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Mixed Pt-Ni Halide Perovskites for Photovoltaic Application

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Submitted:

17 November 2024

Posted:

19 November 2024

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Abstract

Cs2PtI6 is a promising photoabsorber with direct bandgap of 1.4 eV and high carrier lifetime, however, the cost of Pt inhibits its commercial viability. Here, we explore the effect of replacing Pt with earth-abundant Ni in solution-processed Cs(PtxNi1-x)(I,Cl)3 thin-films on the properties and stability of the perovskite material. Films fabricated with CsI and PtI2 precursors result in perovskite phase with bandgap of 2.13 eV which transitions into stable Cs2PtI6 with a bandgap of 1.6 eV upon annealing. Complete substitution of PtI2 in films with CsI + NiCl2 precursors results in a wider bandgap of 2.35 eV and SEM shows 2 phases- a rod-like structure identified as CsNi(I,Cl)3 and residual white particles of CsI, also confirmed by XRD and Raman spectrum. Upon extended thermal annealing, the bandgap reduces to 1.65 eV and transforms to CsNiCl3 with a peak shift to higher 2-theta. Partial substitution of PtI2 with NiCl2 in mixed 50-50 Pt-Ni-based films produces a bandgap of 1.9 eV exhibiting a phase of Cs(Pt,Ni)(I,Cl)3 composition. A similar bandgap of 1.85 eV and the same diffraction pattern with improved crystallinity is observed after 100 hours of annealing, confirming the formation of a stable mixed Pt-Ni phase.

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Subject: Engineering  -   Energy and Fuel Technology
Copyright: This open access article is published under a Creative Commons CC BY 4.0 license, which permit the free download, distribution, and reuse, provided that the author and preprint are cited in any reuse.
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