The last decades have offered new challenges to researchers worldwide through the problems our planet is facing both in the environment protection field and the need to replace fossil fuels with new environmentally friendly alternatives. Bioenergy as a form of renewable energy is an acceptable option from all points of view and biofuels due to their biological origin have the ability to satisfy the new needs of humanity. By releasing some non-polluting combustion products into the atmosphere, biofuels have already been adopted as additives in traditional liquid fuels, being intended mainly for internal combustion engines of automobiles. The current work proposes an extension of biofuels application in combustion processes specific to industrial furnaces. This technical concern is not found in the literature, except for achievements of the research team involved in this work, which has performed previous investigations. A 51.5 kW-burner was designed to operate with glycerine originating from triglycerides of plants and animals, mixed with ethanol, an alcohol produced by the chemical industry recently used as an additive in gasoline for automobile engines. Industrial oxygen was chosen as the oxidizing agent necessary for the liquid mixture combustion, allowing to obtain much higher flame temperatures compared to the usual combustion processes using air. Mixing glycerine with ethanol in 8.8 ratio allowed growing flame stability, accentuated also by creating swirl currents in the flame through the speed regime of fluids at the exit from the burner body. Results were excellent both through the flame stability and low level of polluting emissions.