Version 1
: Received: 10 September 2024 / Approved: 10 September 2024 / Online: 10 September 2024 (15:43:25 CEST)
How to cite:
Saffon-Merceron, N.; Lherbet, C.; Hoffmann, P. Synthesis and Characterization of N-Nitrososydnonimine as NO. Donor. Preprints2024, 2024090838. https://doi.org/10.20944/preprints202409.0838.v1
Saffon-Merceron, N.; Lherbet, C.; Hoffmann, P. Synthesis and Characterization of N-Nitrososydnonimine as NO. Donor. Preprints 2024, 2024090838. https://doi.org/10.20944/preprints202409.0838.v1
Saffon-Merceron, N.; Lherbet, C.; Hoffmann, P. Synthesis and Characterization of N-Nitrososydnonimine as NO. Donor. Preprints2024, 2024090838. https://doi.org/10.20944/preprints202409.0838.v1
APA Style
Saffon-Merceron, N., Lherbet, C., & Hoffmann, P. (2024). Synthesis and Characterization of N-Nitrososydnonimine as NO. Donor. Preprints. https://doi.org/10.20944/preprints202409.0838.v1
Chicago/Turabian Style
Saffon-Merceron, N., Christian Lherbet and Pascal Hoffmann. 2024 "Synthesis and Characterization of N-Nitrososydnonimine as NO. Donor" Preprints. https://doi.org/10.20944/preprints202409.0838.v1
Abstract
N-Nitroso-3-morpholinosydnonimine 3 was prepared by nitrosation of SIN-1 and characterized by 1H-NMR, 13C-NMR and HRMS. Its structure, confirmed by single crystal X-ray diffraction analysis, was found in agreement with its mesoionic and aromatic character. Unlike SIN-1, which releases both nitric oxide and superoxide radical, decomposition of this nitrosylated sydonimine could yield nitric oxide as the only decomposition product, and thus without the formation of toxic peroxynitrite.
Keywords
Sydnone; Sydnonimine; Imine; Nitric oxide; SIN-1
Subject
Chemistry and Materials Science, Organic Chemistry
Copyright:
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
