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Ventilation and Bedding Effects on Air Quality in Swine Confinement Systems
Hong Lim Choi,
Andi Febrisiantosa,
Anriansyah Renggaman,
Sartika Indah Amalia Sudiarto,
Chan Nyeong Yun,
Arumuganainar Suresh
Posted: 03 January 2025
Urban Green Space Measurements: A Narrative Review of Practical Applications
Doo-Hong Lee,
Brent Chamberlain,
Hye-Yeon Park
Posted: 03 January 2025
YS3AM: Adaptive 3D Reconstruction and Harvesting Target Detection for Clustered Green Asparagus
Si Mu,
Jian Liu,
Ping Zhang,
Jin Yuan,
Xuemei Liu
Posted: 03 January 2025
Integrating Synthetic Data and Deep Learning for Enhanced Defect Detection and Quality Assurance in Manufacturing Processes
Armin Moghadam,
Sahib Bhatia,
Fatemeh Davoudi Kakhki,
Hiroyuki Ichikawa
Posted: 03 January 2025
Assessment of the Inter and Intra-Individual Variability in the Jump of Agility Dogs
Patricia López,
Luna Gutiérrez-Cepeda,
Francisco Miró
Posted: 03 January 2025
Updates In Common Genetic Variants May Help Guide Drug Selection For Treating Uncontrolled Diabetes
Shadi Bazzazzadehgan,
Zia Shariat-Madar,
Fakhri Mahdi
Posted: 03 January 2025
Design, Manufacturing, and Economic Analysis of Parametric Open-Source 3-D Printed Easy Connect Pipe Fittings
Abolfazl Taherzadeh Fini,
Cameron Brooks,
Alessia Romani,
Anthony G. Straatman,
Joshua Pearce
Posted: 03 January 2025
Experimental Assessment on Multiple Properties of Mycelium-Based Composites with Sewage Sludge and Bagasse
Min Hu,
Xuejuan Cao
Posted: 03 January 2025
Weaponized IoT: A Comprehensive Comparative Forensic Analysis of Hacker Raspberry Pi and PC Kali Linux Machine
Mohamed Chahine Ghanem,
Eduardo Almeida Palmieri,
Wiktor Sowinski-Mydlarz,
Sahar Al-Sudani,
Dipo Dunsin
Posted: 03 January 2025
Design, Synthesis, and Tribological Behavior of an Eco-Friendly Methylbenzotriazole-Amide Derivative
Fan Yang,
Zenghui Li,
Hongmei Yang,
Yanan Zhao,
Xiuli Sun,
Yong Tang
Benzotriazole and its derivatives show good tribological properties, anti-oxidation, anti-corrosion, rust prevention and dispersion capabilities as lubricating additives, becoming the common multifunctional additives. And how to avoid sulfur- or phosphorus-introduction to improve their functionality and the compatibility with hydrocarbons is the forefront research. In this study, methylbenzotriazole and oleic acid were applied to synthesize a new methylbenzotriazole-amide that with long alkyl-chain (E)-N-(2-(5-methyl-2H-benzodiazole-2-yl)ethyl)octadec-9-enamide (MeBz-2-C18), which was characterized by nuclear magnetic resonance (NMR), high-resolution mass spectrometry (HR-MS), FT-IR and thermogravimetric analysis (TGA). The thermal stability and tribological properties of MeBz-2-C18 were compared with the commercially available benzotriazole oleamide (T406). The results show that MeBz-2-C18 has better thermal stability and base oil compatibility than that of T406, and 0.5 wt.% addition of MeBz-2-C18 could decrease the average wear scar diameter (ave. WSD) by 21.6%. The wear surface analysis and DFT calculation show that the amide group in MeBz-2-C18 is preferentially broken during friction, which would reduce the interfacial shear force and easily react with the metal surface to form iron oxide film, thus demonstrating a better anti-wear and friction reducing performance, indicating its potential application as an environmental friendly multifunctional additive.
Benzotriazole and its derivatives show good tribological properties, anti-oxidation, anti-corrosion, rust prevention and dispersion capabilities as lubricating additives, becoming the common multifunctional additives. And how to avoid sulfur- or phosphorus-introduction to improve their functionality and the compatibility with hydrocarbons is the forefront research. In this study, methylbenzotriazole and oleic acid were applied to synthesize a new methylbenzotriazole-amide that with long alkyl-chain (E)-N-(2-(5-methyl-2H-benzodiazole-2-yl)ethyl)octadec-9-enamide (MeBz-2-C18), which was characterized by nuclear magnetic resonance (NMR), high-resolution mass spectrometry (HR-MS), FT-IR and thermogravimetric analysis (TGA). The thermal stability and tribological properties of MeBz-2-C18 were compared with the commercially available benzotriazole oleamide (T406). The results show that MeBz-2-C18 has better thermal stability and base oil compatibility than that of T406, and 0.5 wt.% addition of MeBz-2-C18 could decrease the average wear scar diameter (ave. WSD) by 21.6%. The wear surface analysis and DFT calculation show that the amide group in MeBz-2-C18 is preferentially broken during friction, which would reduce the interfacial shear force and easily react with the metal surface to form iron oxide film, thus demonstrating a better anti-wear and friction reducing performance, indicating its potential application as an environmental friendly multifunctional additive.
Posted: 03 January 2025
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