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A peer-reviewed article of this preprint also exists.
Sample Name | Crystalline Phase | Crystallite Size, (nm) | Reducibility, % |
---|---|---|---|
10 Ni/Z | NiO | 17 | 100 |
10 Co/Z | Co3O4 | 26 | 79 |
10Cu/Z | CuO | 35 | 100 |
10Ni10Co/Z | NiO*/-Co1.3Ni1.7O4*/-Co3O4 | 17*/-26*/-26 | 82 |
10Ni10Cu/Z | NiO/ Ni0.8Cu0.2O*/-CuO | 17*/-35 | 100 |
5Ni5Co/Z | Co1.3Ni1.7O4 | 35 | 100 |
5Ni5Cu/Z | NiO/Ni0.8Cu0.2O*/-CuO | 13*/-21 | 100 |
Samples | SBET (m2/g) | Micropore Volume (cm3/g) | Total Pore Volume (cm3/g) |
---|---|---|---|
10Ni/Z | 115 | 0.019 | 0.169 |
10 Co/Z | 152 | 0.034 | 0.183 |
10Cu/Z | 86 | 0.006 | 0.186 |
10Ni10Co/Z | 82 | 0.015 | 0.133 |
10Ni10Cu/Z | 75 | 0.013 | 0.128 |
5Ni5Co/Z | 111 | 0.020 | 0.159 |
5Ni5Cu/Z | 96 | 0.015 | 0.160 |
Z | 380 | 0.107 | 0.326 |
Samples reduced at 600 °C | |||
10Ni10Co/Z | 181 | 0.047 | 0.130 |
5Ni5Co/Z | 228 | 0.061 | 0.152 |
10Ni/Z | 240 | 0.066 | 0.154 |
Composition, at. % | Cu | Ni | Co | Si | Al | O | Fe | Na | Ca | Mg |
---|---|---|---|---|---|---|---|---|---|---|
10Ni10Cu/Z | 3.2 | 7.3 | - | 10.4 | 4.5 | 61.4 | 3.9 | 6.5 | 1.4 | 1.4 |
10Ni10Co/Z | - | 11.4 | 3.9 | 9.1 | 3.5 | 60.3 | 5.0 | 4.0 | 1.3 | 1.5 |
Catalysts | Conversion, % | HPA yield, % | GVL yield, % |
---|---|---|---|
10Ni/Z | 35.0 | 8.0 | 27.0 |
10Co/Z | 2.7 | 0.8 | 1.9 |
10Cu/Z | 5.9 | 1.1 | 4.8 |
5Ni5Co/Z | 51.0 | 7.0 | 44.0 |
5Ni5Cu/Z | 63.0 | 10.0 | 53.0 |
10Ni10Co/Z | 99.5 | 14.8 | 84.7 |
10Ni10Cu/Z | 100.0 | 15.0 | 85.0 |
Samples | SBET (m2/g) | Total Pore Volume (cm3/g) | Crystalline Phases | Crystallite Size, nm |
---|---|---|---|---|
10Ni10Co/Z spent | 275 | 0.462 | Ni0/Co0 | 21 |
10Ni10Cu/Z spent | 271 | 0.422 | Cu0, Cu0.81Ni0.19 | 13/13 |
5Ni5Co/Z spent | 256 | 0.379 | Ni0/Co0 | 19 |
5Ni5Cu/Z spent | 279 | 0.400 | NixCu1-x (x~0.5) | 13 |
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content. |
Submitted:
22 November 2023
Posted:
01 December 2023
You are already at the latest version
A peer-reviewed article of this preprint also exists.
Submitted:
22 November 2023
Posted:
01 December 2023
You are already at the latest version
Sample Name | Crystalline Phase | Crystallite Size, (nm) | Reducibility, % |
---|---|---|---|
10 Ni/Z | NiO | 17 | 100 |
10 Co/Z | Co3O4 | 26 | 79 |
10Cu/Z | CuO | 35 | 100 |
10Ni10Co/Z | NiO*/-Co1.3Ni1.7O4*/-Co3O4 | 17*/-26*/-26 | 82 |
10Ni10Cu/Z | NiO/ Ni0.8Cu0.2O*/-CuO | 17*/-35 | 100 |
5Ni5Co/Z | Co1.3Ni1.7O4 | 35 | 100 |
5Ni5Cu/Z | NiO/Ni0.8Cu0.2O*/-CuO | 13*/-21 | 100 |
Samples | SBET (m2/g) | Micropore Volume (cm3/g) | Total Pore Volume (cm3/g) |
---|---|---|---|
10Ni/Z | 115 | 0.019 | 0.169 |
10 Co/Z | 152 | 0.034 | 0.183 |
10Cu/Z | 86 | 0.006 | 0.186 |
10Ni10Co/Z | 82 | 0.015 | 0.133 |
10Ni10Cu/Z | 75 | 0.013 | 0.128 |
5Ni5Co/Z | 111 | 0.020 | 0.159 |
5Ni5Cu/Z | 96 | 0.015 | 0.160 |
Z | 380 | 0.107 | 0.326 |
Samples reduced at 600 °C | |||
10Ni10Co/Z | 181 | 0.047 | 0.130 |
5Ni5Co/Z | 228 | 0.061 | 0.152 |
10Ni/Z | 240 | 0.066 | 0.154 |
Composition, at. % | Cu | Ni | Co | Si | Al | O | Fe | Na | Ca | Mg |
---|---|---|---|---|---|---|---|---|---|---|
10Ni10Cu/Z | 3.2 | 7.3 | - | 10.4 | 4.5 | 61.4 | 3.9 | 6.5 | 1.4 | 1.4 |
10Ni10Co/Z | - | 11.4 | 3.9 | 9.1 | 3.5 | 60.3 | 5.0 | 4.0 | 1.3 | 1.5 |
Catalysts | Conversion, % | HPA yield, % | GVL yield, % |
---|---|---|---|
10Ni/Z | 35.0 | 8.0 | 27.0 |
10Co/Z | 2.7 | 0.8 | 1.9 |
10Cu/Z | 5.9 | 1.1 | 4.8 |
5Ni5Co/Z | 51.0 | 7.0 | 44.0 |
5Ni5Cu/Z | 63.0 | 10.0 | 53.0 |
10Ni10Co/Z | 99.5 | 14.8 | 84.7 |
10Ni10Cu/Z | 100.0 | 15.0 | 85.0 |
Samples | SBET (m2/g) | Total Pore Volume (cm3/g) | Crystalline Phases | Crystallite Size, nm |
---|---|---|---|---|
10Ni10Co/Z spent | 275 | 0.462 | Ni0/Co0 | 21 |
10Ni10Cu/Z spent | 271 | 0.422 | Cu0, Cu0.81Ni0.19 | 13/13 |
5Ni5Co/Z spent | 256 | 0.379 | Ni0/Co0 | 19 |
5Ni5Cu/Z spent | 279 | 0.400 | NixCu1-x (x~0.5) | 13 |
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content. |
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Catalysts,
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et al.
Catalysts,
2019
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