1. Introduction
In contemporary research, power dissipation has emerged as a critical factor across various domains, spanning from the production of miniaturized electronics to nuclear power plants, as highlighted in reviews by [
1,
2,
3]. Within the electronic industry, as MEMS processing technology advances towards high-speed, large buffer memory in smaller devices, there is a growing focus on the extensive study of pool boiling to achieve efficient cooling.
Nucleate boiling proves to be effective in dissipating a substantial heat flux with a minimal temperature difference, facilitating efficient component cooling. In pool boiling, heat is transferred from a surface to liquid in a macroscopic state of rest. The initiation of boiling occurs when the local temperature is sufficiently high to permit the formation and growth of vapor bubbles on surface imperfections. These imperfections or cavities act as nucleation sites for the growth of bubbles, arising from vapor initially trapped within them [
4]. Surface roughness, porosity, and wettability are believed to influence boiling behavior, although bubble nucleation can also take place on a smooth surface without imperfections. In such cases, nucleation energy is contingent upon the contact angle, defined as the angle between a tangent to the liquid surface and the solid surface. Typically, a right angle is considered neutrally wetting, with lesser angles indicating hydrophilic properties and greater angles indicating hydrophobic characteristics. Both hydrophilic and hydrophobic surfaces contribute positively to improving boiling performance, with hydrophilic surfaces aiding in rewetting following bubble departure, and hydrophobic surfaces promoting bubble nucleation seeded by a stored vapor in cavities [
1,
2]. Additionally, the contact angle between the liquid-vapor interface at the bubble base and the surface varies during the stages of bubble growth and departure [
5,
6,
7].
Recent research in nucleate pool boiling has emphasized the development of novel surface manipulation methods to enhance phase-change heat transfer. These methods include mechanical machining, chemical treatments, nanoparticle coatings, and micro-/nanoelectromechanical systems techniques, such as photolithography and reactive ion etching, as well as fiber-laser texturing that avoids additional layers [
8,
9,
10,
11,
12]. In the context of ongoing efforts to improve heat transfer, this study investigates the impact of thermophysical properties on nucleate boiling for two materials with distinct characteristics: copper and silicon oxide. Notably, copper exhibits thermal diffusivity and conductivity two orders of magnitude greater than silicon oxide.
While numerous numerical models and experiments have explored the bubble cycle and precise bubble cycle data [
13,
14,
15], predicting boiling heat transfer remains intricate due to the necessity of considering phenomena occurring over multiple scales—from the adsorbed vapor at the nanometer scale [
16,
17] to the bubble diameter at the millimeter scale. Timescales also vary widely, from microlayer formation at the microsecond scale (
) to evaporation at the millisecond scale (
), significantly contributing to bubble growth [
18,
19,
20,
21,
22]. Our proposed model is highly versatile, spanning multiple scales from nano to milli, and timescales from tenths of milliseconds to minutes, allowing the independent variation of parameters through computational simulations.
Reproducing boiling data is challenging due to contamination and cavity reactivation. Thus, our model analyzes bubble departure frequency in small copper and silicon oxide heaters, maintaining a fixed contact angle and comparing the results to established expressions and experimental data. Focusing on bubble departure frequency, which is simpler to observe during experimentation than other bubble characteristics, serves as a valuable metric for assessing the effectiveness of boiling on a given surface. This frequency is linked to the heater’s dissipation potency, depending on both the growth time of the bubbles and the recovery time of the microlayer of fluid, which rewets and cools the heater upon bubble departure [
23].
Over the past half-century, significant efforts have been directed towards developing heat transfer models to determine these times. A theory presented in [
24] outlines the rate of growth of a vapour bubble from a heated wall in a liquid near its saturation temperature. Predictions from this analysis bear some relation ( 25 per cent) to experimental results under conditions where assumptions are approximately valid. A corrected version is established in [
25], substantially reducing the growth constant of bubbles and approaching experimental results more closely. However, recovery or wait times notably vary in each experiment. An expression for wait time was analytically derived by C.-H. Han and P. Griffith [
26], considering transient heat conduction through the heater at a constant temperature to the microlayer of fluid, but significantly underestimate to experimental values of wait times. In an attempt to bridge this gap, Podowski et al. [
27] consider the wall surface temperature as a time-dependent, fluctuating parameter, solved through a one-dimensional heat conduction equation through the wall. Although this consideration introduces a dependence on wall material properties in wait times, it still deviates from experimental results. In [
28], an empirical relationship is proposed, fitting well with experimental data, and is the one utilized in our model.
Through numerical simulations, this study systematically investigates the effects of the thermophysical properties of the heater on nucleate pool boiling for two distinctly different heater materials, testing the proposed different mechanisms with semi-empirical relationships known in the literature.
4. Conclusions
We analyze the effect of the intrinsic properties of the heater material on nucleate boiling through a model introduced in this work. This model incorporates many ingredients known in the literature, describing the various mechanisms involved in this phenomenon. In experiments, it is impossible to change one parameter without modifying the others. In other words, these experiments are challenging to reproduce even under the same conditions. For example, the vapor trapped in surface imperfections changes significantly from one trial to another, making it difficult to study which mechanism is predominant when comparing results. Simulations allow us to overcome this problem and study changes by modifying one parameter at a time.
We compared two materials,
and
, and found a substantial difference in nucleate boiling refrigeration between a good thermal conductor like
and a poor conductor like
. Even assuming that the properties of both surfaces remain the same, i.e., they have the same density of cavities that can be activated with a certain Gaussian size distribution and that both surfaces maintain the contact angle with the refrigerant liquid, we found that the average bubble frequency varies from one material to another. This is attributed to both the bubble growth time and the time lapse between bubbles generated in the same active cavity, both of which exhibit a notable dependence on the material. We observed an influence of neighboring bubbling sites, especially in
due to its very low thermal conductivity and diffusivity. In fact, temperature variations become highly visible in such materials due to their significant inertia in recovery. Finally, we contrasted the simulation results with a semi-empirical correlation known for the bubble frequency times the departure diameter, obtaining good agreement between them (see Eq. (
16) and
Figure 6).