and Evaluation Laboratory (DEMATEL) and Interpretive Structural Modeling (ISM) techniques as a method of systematic structural analysis to comprehend the relationships between the aforementioned systems. We provide a comprehensive literature review on the application of these soft operation research (SOR) techniques. We note that SOR methods are suitable for the formulation of effective and long-lasting public policies. Using an example, we demonstrate the primary advantage of DEMATEL and ISM, which is the establishment of easily comprehendible causal relationships between the systems in the SoSs.

Background: Recently the role of nutraceutical compounds in the prevention of human diseases is rapidly increasing. Here, we aim to evaluate the beneficial effect of dietary supplementation with seven active principles, lycopene, sulphoraphane, silymarin, glutathione, escin, tryptophan, green tea catechins, on human health. Methods: An extensive search of PubMed and Medline database was performed with the following keywords: “silymarin”, “sulforaphane”, “lycopene”, “green tea catechins”, “tryptophan”, “glutathione” and “escin” accompanied by the keywords “supplement”, “supplementation”, “nutraceutics”. All pre-clinical and clinical trials have been considered for this review. Results: One-hundred and eighteen full-text articles were eligible for inclusion in this review. The papers examined presented considerable variability due to the wide heterogeneity of dosages administered, population involved and outcomes pursued. Conclusion: Nutritional supplementation with lycopene, sulphoraphane, silymarin, glutathione, escin, tryptophan and green tea catechins appears to exert a wide range of benefits on human health, ranging from mood and cognition to cardiovascular health, fertility, metabolism, antioxidant and anti-inflammatory capabilities, potential anti-cancer effects. Further studies are required to better define the potential synergic effect, optimal dosage, mechanism of action and tolerability profile of these substances.

The issue of environmental sustainability is increasingly topical and one of the most impactful sectors is that of the construction industry. As stated in the reports of the GlobalABC, the building sector is the main responsible for GHG emissions, generating about 37% of global CO2e emissions. Already during the phases of production and construction of buildings about 10% of global emissions are produced, while the remaining part comes from their use, from the energy for air conditioning and lighting. Reducing emissions in the pre-use phase of buildings is therefore a crucial issue for combating climate change. The research investigates the potential of timber construction systems, thanks to the carbon storage property of the material. The proposed calculation methodology is structured according to the LCA-Life Cycle Assessment approach, referring to the C2H phase (from Cradle-To-Handover), and evaluates emissions related to the production and construction of buildings. To identify the timber construction system that minimizes CO2e emissions, within the limits of the investigation (A1-A5 phases), the method was applied to two buildings built with different technologies: one with X-Lam panels and one with a framed structure. The results were analyzed, compared, and discussed to demonstrate that the timber buildings are the most virtuous solution in the Net Zero Carbon perspective by 2050.