3.1. Forward Bias
Electrical characterization of devices was performed using a 4156C Precision semiconductor parameter analyzer and a Keithley K2657 Tesla GPIB 24 parameter analyzer. The measured diodes have a diameter of 90 µm and an anode diameter of 50 µm. The current in this study was normalized using an area of cm².
Figure 2a shows the typical forward J-V characteristics in semi-log scale obtained on a GaN pseudo-vertical Schottky diode, showing a low turn-on voltage of ~ 0.6 V defined at J = 1 A/cm
-2 and a good On/Off current ratio of
The device achieves an output current density of ~ 2.5 kA/cm² and low differential specific on-resistance
of 1.9 mΩ.cm² at 5V as shown in Figure (b), despite the expected current crowding effect at the edges in quasi-vertical structures [
19]. The ideality factor n of 1.03 and the Schottky barrier height
of 0.95 eV (consistent with the extracted schottky barrier height from C-V measurement ~ 1.02 eV) were extracted from Equation (2), at room temperature (RT = 300K). The high current on/off ratio and near-unity ideality factor indicate the excellent quality of the Ni/n-GaN interface. These characteristics suggest efficient electron flow when the device is on and minimal leakage when the device is off, showcasing the interface’s effectiveness in controlling current. Additionally, the near-unity ideality factor implies that the diode closely follows ideal diode behavior, indicating that the dominant current is Thermionic Emission TE.
Where is the saturation current, A is the area of the anode contact, A* is the effective Richardson’s constant (theoretically 26.4 A/cm².K2 for GaN), is the Schottky barrier height, q is the elementary charge (1.6), k Boltzmann’s constant, T is the temperature and n is the ideality factor.
Figure 3a,b show the typical temperature-dependent forward characteristics of the SBD. For all measured samples, the T-J-V characteristics show two trends when the forward voltage V is lower (V < ~0.6 V) and higher (V > ~0.6 V). When V is low, the current is dominated by hot electron emission from GaN to Ni/ contact across the Schottky barrier. The higher the temperature, the more electrons have enough energy to cross the Schottky barrier, and the higher the current. On the other hand, when V is higher, the current is limited by electron transport in the n-GaN drift region following the ohmic conduction law. As the temperature increases, the mobility of electrons decreases and the differential Ron,sp increases from 1.9 mΩ.cm² at 25 °C to 2.5 mΩ.cm² at 160 °C, probably due to the reduced electron mobility, attributed to thermally enhanced phonon scattering as shown in the inset of
Figure 3a [
21].
From Equation (2),
and n can be determined from the intercept and the slope of the linear region of ln (J)-V plot respectively. In
Figure 4a, the ideality factor n of several devices increases from 1 to ~ 1.3 ± 0.05 at higher temperature which may indicate the impact of the surface traps on device performance [
20], the extracted n suggest that the current transport mechanism is dominated by the thermionic emission (TE) at low temperature (from 300 K to 375K) and by thermionic field emission (TFE) at higher temperature (T > 375 K). The variation
of barrier height
when the temperature is between 375 and 425 K as shown in
Figure 4a, confirms the impact of traps on the Ni/GaN interface. These results suggest the thermal instability of the Schottky contact of the SBD at high temperatures. [
22]
From calculations as illustrated in
Figure 4b, the experimental Richardson’s constant for several devices determined from the intercept of the linear fitting of Equation (2) of 4.6 ± 0.7 A cm
-2 K
-2. It is suggested that the discrepancy from the theoretical value of 26.64 A K
−2 cm
−2, is due to the quality of the epitaxial layers and inhomogeneity in the barrier [
23].
3.2. Reverse Bias
Figure 5a shows the typical reverse J-V characteristics of the GaN pseudo-vertical SBD. The destructive Breakdwon Voltage BV of the schottky barrier diode is around 80 V, this low voltage capability is mainly related to the absence of edge termination [
17,
18], and in particular due to expected high electric field at the edges of the Schottky contact.
Leakage current in vertical devices has typically been associated with defects in the active layers since the dislocation density is high [
11,
24], in particular for GaN on Si devices.
The physical origin leakage current leakage in Schottky barrier diode SBDs can be either based on the electrical properties at the electrode - Semiconductor interface. These are referred to as electrode - limited conduction mechanisms. Other mechanisms which depend only on the properties of the Semiconductor material itself, These conduction mechanisms are called bulk - limited conduction mechanisms or transport - limited conduction mechanisms. It is crucial to distinguish between these mechanisms, as multiple conduction processes can simultaneously contribute to current flow through the GaN drift layer. Measuring temperature-dependent conduction currents can provide insights to reveal the origin of these currents, given that different mechanisms respond differently to temperature changes. The electrode-limited conduction mechanisms include (1) Schottky or thermionic emission _TE, (2) Fowler-Nordheim tunneling _FNT, (3) direct tunneling or field emission _FE, and (4) thermionic-field emission _TFE. On the other hand, the bulk-limited conduction mechanisms include (1) Poole-Frenkel emission _FPE, (2) hopping conduction, (3) ohmic conduction, (4) space-charge-limited conduction _SCLC, (5) ionic conduction _IC and (6) grain-boundary-limited conduction [
16].
To investigate the reverse leakage mechanisms, temperature dependence of reverse J-V curves for Ni/Au SBDs was measured from 313 to 433 K with voltage up to – 40 V, as shown in
Figure 5b. The characteristics can be divided into three different voltage regions. Region “A”is near zero bias, while region “B” is from -1 to -10 V and region “C” is -10 to -40 V. For Schottky devices under a reverse regime, the voltage is supported across the drift region, forming a depletion layer, with a maximum electric field located at the metal-semiconductor contact. The breakdown voltage is constrained by breakdown at the edges. Edge terminations are necessary to reduce the electric field at their location, leading to behaviour closer to parallel-plane breakdown.
Table 1 summarizes only the possible current transport mechanisms and their electric field and temperature dependencies of Schottky barrier diodes SBDs grown with localized epitaxy, many process were excluded as the most investigations already reported for GaN on Si devices are focused on few mechanisms such as Thermionic emission TE, Frenkel- Poole Emission FPE, Variable Range Hopping VRH, and finally Trapped or Phonon – Assisted Tunneling TAT, PAT [
16].
Where and ND – NA were extracted from CV measurements as mentioned above.
In Region A, the leakage current can be limited by the Schottky contact, for which the conduction mechanism is dominated by Schottky emission. Electrons can gain sufficient energy by thermal excitation; electrons from the metal will overcome the Schottky barrier towards the conduction band. The
Figure 6. Illustrate the Ni / n-GaN energy band diagram when the metal is under negative bias. Thermionic emission mechanism is one of the most observed conduction process in Schottky barriers diodes (SBDs).
Figure 7a shows the reverse ln (J) versus V obtained at different temperatures at voltages from 0 to -0.4 V. The good fit between the experimental data and the Thermionic Emission (TE) model suggests that TE is the main mechanism at near zero bias with barrier lowering of
(The barrier lowering due the image force phenomenon is called Schottky effect). Furthermore, the linear relation between ln (J/T²) and E
1/2, as shown in
Figure 6b, confirms the dominance of this mechanism in this region.
In Region B, by increasing the reverse bias, the leakage current increases with temperature as observed in
Figure 5b. This can be caused by the Frenkel–Poole emission (FPE), which is a process similar to Schottky emission or thermionic emission (TE), involving the thermal excitation of electrons from traps into the semiconductor’s conduction band. This similarity often leads to FPE emission being referred to as internal Schottky emission. In this context, when an electron is in a trap, an applied electric field across the dielectric film can reduce the electron’s Coulomb potential energy. This reduction in potential energy may increase the probability of an electron being thermally excited from the trap into the conduction band. The schematic energy band diagram of the FP emission is shown in
Figure 8.
According to the FPE equation, ln (J/E) should have a linear relationship with the square root of electric field (Note that the electric field strength (E) was calculated using the Equation (3)) as shown in
Figure 9, which indicates that FPE is the dominant leakage process in region B.
In such a case,
A(
T) and
B(
T) are the intercept and slope of the ln (
J /
E) versus
E1/2 plot and are defined as:
From
Figure 10a, the trap level for FPE extracted from the linear fitting of Equation (4) is found at
below the conduction band. They could be possibly related to nitrogen or gallium vacancies V
N -V
Ga and nitrogen antisite N
Ga- related defect [
29]. However, further experiments like characterization by deep level transient spectroscopy DLTS are needed to confirm these observed traps. In addition, the relative dielectric constant of GaN has been extracted,
from the linear fitting of Equation (5) as shown in
Figure 10b. Furthermore, this was confirmed by the extracted Frenkel Poole coefficient β
FP of 3.13 x 10
-4 eV V
-1/2 cm
1/2. These values are in good agreement with reported values for GaN (5.4 and 7 x 10
-4 eV V
-1/2 cm
1/2 for
and β
FP, respectively) [
28,
29], and confirm the domination of FPE at region B with voltage range -0.5 to -10 V.
Finally, in region C, when the reverse bias increases up to -40 V with a corresponding Electric field up to 1.1 MV/cm, the leakage current becomes insensitive to the temperature. This indicates that the reverse leakage is mainly dominated by variable range hopping (VRH), for which the increased electric field distort the energy band and make it steeper. The steeper VRH band results in a shorter hopping from the Schottky Fermi level and the VRH level in GaN. Therefore, electrons could hop more easily from the Schottky metal to the GaN drift layer [
30,
31]. The schematic energy band diagram of the FP emission is illustrated in
Figure 11.
The clear linear relationship between ln (J) and E is demonstrated, as shown in
Figure 12a, suggest the dominance of VRH.
Figure 12b shows an Arrhenius plot of the reverse current at several voltages versus the inverse of the temperature. At high field, the current has a lower temperature dependency and follows Mott’s law [ln
]. The extracted characteristic temperature T
0 is 2.2 ± 1.1 x 10
7 K, which is within the typical range of 10
6- 10
9 K and is consistent with reported values in the literature (4.92 x 10
7 for N
D ~ 3 x 10
16 cm
-3) [
32,
33].
The investigated mechanisms were further confirmed by having the differential slope d[log(ln(J))] / dlog(E) as presented in
Figure 13, where J is the current density and E is the applied electric field in the depletion region. When d[log(ln(J))]/dlog(E) is around 0.5, the Frenkel – Poole emission (FPE) process is the dominant leakage mechanism. On the other side, if d [log (ln(J))] / dlog(E) is close to 1, the variable range hopping (VRH) dominates the leakage current [
26].
Figure 14, summarizes and illustrates the different leakage mechanisms revealed by temperature dependent study of GaN-on-Si quasi-vertical SBD grown by localized epitaxy. At region A, Thermionic Emission (TE) dominates the leakage current since the applied voltage has a negligible impact on the Schottky barrier, which electrons transport from metal to the n-GaN layer. As the bias increases, trapped electrons gains sufficient energy to surmount the trap state, which can be referred to the Frenkel-Poole Emission (FPE) process. Finally, at region C, the increasing electric field reduces the hopping distance from the metal to trap states, which allows the electrons to hop easily from the Schottky metal to the conduction band of GaN drift layer, which is referred to Variable Range Hopping (VRH). These leakage mechanisms are in agreement with previously reported studies for GaN devices [
34,
35,
36].