Preprint Article Version 1 This version is not peer-reviewed

Application of Κ-Carrageenan for One-Pot Synthesis of Hybrids of Curcumin Natural with Iron and Copper: Stability Analysis and Application in Papilloscopy

Danielle Tapia Bueno
ORCID logo ,
Amanda Fonseca Leitzke
,
Juliana Porciúncula da silva
ORCID logo ,
Daisa Hakbart Bonemann
,
Gabrielly Quartieri Sejanes
,
Bruno Nunes da Rosa
,
Tais Poletti
,
Guilherme Kurz Maron
ORCID logo ,
Bruno Vasconcellos Lopes
,
Matheus de Paula Goularte
ORCID logo ,
Darci Alberto Gatto
,
André Luiz Missio
ORCID logo ,
Neftali Lenin Villareal Carreno
,
Claudio Martin Pereira de Pereira
*
Version 1 : Received: 9 October 2024 / Approved: 9 October 2024 / Online: 10 October 2024 (10:21:06 CEST)

How to cite: Bueno, D. T.; Leitzke, A. F.; da silva, J. P.; Bonemann, D. H.; Sejanes, G. Q.; da Rosa, B. N.; Poletti, T.; Maron, G. K.; Lopes, B. V.; Goularte, M. D. P.; Gatto, D. A.; Missio, A. L.; Carreno, N. L. V.; de Pereira, C. M. P. Application of Κ-Carrageenan for One-Pot Synthesis of Hybrids of Curcumin Natural with Iron and Copper: Stability Analysis and Application in Papilloscopy. Preprints 2024, 2024100766. https://doi.org/10.20944/preprints202410.0766.v1 Bueno, D. T.; Leitzke, A. F.; da silva, J. P.; Bonemann, D. H.; Sejanes, G. Q.; da Rosa, B. N.; Poletti, T.; Maron, G. K.; Lopes, B. V.; Goularte, M. D. P.; Gatto, D. A.; Missio, A. L.; Carreno, N. L. V.; de Pereira, C. M. P. Application of Κ-Carrageenan for One-Pot Synthesis of Hybrids of Curcumin Natural with Iron and Copper: Stability Analysis and Application in Papilloscopy. Preprints 2024, 2024100766. https://doi.org/10.20944/preprints202410.0766.v1

Abstract

In this study, hybrid materials were synthesized incorporating curcumin, Cu²⁺ or Fe³⁺, and Kappa-carrageenan as a reducing agent to improve its stability, considering that curcumin has low thermal and solution stability, which limits its applications. Colorimetric analysis showed color changes in the hybrids, ultraviolet-visible spectroscopy revealed band shifts in the hybrids, and infrared analysis indicated shifts in wavenumbers, suggesting changes in the vibrational state of curcumin after bonding with metal ions. These techniques confirmed the formation of the hybrid materials. Thermogravimetric and chromatographic analyses demonstrated greater thermal and solution stability for the hybrids compared to curcumin. Additionally, the hybrid composites effectively developed natural and sebaceous latent fingerprints with good clarity and contrast on glass surfaces. Both composites performed similarly to commercial gold powder. When applied to surfaces representative of forensic scenarios, the composites were versatile, revealing sufficient fingerprint details for human identification on both porous and non-porous surfaces. Scanning electron microscopy images showed greater clarity in sebaceous and natural fingerprints developed with the Fe composite compared to the Cu composite, due to minimal interaction of Fe with the glass surface.

Keywords

Curcumin; hybrid materials; stability in solution; thermal stability; papilloscopy

Subject

Chemistry and Materials Science, Materials Science and Technology

Copyright: This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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