Preprint Article Version 1 This version is not peer-reviewed

Laponite vs. Montmorillonite as Eugenol Nanocarriers for Low Density Polyethylene Active Packaging Films

Version 1 : Received: 5 November 2024 / Approved: 5 November 2024 / Online: 5 November 2024 (10:01:16 CET)

How to cite: Kechagias, A.; Salmas, C. E.; Chalmpes, N.; Leontiou, A. A.; Karakassides, M. A.; Giannelis, E. P.; Giannakas, A. E. Laponite vs. Montmorillonite as Eugenol Nanocarriers for Low Density Polyethylene Active Packaging Films. Preprints 2024, 2024110286. https://doi.org/10.20944/preprints202411.0286.v1 Kechagias, A.; Salmas, C. E.; Chalmpes, N.; Leontiou, A. A.; Karakassides, M. A.; Giannelis, E. P.; Giannakas, A. E. Laponite vs. Montmorillonite as Eugenol Nanocarriers for Low Density Polyethylene Active Packaging Films. Preprints 2024, 2024110286. https://doi.org/10.20944/preprints202411.0286.v1

Abstract

This study investigates the use of two nanoclays, Laponite (Lap) and Montmorillonite (Mt), as eugenol slow release carriers for enhancing the functionality of low-density polyethylene (LDPE) active packaging films. Utilizing a vacuum-assisted adsorption method, eugenol was successfully intercalated into Lap and Mt nanoclays, forming EG@Lap and EG@Mt nanohybrids. The nanohybrids were subsequently incorporated into LDPE films at varying concentrations (5, 10, and 15 wt.%). Extensive characterization by a number of analytical techniques confirmed effective integration and dispersion of the nanohybrids within the LDPE matrix. EG@Lap and EG@Mt nanohybrids enhanced the films’ antioxidant and barrier properties, with EG@Lap demonstrating higher eugenol release rates, antioxidant activity, and barrier effectiveness. Packaging tests on minced pork revealed that the LDPE/15EG@Lap films extended shelf life by approximately two days more compared to the LDPE/15EG@Mt films, due to the higher eugenol release. These findings suggest that EG@Lap-based films offer improved active packaging capabilities, with potential applications in a number of areas where extending the freshness of perishable foods is needed.

Keywords

laponite; Montmorillonite; Eugenol; LDPE; nanohybrids; active packaging; control release; pork minced shelf-life 

Subject

Chemistry and Materials Science, Nanotechnology

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