Appendix A.3. Geometric phase with 4-component spinors
When the polarization state of light undergoes a series of operations and returns to its original state, the final state differs in an additional overall phase factor from the original one. It was pointed out by Pancharatnam that the phase difference is not only due to the dynamical phase from the accumulated path lengths but also involves a geometric phase [
32]. Berry introduced the corresponding theory for quantum mechanical state vector and re-derived the Pancharatnam’s geometric phase [
33,
34]. If the cyclic path consists of only great circles, additional dynamical phase will not develop, and the geometric part increases by
19, where
is the solid angle that the geodesic path of cyclic operations subtends on the Poincare sphere
20.
The emergence of geometric phase can be demonstrated in SL(2,C) by considering three successive Hermitian operations on a spinor. For example, let
,
and
be three radial unit vectors at points 1, 2 and 3 on the Poincare sphere:
And let
,
and
be the spinors that correspond to these radial unit vectors:
We consider a closed loop
projection operations that starts by acting on
and finally brings the state back to
which may differ from the first one only by a phase angle
:
For simplicity and without loss of generality when we choose
This is the geometric phase and it’s magnitude is equal to
. The result can be checked by calculating the area subtended by the cyclic path in terms of the angular variables. In this example, the corners of the spherical triangle are defined by the unit vectors,
,
and
, hence, it is convenient to use the following formula in order to calculate the area of the spherical triangle [
35]:
As an example let
. From Equation (205),
and from Equation (207)
. Hence,
21.
Similar relations can be derived with
Z matrices and 4-component spinor pairs. But, now the type of transformation is important,
must act on the pair
, (
or
D). As an example, this time, we demonstrate the emergence of the geometric phase with unitary operations (rotations) on the 4-component spinor pairs. In order to avoid the dynamical phase we consider trajectories on the great circles. Let us start with
at the point
:
First we rotate
about the
y-axis CCW by
. A
matrix with
does this job:
Then we apply a
CCW rotation about the
z-axis
Finally we rotate the state CCW about the
x-axis by
:
The final state differs from the initial one by a phase angle
, and this is the expected geometric phase for this cyclic unitary operations on the Poincare sphere.
If we work with , or we have to use the associated form of the Z matrix. Similar operations are also possible with dotted and undotted contravariant states by using and matrices respectively.
Appendix A.4. Coherent parallel combination of transformations and interpretation of Z as a state of the transforming medium
Up to now Z matrices were abstract mathematical operators that transform abstract mathematical objects (spinors). In a real experiment the transformation of the physical state of the system is carried out by an apparatus. For example, the polarization state of a beam of light (or a single photon) is modified as it passes through an optical medium.
The overall effect of the interaction of light with a deterministic, i.e., non-depolarizing, medium or optical element can be described by a 2×2 complex matrix
J, referred to as the Jones matrix [
28]. In order to obtain the Jones matrix boost and rotation parameters of the Lorentz group should be replaced by spectroscopic parameters (diattenuation and retardation) associated with various anisotropy properties of the optical medium
22. Jones matrix
J differs from
L of SL(2,C) by a complex constant [
25], hence it is an element of GL(2,C). This complex overall factor
k is due to the isotropic phase retardation (
and isotropic amplitude absorption (
):
, where
. Hence, in polarization optics,
. Similarly
. Accordingly,
. It may be appropriate to define new parameters,
[
18]:
In order to obtain the optical version of the
Z matrix we have to modify Equation (184). After multiplying
by
k, we replace
and
in
by birefringence and dichroism parameters:
and
for linear birefringence,
for circular birefringence;
and
for linear dichroism and
for circular dichroism
23. For example, the state of the medium that given by
is a horizontal linear polarizer,
is a linear polarizer at
,
is a quarter wave plate (vertical fast axis),
is a circular retarder (
). List of basic optical elements and their states can be found in the Appendix.
There are basically two types of light-medium interaction: serial and parallel
24. In a serial combination Jones matrices act on a 2-component spinor in succession
In a parallel process, an optical recombination takes place during the light-medium interaction. When the light beam simultaneously illuminates different parts of the medium, each part having different optical properties, the light emerging from different parts, in general with different polarizations, may recombine into a single beam. If the medium is composed of several non-depolarizing (deterministic) components, each component with a well defined Jones matrix, then the matrix associated with the coherently combined overall optical system is simply given by a linear combination of the individual matrices of the components [
26,
27]:
where
Complex coefficients
are generally functions of space, time and frequency and they play the role of probability amplitudes of quantum mechanics
25 26. Similar relations can be written in terms of
N matrices:
The 4×4 real matrix for transforming the Stokes vector of the light is the Mueller matrix
M that is directly connected with the experimental work. If the medium is deterministic,
M can be obtained from
N matrix as,
. As opposed to
J and
N,
M does not contain any information about the overall phase introduced by the material medium.
M differs from the Lorentz transformation matrix
by a positive real constant
27.
The resultant matrix state
N in Equation (217) corresponds to the nondepolarizing Mueller matrix of the coherently combined system. Without loss of generality we may restrict our presentation to a two-term coherent parallel combination, then
M can be written in terms of
N matrices as follows:
In this expansion,
and
are the Mueller matrices of the nondepolarizing component systems, whereas,
and
are the matrices resulting from coherence that cannot be interpreted as Mueller matrices in the usual sense. Although, the combined term
turns out to be a real matrix, it is still not a Mueller matrix [
18].
It may be more convenient to work with vectors rather than matrices to represent optical media states. The
state interpretation of the transformation matrices becomes more clear in the vector representation. The vector state can be defined as the first column of the
N matrix [
8]:
It is possible to decompose a given vector state
with respect to a complete basis set of component systems:
Here, we simply apply the ordinary vector decomposition procedure. The natural basis are
These basis correspond respectively to free space (identity), half-wave plate (
fast axis), half-wave plate (
fast axis) and a circular retarder (
). We may use other states as basis if we like. For example, let
and
correspond to orthonormal vector states of a linear horizontal polarizer and a linear vertical polarizer, then the following expansion of
will correspond to a horizontal quarter-wave plate state [
18]:
where
28 and
Therefore, at least mathematically, we can consider an ideal quarter-wave plate state as a coherent linear combination of two orthogonal linear polarizer states. In practice, this means that, if it could be possible to combine two orthogonal polarizers coherently with the associated complex coefficients as given in Equation (222), we would obtain an artificial quarter wave plate that effectively responds to the incident light just like a genuine one.
In general, we can use non-orthogonal basis to decompose a given covariance vector . However, decomposition with respect to non-orthogonal basis is more involved: we have to take into account covariant and contravariant types of bases and expansion coefficients. As an example, the covariance vector of an ideal partial polarizer can be decomposed into two non-orthogonal states, one of them being the direct beam state which corresponds to the identity Mueller matrix, and the other component being a horizontal linear polarizer state, with a suitable coefficient.
There are coherent parallel combination experiments that demonstrate the state interpretation of
J,
N and
in light-nanoparticle interactions [
18,
19,
20,
21]. In a certain interval of wavelength, a nanorod oriented at an angle
in the the
x-
y plane responds to the incident light propagating along the
z axis as a linear polaizer and the associated vector state is
It can be mathematically shown and experimentally observed that two crossed orthogonal identical nanorods respond to the incident light as an identity (free space)[
18,
19]:
In this expression, for simplicity, we let the Lorentzian polarizabilities of the nanorods equal to one.
In a three dimensional arrangement, if there is a spacing between the two nanorods as depicted in
Figure A1, coherently combined system manifests optical activity along the
z axis due to the relative phase and mutual interaction between the nanorods. It is worth noting that, since the nonorod vector states are in the form given in Equation (224), the fourth component that corresponds to the
anisotropy, which is related to the optical activity, is always zero, i.e., for non-interacting nanorods no coherent linear combination can result in a vector state with
29. For the system given in
Figure A1, the emergence of optical activity can be described as a three term coherent combination of vector states, two of them associated with non-interacting nanorods and the third one being the state due the interaction:
where
is the phase difference due to the spacing between the nanorods along the
z axis,
contains the Lorentzian polarizability and the interaction coefficient, the overall factor
,
G is a function of the Lorentzian polarizability and the far field factor,
is a compound factor involving phase, polarizability and interaction coefficient [
21]
30 31.
Figure A1.
Optical activity in a coupled dimer. and are the dipoles associated with the nanorods, Light propagates along .
Figure A1.
Optical activity in a coupled dimer. and are the dipoles associated with the nanorods, Light propagates along .
Appendix A.4.1. Unitary formulation of the rotation of the medium in space
J,
N matrices and
vector are the states of the transforming medium or the optical element, therefore they are themselves subjected to transformations. Particularly, if the optical element is rotated CCW by an angle
about an axis parallel to the direction of propagation of light, the state of the optical element is also rotated:
is unitary
matrix, element of SL(4,C):
indicates the direction of propagation of light
32. The corresponding Mueller matrix is rotated as
33
If we choose the direction of the light beam along the
z axis
and