Preprint Article Version 1 This version is not peer-reviewed

Carbon-based in-situ Ti-TiC Metal Matrix Composite manufactured by Laser Powder Bed Fusion

Version 1 : Received: 6 August 2024 / Approved: 7 August 2024 / Online: 7 August 2024 (07:02:37 CEST)

How to cite: Bernard, G.; Pejchal, V.; Sereda, O.; Logé, R. E. Carbon-based in-situ Ti-TiC Metal Matrix Composite manufactured by Laser Powder Bed Fusion. Preprints 2024, 2024080485. https://doi.org/10.20944/preprints202408.0485.v1 Bernard, G.; Pejchal, V.; Sereda, O.; Logé, R. E. Carbon-based in-situ Ti-TiC Metal Matrix Composite manufactured by Laser Powder Bed Fusion. Preprints 2024, 2024080485. https://doi.org/10.20944/preprints202408.0485.v1

Abstract

This study outlines a 3-step production process for Ti-TiC Metal Matrix Composite (MMC) employing powder Mechanical Blending, Laser Powder Bed Fusion (LPBF), and a heat treatment. A TiC fraction of more than 20 vol% was formed in-situ through the reaction of titanium with carbon during the LPBF process. The manufactured MMC pieces showed a record stiffness and fracture strain combination. The LPBF energy density impacted strongly porosity type. The as-built microstructure displayed an homogeneous distribution of sub-stoichiometric TiC dendrites which were fully converted into equiaxed TiC grains during the heat treatment. The TiC C/Ti ratio was found to be close to 0.5, resulting in an effective reinforcement content nearly twice the one expected for stoichiometric TiC, leading to stronger reinforcement. The mechanical analysis revealed a Young’s modulus of up to 149 GPa and an ultimate tensile strength of up to 770 MPa, indicating a 27% and 34% improvement, respectively, compared to commercially pure Titanium produced by LPBF and heat treated in the same conditions. A fracture strain of up to 2.8% was achieved. The combination of in-situ formation of defect-free TiC reinforcement and subsequent heat treatment enables to reach an exceptional ductility, considering the 20 vol% reinforcement content.

Keywords

Metal Matrix Composite; In-situ Composite; Laser Powder Bed Fusion; Titanium; Titanium Carbide; Mechanical Property

Subject

Chemistry and Materials Science, Ceramics and Composites

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