1. Introduction
Turbidity is caused by the existence of suspended particles, organic matter, and chemicals, and is widely measured in natural resources, irrigation water, food and beverage industry, and drinking water [
1,
2,
3]. As an important water quality parameter, turbidity not only indicates the efficiency of some treatment processes (e.g., sand filtration) but also reflects water quality changes in the distribution systems. For example, cast iron and steel pipes constitute a large proportion in Drinking Water Distribution Systems (DWDS) in many countries (e.g., 57% in USA [
4]), where the internal corrosion is ubiquitous [
5]. Disturbance of corrosion scale due to changes of water quality or hydrodynamic conditions may result in water discoloration and/or contaminant release, leading to consumer complaints and potential threat to public health. Discolored water episodes (red water) have been reported worldwide such as U.S. [
6,
7], China[
5], and European countries [
8,
9]. Turbidity measurement, particularly continuous monitoring at several locations at the same time, has been suggested as a practicable technology providing data to be used to identify causal factors and quantify discoloration risks [
10]. Moreover, turbidity has been correlated with contamination with Giardia and Cryptosporidium and used as a surrogate measure for risk of contamination by these pathogens [
11]. Studies also revealed a strong temporal relationship between turbidity and gastrointestinal events during and preceding the major waterborne disease outbreak in Milwaukee in 1993 [
12]. All these findings emphasize the importance and necessity of turbidity monitoring in a contamination warning system, preferably with cost-effective and real-time monitoring methods.
Turbidity can be measured either by determining the degree of light transmission (turbidimetry) or by evaluating the degree of light-scattering (nephelometry) [
13]. The major standard methods include US EPA method 180.1, ISO 7027, and GLI method 2 [
14,
15,
16]. In practice, turbidity can be measured using a turbidity instrument in the lab or a portable turbidimeter in the field. Several on-line, reagent-free water monitoring systems are also commercially available, but the bulky size and high cost prohibit their application in DWDS [
17,
18]. Solid-state multi-parametric sensor arrays incorporating turbidity sensors have also been developed [
19]. Further, research efforts have been taken to design smart sensor networks. For example, low-cost water quality sensor nodes which consist of sensing, data processing, and communicating components have been investigated, where the measurement nodes that are interfaced to multi-parametric sensor arrays are proposed to be installed in a spatially-distributed manner and form a wireless sensor network [
18,
19,
20,
21,
22]. While the networking capability is appealing, both the hardware and the software of such systems need further improvement. In addition, the sensing performance and the lifetime may be limited by the battery power, leading to extra maintenance cost [
20].
Innovative design of the turbidimeter is vital to achieve accurate measurement as well as to develop robust and low-cost distributed sensors. In this regard, fiber optical turbidity sensors possess some important advantages such as low cost, compactness, great flexibility, high stability over a wide temperature range, immunity to electromagnetic interference, water and corrosion resistance, and compatibility with multi-sensor schemes [
23,
24,
25]. An optical fiber turbidity sensory system generally consists of a light source, a sensing element (transducer), a detector, and optical fibers which act as a light transmission medium between water samples and the receiver circuit. Often, one or more fibers are used for emitting light and the rest are used for receiving the light reflected/scattered from the water sample [
26,
27,
28,
29]. Although the potential applications of optical fiber-based turbidimeters in remote sensing and multi-sensor systems have been acknowledged, research on developing such sensor networks is very limited if any. Most previous studies used plastic optical fibers with a core diameter of 1 mm [
23,
24,
25,
26,
27,
28]. While they are more flexible and rugged as well as easier to handle and install than glass fibers, plastic fibers suffer from very high optical attenuations, which limits the typical fiber lengths to below 100 m. This sets the requirement for the interrogation and detection system to remain “local” to the water source, inherently prohibiting remote, off-site turbidity measurement. Meanwhile, future DWDS call for large-scale, distributed turbidity-monitoring networks for real-time,
in-situ drinking water quality monitoring. There is hence a demand for turbidity sensors based on low-loss glass fibers.
In an effort to address the aforementioned challenges, in this study, we designed and developed an innovative, low-cost glass optical fiber-based turbidity sensor as the foundation for future development of real-time, in-situ sensor networks. Turbidity sensing properties of the sensor were systematically evaluated. The performance was also examined in real environmental samples under the influence of temperature and flow rate to verify the feasibility of turbidity measurement for the proposed applications.
2. Methods
2.1. Design and Measurement Principle
Turbidity represents the optical clarity of water, which can be measured by an angular distribution of scattered light (i.e., nephelometry) or a reduction in intensity of transmitted light. In this study, back-scattering is used to determine turbidity to circumvent the difficulties of transmitted light measurement in low turbidity samples and interference by light absorption caused by dissolved species in water samples. Moreover, compared to other nephelometry approaches, the back-scattering approach does not require separate light transmitters and receivers. A single fiber can simultaneously deliver light into the water and collect the back-scattered light, allowing easy scale-up of the number of probes and, hence, making possible a distributed scheme.
The main technical challenge for a glass fiber-based nephelometer is the small core sizes of glass fibers. Typical core sizes of glass fibers range from 10 μm to 200 μm in diameter, which are markedly smaller than the core sizes of plastic fibers (typically > 1 mm). As a result, the amount of scattered light that can be collected by a glass fiber is orders-of-magnitude lower than a plastic fiber due to the much smaller light-collecting area of the glass fiber. With lower collected optical power, glass-fiber turbidity sensors are projected to have poor signal-to-noise ratios (SNR) and hence reduced turbidity sensitivity. This is why plastic fibers have been widely studied for turbidity measurement while little research has been reported on glass fiber-based nephelometers.
To overcome this shortcoming of glass fiber, we propose here a balanced photodetection scheme, where the use of differential detection helps remove much of the common-mode noise. This allows a large electronic gain to be utilized to counter the small collected optical signal from scattering. The scheme has shown great promise to measure turbidity down to the levels relevant to drinking water, as described in the following.
2.2. Experimental System, Materials and Equipment
A system layout of the glass-fiber turbidity measurement unit is shown in
Figure 1. The entire unit was constructed using glass fibers with a 200-
μm core size and a 0.22 numerical aperture. The laser operated at 980 nm, with about 10 mW of power delivered into the water. A 50:50 fiber coupler evenly split the laser output into two arms. In each arm, a circulator routed the laser light into the water samples. Two water samples were used for measurement, one pure-water sample as the reference and one “polluted” sample for turbidity determination. The back-scattered light from the samples was collected by the same fibers that delivered the light and was directed toward the detector by the circulators. A balanced Si photodetector (Thorlabs PDB450A) converted the optical signals into electrical signals, subtracted them to generate a differential output, and amplified this differential signal with a transimpedance amplifier (TIA). The TIA has a tunable gain that can be set between 10
3 and 10
7. A digital multimeter (RIGOL DM3058E) as well as an oscilloscope were used to record and monitor the TIA output.
Pictures of the actual setup are shown in
Figure 2. The unit has a footprint of 1 ft. × 2 ft, with ample room for further minimization. To better illustrate the effect of scattering caused by turbidity, the laser shown in the picture operated at 532 nm (green), whereas the actual measurement was performed with a more stable 980-nm diode laser.
Turbidity standard solutions (0 ~ 100 NTU) were purchased from ThermoFisher Scientific. Tap water and surface water samples were taken from the water quality lab and a pond located on the university campus. A commercial turbidity meter (Orion™ AQUAfast AQ3010) was also used to measure the sample turbidity for comparison purposes when needed.
Author Contributions
Data curation, C.T.V. and A. A. Z.; Formal analysis, C. T. V. and A. A. Z..; Funding acquisition, L.D. and T. W.; Investigation, C. T. V., L. D., and T. W.; Methodology, L.D. and T. W.; Project administration, L.D. and T. W.; Resources, L.D. and T. W.; Supervision, L.D. and T. W.; Validation, C.T.V. and A. A. Z; Visualization, C.T.V. and A. A. Z.; Writing—original draft, L.D. and T. W.; Writing—review and editing, L.D. and T. W. All authors have read and agreed to the published version of the manuscript.