Preprint Article Version 1 This version is not peer-reviewed

Dual-Phase High Entropy Alloy for High-Temperature Application

Version 1 : Received: 24 July 2024 / Approved: 24 July 2024 / Online: 24 July 2024 (13:10:07 CEST)

How to cite: Lastovich, M.; Kareem, S. A.; Bodunrin, M.; Rock, C.; Gwalani, B. Dual-Phase High Entropy Alloy for High-Temperature Application. Preprints 2024, 2024071945. https://doi.org/10.20944/preprints202407.1945.v1 Lastovich, M.; Kareem, S. A.; Bodunrin, M.; Rock, C.; Gwalani, B. Dual-Phase High Entropy Alloy for High-Temperature Application. Preprints 2024, 2024071945. https://doi.org/10.20944/preprints202407.1945.v1

Abstract

High temperature Ni-superalloys are limited by reliance on critical elements and complex processing steps. High entropy alloys (HEAs) have demonstrated stable single/dual phase microstructures with strong ordering tendencies. A dual phase (FCC+BCC) Al0.5Co0.5CrFeNi1.5Ti0.25 alloy (developed using CALPHAD) was tested for room and high temperature compression behavior. The microstructure mainly comprises of coarse ordered FCC(L12) surrounding decomposed lamellae of ordered FCC(L12) and BCC(L21) phases, which coarsened upon annealing at high temperature (1100 °C) into a bi-continuous structure of disordered FCC+BCC(B2). Additionally, cold rollability of the cast alloy increased from <5% to ~40% after annealing, with a corresponding softening observed in room temperature compression mainly due to disordering of FCC and BCC phases. Peak flow stresses of 793.45MPa, 535.12MPa, and 324.40MPa were achieved at 800oC, 900oC, and 1000oC respectively for the high temperature annealed alloy.

Keywords

high entropy alloys; alloy design; high temperature properties; order-disorder transformations; Gleeble; in situ X-Ray diffraction; DSC; precipitation strengthening; compression; rollability

Subject

Engineering, Metallurgy and Metallurgical Engineering

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