Schrödinger’s quantum mechanics is limited to the description of spin less particles. Indeed the need for spin became necessary as Schrödinger equation could not account for the result of the Stern Gerlach experiments, predicting a single spot instead of the two spots obtained for hydrogen atoms. Thus Pauli introduced his equation for a non-relativistic particle with spin is given by:
here is a two dimensional complex column vector (also denoted as spinor),
is a two dimensional hermitian operator matrix,
is the magnetic moment of the particle, and
I is a two dimensional unit matrix.
is a vector of two dimensional Pauli matrices which can be represented as follows:
The ad-hoc nature of this equation was later amended as it became clear that this is the non relativistic limit of the relativistic Dirac equation. A spinor
satisfying equation (
42) must also satisfy a continuity equation of the form:
In the above:
The symbol
represents a row spinor (the transpose) whose components are equal to the complex conjugate of the column spinor
. Comparing the standard continuity equation to equation (
44) suggests the definition of a velocity field as follows [
24]:
Holland [
24] has suggested the following representation of the spinor:
In terms of this representation the density is given as:
The mass density is given as:
The probability amplitudes for spin up and spin down electrons are given by:
Let us now look at the expectation value of the spin:
The spin density can be calculated using the representation given in equation (
47) as:
This gives an easy physical interpretation to the variables
as angles which describe the projection of the spin density on the axes.
is the elevation angle of the spin density vector and
is the azimuthal angle of the same. The velocity field can now be calculated by inserting
given in equation (
47) into equation (
46):
We are now in a position to calculate the material derivative of the velocity and obtain the equation of motion for a particle with ([
24] p. 393 equation (9.3.19)):
The Pauli equation of motion differs from the classical equation motion and the Schrödinger’s equation of motion. In addition to the Schrödinger quantum force correction we have an additional spin quantum force correction:
as well as a term characterizing the interaction of the spin with a gradient of the magnetic field, which is the Stern-Gerlach term.
As both the upper and lower spin components of the wave function are expanding in free space the gradients which appear in
will tend to diminish for any macroscopic scale making this force negligible. To estimate the condition quantitatively we introduce the typical spin length:
Using the above definition we may estimate the spin quantum force:
this suggested the definition of the hybrid typical length:
In terms of this typical length we may write:
Thus the conditions for a classical trajectory become:
Another important equation derived from equation (
42) is the equation of motion for the spin orientation vector ([
24] p. 392 equation (9.3.16)):
The quantum correction to the magnetic field explains [
24] why a spin picks up the orientation of the field in a Stern-Gerlach experiment instead of precessing around it as a classical magnetic dipole would.