1. Introduction
Energy demands and environmental concerns have been witnessing a significant paradigm shift towards sustainable practices. At the same time, the increasing urbanization and world population have been demanding more energy to attend the societies´ higher demand. In order to do attend both, a change in the political paradigm is necessary towards to help develop new green technologies and turn them into feasible energy-production activities [1]. For instance, energy harvesting (EH) is one innovative conjunction of techniques and applications [2] where the inherent energies from the geoenvironment are tapped to generate power while promoting eco-friendly solutions, also within the scope of Sustainable Goals Development Agenda for 2030 [3]. Cao et al. [4] defined EH as primordial in the new era of the internet of things (IoT) and artificial intelligence (AI) for a smarter and sustainable world. Other digital systems, such as sensors, UAVs and robots can benefit from EH sources.
Furthermore, R. Perez and M. Perez [5] compared world’s reserves in TW/year for renewable and finite energies, for finite ones with 900 TW, coal has the highest, followed by uranium, petroleum and natural gas representing still a great amount when having attention to 16 TW/year world’s utilization. In addition, although finite resources have high energy-production potential, they are also generally associated to industrial processes and economical activities, implying in carbon emissions and, thus, affecting the aimed sustainable goals for the future. Petroleum, for example, responds for the third-largest source of carbon emissions, due to the processes taken in the refineries, leading to the necessity of researching alternatives to the finite resources or mitigating their impacts through enhancing energy efficiency and optimizing equipment and parameters [6]. Renewable ones are the focus when dealing with EH, and according to this same study, only solar have the potential of 23,000 TW/year, followed with less exorbitant numbers exposed in Fig.1, based on [
5], by wind, oceanic (OTEC), hydro, geothermal, gravitational (TIDES) and biomass, being the latter promoted as a carbon-neutral, transitionary source that could act to the diversification of energy sources [
7,
8]. In addition, renewable sources potential energy-production values could be higher in the following years, as the efficiency of each used methodology is increased through research and development.
Figure 1.
Renewable and finite energy reserves.
Figure 1.
Renewable and finite energy reserves.
EH over geoenvironmental engineering needs attention in several types of works and potential processes. Summing up, it needs analysis on containment systems management when observing landfilling and other storage facilities for hazardous and non-hazardous wastes, structures with contaminant transport control which measure the pollutants looking to avoid soil, surface water and groundwater contamination, wastewaters management that involve safety transport, treatment and reuse processes, remediation of contaminated sites like brownfields, dumps, mines and ponds, and valorization of industrial wastes as geomaterials [
9]. Across the globe, EH techniques have garnered immense attention for their potential to transform geoenvironmental engineering projects, the key factor emerges within the integration of renewable energy sources into conventional engineering practices [
10]. Furthermore, Balakrishnan
et al. [
10] highlighted the fight against the unwillingness of the private sector regarding investments due to late return of capital, and the major role of the government to surpass this obstacle [
11]. Solar photovoltaic systems, a prime example of EH, have gained substantial prominence in the past decades, according to the International Energy Agency (IEA), the global installed capacity of solar photovoltaic systems exceeded 700 GW by the end of 2022, illustrating the rapid uptake of this sustainable energy source [
12,
13]. Furthermore, piezoelectric systems have emerged as another noteworthy EH method which harnesses mechanical vibrations from traffic movement or groundwater flow and wind, converting them into electrical energy [
14,
15,
16,
17]. Alerting to its implementation in urban environments and demonstration of its potential to power remote sensors and monitoring systems. In addition, thermoelectric generators (TEGs), for instance, have gained prominence for their ability to convert temperature gradients into electricity, finding applications in geothermal areas, where subsurface temperature variations can be tapped producing a noteworthy power output [
18,
19].
Geoenvironmental engineering is also closely linked to the field of geotechnical engineering, where soil properties and movement play a pivotal role. Recent advancements have led to the integration of EH with geotechnical activities like self-powered sensing systems embedded within soil structures have been developed, enabling real-time monitoring without external power sources [
2]. Moreover, microbial fuel cells (MFCs), enzyme-based fuel cells (EBFCs) and triboelectric nanogenerators (TENGs) have emerged as novelties EH technique that harnesses several industrial activities into opportunity to energy generation from biochemical mechanism. The energy generated through microbial processes offers a sustainable means to power geoenvironmental applications [
20,
21]. In addition, geothermal energy is another sector that provides high potential for EH, while being considered a renewable, clean source and with a relatively low-cost production addition, geothermal energy is considered a renewable, clean source and with a relatively low-cost production [
22]. Its process consists of using the using the earth’s deeply complex physical chemical for energy production through geothermal plants. Salazar
et al. [
23] analyzed this source for Colombia, stating that it not only has provided to be a good alternative for EH, but also that if used in its full potential, it could represent 20% of Colombia´s energy need, instead of the current 1.65%, other authors have studied similar topics around the world [
24,
25]. If applied on large a scale and for other countries, this sector could be responsible for largely contributing for mitigating the current energy crisis. Besides, Zhu
et al. [
26] alerted for a worldwide and current journey where the energy harvesting processes that are used are going to be transformed using TENG to nanoenergy and nanosystems, those challenges will be pointed out regarding geoenvironmental applications.
EH can also be obtained from environmental sanitation works such as biological wastewater treatment processes [
27,
28,
29] (e.g. activated sludge, algae technology, constructed wetlands and lagoons) and solid waste composting [
30,
31,
32]. Wastewater and water flow can also be harnessed to generate hydroelectric power [
33,
34] using micro-turbines and solar panels can be installed on the rooftops of water and wastewater treatment plants, as well as in solid waste management infrastructures, to generate electricity from sunlight. Methane produced in solid waste landfills [
31] and anaerobic digestion reactors [
35,
36] can be captured and used for electricity generation or as a fuel source. The temperature difference between wastewater and organic solid waste and the environment can be used to generate thermal energy through heat exchangers and heat pumps [
37,
38]. Environmental sanitation facilities located in open areas in windy regions may be suitable for wind turbines [
39,
40]. Microbial fuel cells (MFC) can be used to capture electrons from organic matter in solid waste [
41] or wastewater [
42,
43]. Thus, EH for geoenvironmental engineering holds immense promise for sustainable development [
9]. The global impact of EH technologies underscore their potential to reshape conventional engineering practices. Such a scenario equally demands adequate politics framework to provide these sectors with the necessary regulation. This paper aims to review EH for geoenvironmental engineering techniques, exploring its global impact, and recent scientific advancements.
2. Literature Review Methodology
This research was done in 3 of the main databases for data analysis - Google Scholar, Scopus, and Web of Science -, the search was performed using Boolean and keywords truncated following schematic
Figure 2a. The starting point was “energ* harvest*” AND “geoenvironment*”, in addition to separated searches with AND “soil dynamic*”, AND “hydraulic*”, AND “solar*”, AND “biochemic*”, AND “magnetic*”, AND “wind*”, AND “vibration*”. For each geoenvironmental application, were searched AND “characteristic*, AND “production*”, AND “quantit*”, looking to evaluate worldwide numbers. The selected papers are exposed in references.
Besides, Scopus’ key-word co-occurrence when searching for “energ* harvest*” AND “geoenvironment*”, which resulted in 132 documents, in which the data was exported from Scopus website and organized by subject areas in pie chart (
Figure 2b), and according to the number of published documents following the years of publication and the countries of the study (
Figure 2c), besides, was developed in VOSviewer software, the keywords’ co-occurrence map (
Figure 2d).
The software Canva online was used to illustrate EH different processes in
Figure 3. And, in order not to infringe copyright and image rights, some images were generated to illustrate geoenvironmental applications using the artificial intelligence (AI) tool: Imagine AI and identified as AI generated (AIG) in
Figure 4.
Figure 2b exposes the main subjects when analyzing EH for geoenvironmental application and, as expected, engineering is first reaching almost 25% followed by what seems to be the general areas for EH: computer, energy, materials, physics, and biochemistry science. Besides, the path used in this work to determine what are the opportunities is to use mainly the least cited: environmental science, medicine, and agriculture.
Figure 2c shows the increase of articles published during the past two decades with the black line, and the red line aligned the number of papers through countries highlighting the two biggest economies worldwide: China with 49 and United States of America with 23. Thus,
Figure 2d keyword co-occurrence helps the understanding of EH, the strongest connections are around sensors, energy management and technology with the red and green dots, followed by the yellow with the main investments with solar energy and less connected with the emerged technologies over biological application.
3. Energy Harvesting Basics
Several authors [
4,
44,
45] explicated the importance of basic physics’, electrical’, electronic’, fluid and solid’s mechanics’, hydraulics’, and soil mechanics’ theories, which to analyze opportunities of EH in geoenvironmental engineering is a must to follow and understand some rules, theorems, law, and equations among:
Newton’s second law
Maxwell’s displacement current
Joule’s thermal conductivity
Strouhal’s number for frequency oscillation
Euler-Lagrange theorem
Bernoulli’s fluid mechanics equation
Navier-Strokes for incompressible Newtonian fluids
Reynolds number for fluids
Darcy’s law of flow rate
Among others, unfairly not cited.
It is important to refer to two major basic electric principles which will be less approached in this research due to less use for EH purpose: electromagnetic and electrostatic. Electromagnetic uses the induction of several materials to generate energy from movement, consisted of inductive material serially aligned surrounded by permanent magnets between two spiral strings, moreover, electrostatic using Coulomb’s law parallel plate capacitors are not very popular for EH [
27].
3.1. Piezoelectricity
First introduced by Pierre and Jaques Curie [
46], a piezoelectric material forms dipole moments, called direct piezoelectric effect which generates energy due to force applied, this force can be from several sources [
47]. When there is tension or compression in the material, an alternative current voltage will be the output, although when the material is polarized the converse piezoelectric effect occurs within extending or contracting due to the applied voltage (
Figure 3a). Direct and converse piezoelectric effect are governed by constitutive equations according to electrical displacement, piezoelectric coefficient, stress, permittivity of the material, electric field, strain, and mechanical compliance [
48]. Piezoelectric utilizes vibrating mass connected into a piezoelectric material and to a circuit with diodes, capacitor, and resistor, generating energy. The involved materials can be varied types, such as bio-based, organic, inorganic and composites, as ferroelectric ceramic, polyvinyde fluoride, macro-fiber composites, among others [
48]. Besides, usually supported by flexible films or biofilms which are made of polymers as polyimide (PI), polyethylene terephthalate (PET) and encapsulated in biocompatible materials such as polydimethylsiloxane (PDMS) and polytetrafluoroethylene (PTFE) [
47,
48,
49].
Fuel cells (FCs) are based on a piezoelectric effect which have a cathode, an anode, a microorganism, and an oxidizing substrate, mainly composed of organic matter, in its structure inside a single or dual chamber. Basically, the microorganism decomposes the organic matter and electrons are generated, and flow through a cation exchange membrane developing a potential difference between electrodes (
Figure 3b) [
50]. EBFCs use similar mechanisms to MFCs, and are classified into in-vitro, plant, animal, or human powered, the last one being wearable as contact lens and patches [
50].
3.2. Pyroelectricity
The pyroelectric effect can be explained as the spontaneous polarization of some crystalline structures when variation of temperature happens transforming the surface bound charge of the crystals (
Figure 3c). Thermal activity uses this principle when heat occurs from any source like water or solar. Once the temperature rises, the intensity of spontaneous polarization will decrease, and the opposite also, as the crystalline structure is connected to an external circuit, the current pyroelectric is generated once atoms or ions move in response to increasing temperature, thus altering the balance of electrical charges in the material [
49]. The effectiveness of thermoelectric materials is based on optimizing Seebeck coefficient, electrical and thermal conductivity, and stability [
45,
51].
Some devices have been developed using pyroelectricity, such as movement sensors. When a person moves in front of the sensor, the temperature variation is detected, and the sensor generates an electrical signal that can trigger systems. Alarm themes, as well as in small energy-generating devices, such as self-contained sensors, watches and even in smart clothes that take advantage of changes in body temperature to generate electricity. Detailed understanding of the molecular and atomic processes underlying pyroelectricity is still an ongoing area of research. Choosing the appropriate pyroelectric materials is crucial to the performance of the devices. Some pyroelectric materials are expensive or difficult to obtain in adequate quantities. Therefore, finding effective and economically viable materials is a challenge.
Another application of pyroelectricity is infrared spectroscopy, where pyroelectric crystals are used as detectors, to identify and analyze chemical substances based on their interaction, and when infrared radiation hits the crystal, it generates an electric current proportional to the intensity of the radiation. It can also be applied to detect gas leaks, as the presence of gas can be detected by pyroelectric sensors. The processing of pyroelectric materials to manufacture devices is a critical step. This includes manufacturing thin films, crystals, or other required formats. The manufacturing process must be scalable, efficient, and repeatable.
3.3. Triboelectricity
Triboelectric nano generators (TENGs) function on the principle of electric charge separation between the friction of particles generating electric charge layer throughout variation in capacitance within those systems. The simplified functioning of Wang’s group invention, TENG is based in Maxwell’s displacement current from a transient electric field and media dielectric polarization which convert mechanical into electrical energy [
50]. TENGs can perform mainly in four modes (
Figure 3d): the vertical contact-separated where two layers in contact are charge with the same amount of opposite charges; the lateral sliding with similar behavior than vertical contact-separated but one layer changes from contact and separation and the other layer to one pole sliding on the first one; the single-electrode where it is connected to an external circuit following single-electrode theory; and the freestanding layer optimizing the previous one using induced potential of both electrodes [
49].
Triboelectric sensors can be used to measure pressure and force and have shown good application as a means of charging small batteries and portable devices, such as smart watches and health tracking bracelets, through body movements [
52]. As for smart fabrics, these have been shown to have excellent performance, since the textile based TENG is qualified as having usability, low cost, flexibility, lightness, and the ability to collect energy and self-powered detection [
53]. Furthermore, it is a power source that can operate for long periods of time without the need for frequent component replacement. Applications for accurately detecting displacement, direction, speed, and acceleration have also been developed [
54]. Despite being recognized as a promising method for energy capture and self-powered devices, it is necessary to improve TENG production efficiency by changing the types of dielectric materials, which requires advanced technology and high implementation costs [
55].
As it is an energy source, which can be considered recent, it is still necessary to investigate how electrons are transferred and how charges are separated during friction between materials. Although triboelectricity has shown promise on a small scale, it is still unclear what its potential is to generate energy at significant levels compared to other energy sources such as solar or wind. While triboelectricity shows potential in wearable technology, there are still challenges to be overcome, such as the size and flexibility of triboelectric generators in wearable devices.
5. Conclusions
In this review, several research topics were analyzed for energy harvesting through the scope of geoenvironmental engineering. The solutions for energy crisis can be related to research & development (R&D) opportunities within each industrial activities sector, based on basic principles of physics, fluid and solid mechanics, soil mechanics, electrical and electronic engineering, and biochemical mechanisms. In addition, it is known that the demand for energy is increasing as urbanization and growth of global population occur. Analyzing the evolution of each sector, new technologies and opportunities appear the most when the sector is in the imminence of crisis. Considering the demands for a greener are further that is forcing the industry to be restructured, it is expected to see further development in a rapid manner, based on the established values for R&D. Sensors, nanogenerators, methodologies and other approaches tend to become cheaper the more they are used and the more they are developed. The political framework should equally follow these evolutions to provide the regulatory framework for providing the right environment to develop new technologies that can arrive on the market.
Thus, new technologies begin as an experiment until they become more accessible. Geoenvironmental engineering is a part of the energy harvest strand, attracting more attention due to its potential. Recent technologies could enhance their development even further and respond to the emergency crisis the world is passing through, attending the demands for a more sustainable future through cleaner energy-production.
Author Contributions
Conceptualization, L.M. and A.A.; methodology, L.M. and A.A.; validation, A.A., L.A., L.F.G. and V.C.; formal analysis, L.M., A.S., M.M., A.A., L.A. and L.F.G.; investigation, L.M., A.S., M.M., A.A., L.A. and L.F.G.; resources, V.C.; data curation, L.M., A.S., M.M., A.A., L.A. and L.F.G.; writing—original draft preparation, L.M., A.S., M.M., A.A. and L.A.; writing—review and editing, L.M., A.S., M.M., A.A., L.A. and L.F.G.; visualization, L.M. and A.A.; supervision, A.A., L.A., L.F.G. and V.C.; project administration, L.M., A.A. and V.C.; funding acquisition, V.C. All authors have read and agreed to the published version of the manuscript.