Bulukumba Regency, South Sulawesi, Indonesia is one of the centres for whiteleg shrimp, Litopenaeus vannamei production that applies intensive technology. However, no information has been obtained regarding the characteristics and status of water quality in coastal areas with environmentally friendly concepts and the potential to receive a waste load. The study aimed to determine the performance of whiteleg shrimp culture in relation to temporal and spatial aspects and characteristic and water quality status. Measurement and sampling of water were carried out before stocking/initial of culture whiteleg shrimp (rainy season) and end of culture/after harvesting of whiteleg shrimp (dry season) at two locations in the coastal area of ​​Bulukumba Regency, namely Bonto Bahari Subdistrict (BB) and Gantarang Subdistrict (GT). Variables measured and analyzed included temperature, salinity, pH, dissolved oxygen, nitrate, nitrite, ammonia, phosphate, total suspended solids, and total organic matter. Data analysis with descriptive statistics, multivariate statistics, and non-parametric statistics. The Storet (Storage and Retrieval) method was used to determine the water quality status. The results showed that the culture of whiteleg shrimp was technology-intensive with a stocking density of 110 - 220 ind/m² with productivity between 13.9 - 44.4 tons/ha/cycle. The predicted waste load of N is 28.00 tons/cycle and P reaches 6.61 tons/cycle. Another result was that changes in water quality status during the rainy season were classified as moderately polluted at the BB location and complying quality standards at the GT location, while in the dry season, both locations were categorized as heavily polluted. Variables of water quality that caused the decrease in water quality status in both locations (BB and GT) were observed to increase salinity, nitrate concentration, and ammonia concentration. However, there was a decrease in dissolved oxygen concentration in the dry season.

Water is essential for all living things however its pain has become serious. Many industrial activities cause its pollution by the release of polluting byproduct. Waste water treatment is hence necessary. In this context, the waste water of the textile industry containing Red Acid 52 was treated by the solid waste of the washed natural phosphate byproduct. Natural phosphate was also studied. The solid materials were first characterized by chemical analysis, Fourier Transform Infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The phosphate materials were after that, tested in the adsorption of the Red Acid 52. The experimental data indicated that the phosphate waste rock allowed the removal of Red Acid 52. Its maximum retention capacity attained 18.4 mg.g-1. Calcinations of materials inhibits the removal capacity found reduced by 60 to 70%. The adsorption kinetics of the Red Acid 52 on the material is well described by the pseudo second order model while the adsorption isotherms are identified by the Langmuir model. Hereafter, the thermodynamic study revealed that the adsorption process is spontaneous and exothermic. Keywords: Waste water, Phosphate co-product, Adsorption, Red Acid 52.

The concern about consuming eco-friendly products has motivated research in the development of new materials. Therefore, films based on natural polymers have been used to replace traditional polymers. This study consists of a production of films based on gelatin reinforced with black pepper essential oil-loaded nanoemulsions and Cloisite Na⁺. The films were characterized by water vapor permeability, mechanical and thermal properties, surface contact angle, X-ray diffraction and scanning electron microscopy. It was observed that the films containing the nanoemulsion have higher permeability values and an increase in their mechanical resistance. The addition of nanoclay contributed to an increase in the surface hydrophobicity of the film and an increase in the tensile strength at break by about 150%. The addition of essential oil nanoemulsions led to an increase in thermal stability. The presence of clay dispersion contributed to the formation of a surface that was slightly rougher and grainier. The addition of the black pepper essential oil nanoemulsion resulted in an increase in porosity of the gelatin matrix. Through X-ray diffraction analysis, it was possible to conclude that both the polymeric gelatin matrix and the essential oils nanoemulsion are intercalated with the clay dispersion.

This work describes a method to carry out 2-D inversion of gravity data in terms of porosity and matrix density distribution using previous DC resistivity inversion results to constraint the fractional pore-water content in the rocks. The inversion is carried out using a controlled random search (CRS) algorithm for global optimization. The method was tested on synthetic data generated from a model representing a graben, and the results show that it can estimate accurate values of contrast-density and porosity. The method was also applied to gravity and dc experimental data collected in NE Portugal, showing results that agree quite well with the known geological information.

The Florida Keys, a delicate archipelago of sub-tropical islands extending from the south-eastern tip of Florida, host the vast majority of the only coral barrier reef in the continental United States. Abiotic as well as microbial components of the surrounding waters are pivotal for the health of reef habitats, and thus could play an important role in understanding the development and transmission of coral diseases in Florida. In this study, we analyzed microbial community structure and abiotic factors in waters around the Florida Reef Tract. Both, bacterial and eukaryotic community structure were significantly linked with variations in temperature, dissolved oxygen and total organic carbon values. High abundances of copiotrophic bacteria as well as several potentially harmful microbes, including coral pathogens, fish parasites and taxa that have been previously associated with Red Tide and shellfish poisoning were present in our datasets and may have a pivotal impact on reef health in this ecosystem.

Currently, a large part of the wells for agricultural use located in the state of Sonora are overexploited, which generates a high degree of saline intrusion and abandonment by nearby communities. In this paper the temperature effect on the final concentration of permeate water was evaluated through voltage and intel concentration variations in a batch electrodialysis reversal process (EDR), in order to identify optimal operating conditions with emphasis on the reduction of energy consumption and cost of desalinated water. Thirty-six samples were prepared: eighteen 2,000 mg/L total dissolved solids (TDS) samples and eighteen 5,000 mg/L TDS samples; brackish well water of 639 mg/L TDS and synthetic salt were mixed to obtain those concentrations. 3 different temperatures (25, 30, 35 °C) and 2 different voltages (10 and 20 V) were tested for each sample. The best salt removal occurred in the 20 V arrays, with 18.34% higher removal for 2,000 mg/L TDS experiments and 25.05% for 5,000 mg/L experiments (average between the 25 to 35 °C tests). Temperature positively affected EDR, especially in the experiments at 10 V voltage, where increasing 10 °C increased its efficiency by 10.83% and 24.69% for 2,000 and 5,000 mg/L TDS, respectively. Energy consumption was lower with increasing temperature (35 °C), as it decreased by 1.405% and 1.613% for 2,000 and 5,000 mg/L TDS concentrations, respectively (average between 10 and 20 V tests), decreasing the cost per m3 of water.

Two types of trenches cross-section in conventional vertical and brand new reverse-V-shape have fabricated on SCD substrate by micro-jet water-assist laser, the epitaxial lateral overgrowth technique has applied by microwave plasma chemical vapor deposition system in forming multiple micrometer-size channels. Raman and SEM techniques have applied in analyze both types growth layer characterization. Optical microscope has used to test microchannels hollowness. As a result, with the brand new reverse-V-shape trench, epitaxial lateral overgrowth layer reaches higher SCD surface morphology and crystal quality.

Recently, we have witnessed a booming development of composites and multi-dopant metal oxides to be employed as novel photocatalysts. Yet the practical application of photocatalysis for environmental purposes is still elusive. Concerns about the unknown fate and toxicity of nanoparticles, unsatisfactory performance in real conditions, mass transfer limitations and durability issues have so far discouraged investments in full-scale applications of photocatalysis. Herein, we provide a critical overview of the main challenges that are limiting large-scale application of photocatalysis in air and water/wastewater purification. We then discuss the main approaches reported in the literature to tackle these shortcomings, such as the design of photocatalytic reactors that retain the photocatalyst, the study of degradation of micropollutants in different water matrices, and the development of gas-phase reactors with optimized contact time and irradiation. Furthermore, we provide a critical analysis of research-practice gaps such as treatment of real water and air samples, degradation of pollutants with actual environmental concentrations, photocatalyst deactivation, and cost and environmental life-cycle assessment.

NMR Spectroscopy is used, in the temperature range 180-350K, to study local order and transport in liquid water (pure and confined) and its solutions with glicerol and methanol at different molar fractions. Being the liquid water thermodynamic dominated by polymorphism (two coexisting liquid phases: high- and low-density HDL and LDL) - with the LDL due to the hydrophilic HB interactions, originating in the supercooled regime the tetrahedral networking and the liquid-liquid transition – we focused our interest to hydrophobic effects (HE) on these. Nowadays, if compared to the hydrophilicity, little is known about hydrophobicity so that the main purpose of this study is to gain new information on it. We measured the relaxation times (T1 and T2) and the self-diffusion (DS). From the times we took advantage of the NMR property to follow the behaviors of each molecular component (the hydrophilic and hydrophobic groups) separately; they are studied directly and DS in terms of the Adam-Gibbs model: obtaining the configurational entropy (Sconf ) and the specific heat contributions (CP,conf ). Due to the HE all the studied quantities, behave differently. For water-glycerol the HB interaction is dominant for all the conditions, whereas for water-methanol are observable two different T-regions above and below 265 K, dominated respectively by the hydrophilicity and hydrophobicity. A situation linked to the water polymorphism. Below this temperature, where the LDL phase and the HB networking develops and grows, the times and CP,conf change behaviors leading to maxima and minima. Above it, where the HB becomes weak and less stable and the HDL dominates, the hydrophobicity determines the solution properties.

The diffusion process of water molecules within a polyetherimide (PEI) glassy matrix has been analyzed by combining the experimental analysis of water sorption kinetics performed by FTIR spectroscopy with theoretical information gathered from Molecular Dynamics simulations and with the expression of water chemical potential provided by a non-equilibrium lattice fluid model able to describe the thermodynamics of glassy polymers. This approach allowed to construct a convincing description of the diffusion mechanism of water in PEI providing molecular details of the process related to the effects of the cross- and self-hydrogen bondings established in the system on the dynamics of water mass transport.

Eco-friendly and low-cost water-based nanolubricants containing rutile TiO2 nanoparticles (NPs) were developed for accelerating their applications in industrial-scale hot steel rolling. The lubrication performance of developed nanolubricants was evaluated in a 2-high Hille 100 experimental rolling mill at a rolling temperature of 850 ℃ in comparison to that of pure water. The results indicate that the use of nanolubricant enables to decrease the rolling force, reduce the surface roughness and the oxide scale thickness, and enhance the surface hardness. In particular, the nanolubricant consisting of 4 wt% TiO2, 10 wt% glycerol, 0.2 wt% sodium dodecyl benzene sulfonate (SDBS) and 1 wt% Snailcool exhibits the best lubrication performance by lowering the rolling force, surface roughness and oxide scale thickness up to 8.1%, 53.7% and 50%, respectively. The surface hardness is increased by 4.4%. The corresponding lubrication mechanisms are attributed to its superior wettability and thermal conductivity associated with the synergistic effect of rolling, mending and laminae forming that are contributed by TiO2 NPs.

Dissolved Oxygen (DO) concentration is a vital parameter that indicates water quality. DO short term forecasting using time series analysis on data collected from an aquaculture pond is presented here. This can provide data support for an early warning system for an improved management of the aquaculture farm. The conventional forecasting approaches are commonly characterized by low accuracy and poor generalization problems. In this article, we present a novel hybrid DO concentration forecasting method with ensemble empirical mode decomposition (EEMD) based LSTM (Long short-term memory) neural network (NN). With this method, first, the sensor data integrity is improved through linear interpolation and moving average filtering methods of data preprocessing. Next, the EEMD algorithm is applied to decompose the original sensor data into multiple intrinsic mode functions (IMFs). Finally, the feature selection is used to carefully select IMFs that are strongly correlated with the original sensor data and integrate both into inputs for the NN. The hybrid EEMD-based LSTM forecasting model is then constructed. Performance of this proposed model in training and validation sets was compared with the observed real sensor data. To obtain the exact evaluation accuracy of the forecasted results of the hybrid EEMD-based LSTM forecasting model, three statistical performance indices were adopted: MAE, MSE, and RMSE. Results presented for short term (12-hour period) and long term (1-month period) give a strong indication of suitability of this method for forecasting DO values.

The quantified residence time distribution (RTD) provides a numerical characterization of mixing in the continue casting tundish, thus allowing the engineer to better understand the metallurgical performance of the reactor. This paper describes a computational fluid dynamic (CFD) modelling study for analyzing the flow pattern and the residence time distribution in a five-strand tundish. Two passive scalar transport equations are applied to separately calculate the E-curve and F-curve in the tundish. The numerical modelling results are compared to the water modelling results for the validation of the mathematical model. The volume fraction of different flow regions (plug, mixed and dead) and the intermixing time during the ladle changeover are calculated to study the effects of the flow control device (FCD) on the tundish performance. The result shows that a combination of the U-baffle with deflector holes and the turbulence inhibitor has three major effects on the flow characteristics in the tundish: i) reduce the extent of the dead volume; ii) evenly distribute the liquid streams to each strand and iii) shorten the intermixing time during the ladle changeover operation.

Governments all over the world are currently grappling with the COVID-19 pandemic. While some countries were very hard hit, others were only mildly hit but all are still taking measures to mitigate the consequences. The virus emerged in December 2019 in Wuhan, China and spread to most continents by the beginning of March 2020, which led to the World Health Organization declaring it as a pandemic on the 11^th of March 2020. Since it was a novel disease, there was limited information on the virus, Severe Acute Respiratory Syndrome Coronavirus 2 (SARS-CoV-2) belongs to the same family as the Severe Acute Respiratory Syndrome Coronavirus 1 (SARS-CoV-1) and the Middle East Respiratory Syndrome Coronavirus (MERS-CoV). Researchers all over the world started working simultaneously to understand the virus to provide the necessary treatment regime or vaccine in order to reduce the impact of the virus on its victims. Africa and other developing countries with limited resources and poor planning and management are expected to be among the worst hit in the long run. The implications of the COVID-19 on food, water, hygiene, sanitation, and the environment in Africa have been reviewed in this paper, as well as possible implications they may pose to the population, based on the existing common practices and their immediate impacts. This information can assist policymakers in Africa to adequately plan the management of the COVID-19 in order to lessen its impact on the population.

AMR and drug void have caused huge panic today with few thousand death per year. MDR Typhoid was a serious old disease and caused serious health hazard in humen and animals demanding an update on molecular biology of the status on transferable genetic elements. R-plasmids combined in F’-plasmid and the new MDR conjugative plasmids were shown abundant in Sanmonella ranging 70-440kb with similarities. BlaTEM, blaCTX-M, blaOXA, blaNDM mdr genes were abundant in >50 plasmids analyzed and metal resistant gene clusters are predominant in most large plasmids. Among the acetyltransferase all catA1, aacA1 and aac-1b-cr genes were located. Abundant streptomycin phosphotransferases (StrAB) and rarely colistin resistant Mcr-5/9 phosphoethanolamine–lipid A transferase were detected. Altered isomeric dihydropterote synthases (Sul1/2/3) were present giving sulfamethoxazole resistance and dhfr gene frequently associated giving trimethoprim resistance. Metal resistant gene clusters like SilABC (CusABC), PcoAB, RcnA, terABC, and merABCXT etc were found in many Salmonella enterica plasmids. Toxin genes like HipA and virulence genes like spvABD were located in few plasmids increasing virulence and pathogenesis. Drug efflux genes tetA or tetB and OqxB, floR, CmlA were frequent where as QepA and EamA genes were rarely seen. Thus, Salmonella metal resistant genes combined with antibiotic resistant genes has tried to overcome the both toxic antibiotics and metalions causing Typhoid AMR. Such acquisition spreads salmoniasis in the live stocks (pig, cow, chicken) where toxic soil and water dominate increasing chance of MDR typhoid in human.

Recent prolonged dry periods and lack of irrigation water have severely affected the productivity of coffee farms’ in the Central Highlands of Vietnam. This paper analyzes the efficiency of irrigation water use for Robusta coffee (Coffea canephora) in Lam Dong province, Highlands, Vietnam. A Cobb-Douglas production function was used to determine coffee productivity’s response to the application of irrigation water and other production factors using data collected from 194 farmers while the Technical Efficiency (TE) and Irrigation Water Use Efficiency (IWUE) were analyzed using a Data Envelopment Analysis (DEA) model. The correlation of different factors to IWUE was determined using the Tobit model. The production function analysis using Cobb-Douglas shows that the volume of irrigation water, amount of working capital, labor and farm size significantly influence coffee productivity. It also shows that indigenous farmers are more efficient in utilizing irrigation water than the (mostly Kinh) migrant farmers. The Tobit result, on the other hand. indicates that farmers’ experience, education level, distance of farm to water source, security of access to water source, extension contact and credit access significantly affect IWUE. The study findings further suggest that mitigating water shortages in coffee farms require sub-regional and national policy support such as better access to credit and extension services, training, land management and household-level effort to improve farming practices, through the application of appropriate technologies and traditional knowledge.

Lake Manzala, the largest of the northern Delta lakes of Egypt, has a great economic importance as a major natural resource of fish and salt. Unfortunately, the lake is suffering from the high inputs of pollutants from industrial, domestic, and agricultural sources. The present study aims to develop the proposed water quality management scenarios to assess and control lake pollution, the pollution sources as well as the pollution spread from the lake to the connected Mediterranean Sea. To apply study methodology, the work tasks divided into two main parts, the first part involved in modelling the lake environments by using Delft3D-WAQ hydrodynamic and water quality model to study the current status and predict the dynamic state of the Lake. This model was calibrated and validated by using various water quality datasets to simulate different scenarios. In the second part, the required lake water quality improvement scenarios were developed to solve the lake water quality problems. The study results showed that the first three developed scenarios that focusing on treatment drain effluent using primary, secondary treatment and surface wetland techniques respectively have a limited efficiency on lake water quality improvement. While the fourth scenario that involved on using biological biofilm techniques can improve lake water quality parameters. Moreover, the fifth scenario that proposed adding a new artificial inlet has a limitation due to the noted increases in lake salinity levels. The sixth scenario that proposed a diversion of some drains can improve lake water quality parameters but it can lead to a decrease in Lake water level. From water quality view point, the last scenario that applying a combination biological biofilm activated technique and also adding a new artificial inlet at northern lake region can represent the optimum scenario. Hopefully, this research will preserve the lake environment and contribute to the benefit of the man health as well. This approach could be extended to the hydrodynamic studies in similar large, shallow lakes anywhere in the world.

The preparation of immobilized graphene–based photocatalyst layers is highly desired for environmental applications. In this study, the preparation of an immobilized reduced graphene oxide (rGO)/TiO₂ composite by electrophoretic deposition (EPD) was optimized. It enabled quantitative deposition without sintering and without the use of any dispersive additive. The presence of rGO had beneficial effects on the photocatalytic degradation of 4-chlorophenol in an aqueous solution. A marked increase in the photocatalytic degradation rate was observed, even at very low concentrations of rGO. Compared with the TiO₂ and GO/TiO₂ reference layers, use of the rGO/TiO₂ composite (0.5 wt% of rGO) increased the first-order reaction rate constant by about 70%. This enhanced performance was due to the increased formation of hydroxyl radicals that attacked the 4-chlorophenol molecules. The direct charge transfer mechanism had only limited effect on the degradation. Thus, EPD-prepared rGO/TiO₂ layers appear to be suitable for environmental application.

Literature data on Legionella spp. presence in houses water networks have been increasing during the last years, but epidemiological reports assert a high incidence of Legionnaires’ disease infection in Italy. Updating our previously published data, we report a five-year survey on Legionella spp. colonization in 235 buildings with an independent hot water production (IB); 82 buildings with a central hot water production (CB); and 58 buildings with a solar thermal system for hot water production (TB). In all the 375 buildings Legionella spp. was researched in hot and cold water samples and microbiological potability standards of cold water were evaluated. Legionella spp. was detected in 27% of the water networks, mostly in CB and TB. We detected correlations between the presence of bacteria and some physical-chemical parameters (low chlorine level and optimal temperature for Legionella spp. growth). Cold water resulted free from microbiological hazards, except for coliform bacteria isolated in three separate cases, and Legionella spp., detected when cold water temperature was about 20°C. After a five-year survey we confirm the presence of a Legionnaires’ disease risk and the need of training programs for all the workers involved in residential water systems management.

(1) Background: Water resources at Chia lagoon experience possible threat to its sustainability. Communities are seeking alternatives to improve water quality at the lagoon. The study evaluated the extent at which local communities are WTP to improve water quality at Chia lagoon and the influencing factors. (2) Methods: A study was conducted at Chia lagoon, Western Part of Lake Malawi from November, 2015 to March, 2016. Wide range of data collection approaches such as household surveys, exploratory surveys, focus group discussions, key informant interviews and field observation were employed. A sample of 240 households were selected randomly. Qualitative data was analysed using content analysis. Multivariate logistic regression analysis was used to determine factors influence WTP. (3) Results: Out of 240 respondents, 57.4% expressed WTP. Multivariate logistic regression analysis demonstrated significant (P<0.01 or P<0.05) relationship between demographic (Gender, age, literacy level), social-economic (Land ownership, main agriculture water source and income) and institution (civic education and social network, extension, water user rights) factors and WTP. (4) Conclusion: The findings from this study provide significant clues for further research and baseline information for local government and local communities in development of more effective and holistic approaches to improve water quality.

Recently a new class of experiments in the field of surface gravity waves has emerged. These experiments serve as demonstration of an analogy to a broad variety of phenomena in optics and quantum mechanics. In particular, experiments involving Airy water-wave packets were carried out. The Airy wave packets have attracted tremendous attention in optics and quantum mechanics owing to their unique properties, spanning from an ability to propagate along parabolic trajectories without spreading, and to accumulating a phase that scales with the cubic power of time. Non-dispersive Cosine-Gauss wave packets and self-similar Hermite-Gauss wave packets, also well known in the field of optics and quantum mechanics, were recently studied using surface gravity waves as well. These wave packets demonstrated self-healing properties in water wave pulses as well, preserving their width despite being dispersive. Finally, this new approach also allows to observe diffractive focusing from a temporal slit with finite width.

High intrinsic water use efficiency (WUEi), the ratio of leaf photosynthesis to stomatal conductance, may be a useful trait in adapting crops to water-limited environments. Carbon isotope ratios can be a useful indicator of WUEi, but might not be well correlated with it if the plants compared differ substantially in mesophyll conductance. In this study, six cultivars of soybeans previously shown to differ in WUEi in indoor experiments were grown in the field in Beltsville, Maryland, and mid-day WUEi was measured on nine clear days during mid-seasons of two years. Measurement dates were chosen for diverse temperatures, and air temperatures ranged from 21 to 34 oC on the different dates. Corrected carbon isotope delta values for 13C (CID) were determined on mature, upper canopy leaves harvested during early pod filling each year. WUEi differed among cultivars both years and the differences were consistent across measurement dates. Correlations between mean WUEi and CID were not significant in either year. It is concluded that consistent cultivar differences in WUEi exist in these soybean cultivars under field conditions, but that carbon isotope ratios may not be useful in identifying them.

There is still a lack of a clinical test to reliably identify patients with Parkinson’s disease (PD) being at risk for aspiration. In this prospective, controlled, cross-sectional study we assessed if swallowing speed for water is a useful clinical test to predict aspiration proven by flexible endoscopic evaluation of swallowing (FEES). Due to this we measured the swallowing speed for 90 ml water in 115 consecutive and unselected PD outpatients of all clinical stages and 32 healthy controls. Average swallowing speed was lower in patients compared with controls (6.5 ± 3.9 ml/s vs. 8.5 ± 3.2 ml/s; p < 0.01). The disease-independent widely used threshold of < 10 ml/s showed insufficient sensitivity of 88% and specificity of 19% with unacceptable false-positive rates of 63% for patients and 69% for controls. Receiver operating characteristic (ROC) analysis was carried out to define a suitable cut-off value for detection of aspiration of water (area under the curve 0.72, p < 0.001) in PD patients. The optimized cut-off value was 5.5 ml/s with a sensitivity of 69% and a specificity of 64%. Overall, measuring swallowing speed is prone to methodological errors and not suitable as a screening instrument to predict aspiration in PD patients.

Descriptive research design was used to select 200 respondents (i.e., 100 from each study places) following purposive sampling technique on two study areas (Market; Living). Personal observation and interview with retailers were done to triangulate the collected data from the formal survey. The collected data was analyzed using SPSS version 20 software program. Descriptive statistical measurements, Index and multinomial regression model was calculated to assess the relationship between customers point of emphasis during packaged water buying and respondents demographic variables. Majority of the respondent who frequently purchase packaged water generated a monthly income between 5000 and 10000 Birr. Television and radio was ranked first compare to other Media. Living place customers were more health concerned as compared to market place customers. Market place customer’s primarily give emphasis to price of packaged water. Almost all (97%) customers did not have the awareness towards packaged water standards. Only 86(43%) of the total respondents checked the chemical composition, of which 74(85%) of the respondents did not understand it. Customers sex, educational level and health status showed significant relationship with choice of packaged water quality -1.42(p<0.05), price -2.45(P<0.01) and health status -1.80(P<0.05) in market place and living places, respectively.

Pb found in rain water is not only caused by tin roof on houses but also caused by the pollution of industrial activities, vehicles and land clearing activity by fire. Pb pollutant dissolves and enters into rain water storages and it’s consumed as drinking. Pb can cause bad impact to human, for example disruption of enzyme, anemia and low intelligence. The purposes of this research are (1) to evaluate Pb, pH and turbidity level in rain water, (2) to analyze the effectiveness of mollusk sand filtration and the absorption of activity carbon to decrease Pb, turbidity and pH, and (3) to analyze the correlation of Pb, length of stay and smoking habit on public health. This research is an experimental by using pre and post test designs with control and observational by using cross sectional design. The research was conducted in urban and rural areas of Pontianak and Kubu Raya regency. The sampling was done in determining the number of samples of Pb, pH and turbidity in rain water. The analyzing the data by using computer program. The results show that: (1) the average of Pb, pH and turbidity level before treatment is considered high at 131.7 µg/L on Pb, turbidity at 20 NTU and low pH at 5.2. After the treatment was the Pb has decreased to 0.71 µg/L and turbidity has to 5.66 NTU, pH to 6.9 and (2) Rain water treatment is very effective to decrease Pb for 99.4% and turbidity for 72%, and (3) there is a correlation among Pb found in rain water, length of stay and smoking activity to public health. Recommends that: the residents of Pontianak and Kubu Raya to process rain water before consuming. The rain water treatment can be done by applying mollusk sand filtration and absorption of active carbon.

Abstract: Currently, thermal power is the largest source of power in the world. Although the impacts of climate change on cooling water sufficiency in thermal power plants have been extensively assessed globally and regionally, their economic consequences have seldom been evaluated. In this study, the Asia-Pacific Integrated Model Computable General Equilibrium model (AIM/CGE) was used to evaluate the economic consequences of projected future cooling water insufficiency on a global basis, which was simulated using the H08 global hydrological model. This approach enabled us to investigate how the physical impacts of climate change on thermal power generation influence economic activities in regions and industrial sectors. To account for the uncertainty of climate change projections, five global climate models and two representative concentration pathways (RCPs 2.6 and 8.5) were used. The ensemble-mean results showed that the global gross domestic product (GDP) loss in 2070–2095 due to cooling water insufficiency in the thermal power sector was −0.21% (−0.12%) in RCP8.5 (RCP2.6). Among the five regions, the largest GDP loss of −0.57% (−0.27%) was observed in the Middle East and Africa. Medium-scale losses of −0.18% (−0.12%) and −0.14% (−0.12%) were found in OECD90 (the member countries of the Organization for Economic Co-operation and Development as of 1990) and Eastern Europe and the Former Soviet Union, respectively. The smallest losses of −0.05% (−0.06%) and −0.09% (−0.08%) were found in Latin America and Asia, respectively. The economic impact of cooling water insufficiency was non-negligible and should be considered as one of the threats induced by climate change.

β-dicalcium silicate (β-Ca₂SiO₄, or β-C₂S in cement chemistry notation) is one of the most important minerals in cement. An improvement of its hydration rate would be the key point for developing environmentally friendly cements with lower energy consumption and CO₂ emissions. However, there is a lack of fundamental understanding on the water/β-C₂S surface interactions. In this work we aim to evaluate the water adsorption on three β-C₂S surfaces at the atomic scale using density functional theory (DFT) calculations. Our results indicate that thermodynamically favorable water adsorption takes place in several surface sites, with a broad range of adsorption energies (−0.78 to −1.48 eV), depending on the particular mineral surface and adsorption site. To clarify the key factor governing the adsorption, the electronic properties of water at the surface were analyzed. The partial density of states (DOS), charge analysis, and electron density difference analyses suggest a dual interaction of water with β-C₂S (100) surface: a nucleophilic interaction of the water oxygen lone pair with surface calcium atoms, and an electrophilic interaction (hydrogen bond) of one water hydrogen with surface oxygen atoms. Despite the elucidation of the adsorption mechanism, no correlation was found between the electronic structure and the adsorption energies.

This study assessed the hydrological performance and runoff water quality of 12 green roof (GR) modular systems located at the Universidad de los Andes campus (Bogotá, Colombia). Based on 223 rainfall events spanning a 3-year period, average rainfall retention was 85% (SD = 25%). T-tests, Welch Test, multiple linear regressions and correlation analysis were performed in order to assess the potential effect of air temperature, substrate type, vegetation cover, relative humidity, antecedent dry weather period (ADWP), rainfall duration and rainfall maximum intensity. In some cases, GR design variables (i.e. growing media and type of vegetation) were found to be significant for describing rainfall retention efficiencies and, depending on the GR type, some hydrological variables were also correlated with the rainfall retention. Rainfall and GR runoff were monitored for Total Kjeldahl Nitrogen (TKN), Nitrates, Nitrites, Ammonia, Total Phosphorus (TP), Phosphates, pH, Total Dissolved Solids (TDS), Total Suspended Solids (TSS), Color, Turbidity, Biological Oxygen Demand (BOD), Chemical Oxygen Demand (COD), Total Coliforms, metals and Poliaromatic Hydrocarbons (PAHs). The results obtained confirmed that GR systems have the ability to neutralize pH, but are source of the rest of the aforementioned parameters, excluding PAHs (with concentrations below detection limits), Ammonia, TSS, Se and Li, where differences with reference values (rainfall and plastic panel runoff) were not statistically significant. Substrate type, event size and rainfall regime are relevant variables for explaining runoff water quality.

Hot rolling tests of a low-alloy steel were conducted at a rolling temperature of 850 ℃ under different lubrication conditions, including benchmarks (dry condition and water) and water-based nanolubricants containing different concentrations of nano-TiO₂ from 1.0 to 8.0 wt%. The effects of nanolubricants on rolling force, surface roughness, thickness of oxide scale and microstructure were systematically investigated through varying nano-TiO₂ concentrations. The results show that the application of nanolubricants can decrease the rolling force, surface roughness and oxide scale thickness of rolled steels, and refine ferrite grains. In particular, the nanolubricant containing an optimal concentration (4.0 wt%) of nano-TiO₂ demonstrates the best lubrication performance, owing to the synergistic effect of lubricating film, rolling, polishing and mending generated by nano-TiO₂.

Climate change such as sea level rise, change in temperature, precipitation, and storminess are expected to impact significantly coastal lagoons. The nature and magnitude of these impacts are uncertain. The objective of the research is to determine the climate change impacts on mixing and circulation at Songkhla lagoon, Thailand. Songkhla lagoon is the largest lagoonal water resource in Thailand and Southeast Asia. The lagoon is a combined freshwater and estuarine complex of high productivity which represents an extraordinary combination of environmental resources believed to be unique in the region. This work is part of a Climate Change impact assessment framework. It is the validation phase (step 5) of the framework applying a case study. Delft 3D was used to simulate CC scenarios in the climate downscaling models, part of the previous framework steps. These results were compared to the current conditions to determine the main changes in mixing and circulation in the coastal lagoon. Three indicators were applied to quantify the impacts: flushing time, salinity intrusion and stratification. The results suggest an increase in water velocities at the inlet in future scenarios and a decrease of flushing time. Salinity and stratification showed more complex changes in futures scenarios.

Species data of 249 National Nature Reserves in China was used to identify potential underlying drivers of latitudinal gradients in plant diversity. We used generalized linear models (GLMs) to assess the correlations between predictor and response variables. We also used SAM (Spatial Analysis in Macroecology) to eliminate autocorrelation along each of the 249 studied locations. We used the Akaike information criterion (AICc; Montoya et al. 2007) to select the independent variables were those included in the best models from different combinations of climate, habitat and animal variables. Variance partitioning was used to decompose the variation in plant richness across different taxonomic levels among the three groups of predictors. We found that: Total plant species, gymnosperms, angiosperms and ferns showed significant latitudinal trends in richness (p < 0.001). Water-energy and habitat variables generally explained more variation in richness across different plant groups than did animal richness. Annual precipitation was selected as the best water-energy variable across different taxonomic plants groups, soil PH and elevation range were selected as the best habitat variables across different taxonomic plant groups. The independent effects of habitatvariables were higher than that of water-energy and animal variables across different taxonomic plants groups. Water-energy, habitat heterogeneity, and animal variables explain 48.8% of the variation in total species richness, 28.2% in gymnosperm richness, 44.2% in angiosperm richness, and 38.9% in fern richness.Plants showed significant latitudinal trends in richness (p < 0.001). Water-energy and habitat variables generally explained more variation in richness across different taxonomic plants groups than did animal variables. The independent effects of habitat variables were higher than those of water-energy and animal variables across different taxonomic plants groups.

As freshwater sources of drinking water become limited cities and urban areas must consider higher-salinity waters as potential sources of drinking water. The Salton Sea in the Imperial Valley of California has a very high salinity (43 ppt), total dissolved solids (70,000 mg/L) and color (1440 CU). Proposals to desalinate the Salton Sea are expected to lower the equilibrium salinity from 45 ppt to 3 ppt yielding significant benefits for ecological restoration. High salinity eutrophic waters such as the Salton Sea are difficult to treat yet more desirable sources of drinking water are not always available. Jar tests were performed to evaluate the treatability of Salton Sea water for potential urban water use by coagulation using aluminum chlorohydrate, ferric chloride and alum. Coagulation-sedimentation proved to be relatively ineffective for lowering turbidity with no clear optimum dose for any of the coagulants tested. Alum was most effective for color removal (28 percent) at a dose of 40 mg/L. Turbidity was removed effectively with 0.45 m and 0.1 m microfiltration. Bench tests of Salton Sea water using Sea Water Reverse Osmosis (SWRO) achieved rejections of 99 percent salinity, 97.7 percent conductivity, 98.6 percent total dissolved solids, 98.7 percent chloride, 65 percent sulfate, and 99.3 percent turbidity.

Analysis of water resources of this area was carried out in order to assessing the water quality by determining the concentrations of Cations, Anions, Heavy metals, Trace elements, PH, Alkalinity, Total Dissolved Solids and microbial loads in water samples. Ten (10) water samples were collected from the study area - samples each of rain water, two pond waters - 1 and 2, stream water, four (4) hand-dug wells, hand pump water and a motorized borehole. The results obtained were compared with WHO standards and it showed that all the cations in water samples are within the limits. The water samples at locations B, E, F, G, H, I, and J have high alkalinity and HC0^-₃ content. The heavy metals (Pb, Ni and Cd) and trace elements (Fe and Cu) are dominantly high in the surface waters. Microbiological substances in the water samples from the study area revealed indicator organisms higher than the WHO standard for drinking water. Samples obtained from location G, I and J recorded an absence of E. coli and are fit for human consumptions but needed to be treated due to high MPN (Most Probable Number) index of viable microorganisms as against WHO standard. This research showed that the water resources of the study area are gradually polluted and in the near future may not be good for drinking.

The purpose of the present research was to analyze the available data on river restoration projects. As the framework of our study, we conducted a structured international survey. We asked selected entities and experts from among those responsible for river restoration in European countries about the details and costs of European Union river restoration projects. We examined 119 river restoration projects that were implemented in Europe between 1989 and 2016; some of the projects were still ongoing. We observed that the number of river restoration projects has been increasing since 1989, which expresses society’s growing interest in improving the quality of aquatic environments. We revealed that 56% of these European river restoration projects have been implemented by dedicated entities and stakeholders, not as part of any structured, larger-scale river restoration policy; this indicates that most European countries do not have integrated plans for river restoration. Our analysis showed that 52% of the projects analyzed have been designed and implemented without the participation of local stakeholders. It also showed that the budgets for river restoration projects did not differ significantly across various time horizons from 1981 to 2016. In our study, the average cost of restoring 1 ha of an average European river was 310 000 EUR (or 195 000 EUR if 4 outlying values are excluded). Considering these projects’ permanent assets and including their amortization, for European river systems, we calculated the average unit price of a river restoration’s value in terms of ecosystem meta-service to be 7 757 EUR · ha^-1 · year^-1 (4 875 EUR · ha^-1 · year^-1 if 4 outlying values were excluded).

Bacteria play a key role in both human health and disease. One of the most prevalent harmful bacteria is E. coli which is responsible for several illnesses ranging from diarrhea, stomach cramp and fever. In this work we explore the application of moderate electric or magnetic fields for treating deionized water that is contaminated with E. coli. We found that moderate alternating electric (AC) fields (10 V/cm to 1kV/cm) and moderate static magnetic fields (10 to 65 mT) can significantly inactivate E. coli by up to 90% or more. This provides the possibilities of developing a low cost and a practical bacteria inactivation technique using electric or magnetic fields.

Diseases caused by contaminated water consumption and poor hygiene are among the leading cause of death in children, the elderly and people with compromised immune system. The present study aims to assess the drinking water quality of some selected drinking water sources in the chosen study area using water quality index (WQI). Samples of drinking waters were collected from four different sources—river, sachet (packaged), borehole and well in Jabi, Abuja, Nigeria for physicochemical and bacteriological analyses using standard methods. With the exception of pH, river water had the highest content of all the physicochemical parameters examined. Some of the physicochemical parameters such as temperature and pH determined in this study were mostly within the World Health Organization (WHO) standard. The bacteriological analyses revealed that the highest total viable counts of 1.54 (0.12) × 10² (cfu/mL) were obtained in the river sample while the least values of 0.03 (0.00) × 10² (cfu/mL) were obtained in the sachet water. Three bacterial isolates of Escherichia coli, Pseudomonas spp and Aeromonas spp were isolated from well water while Pseudomonas spp and Proteus spp were isolated from borehole water. All other bacteria were isolated from the river. The study demonstrates that the safest drinking water source in Idu district, Jabi, Abuja is the sachet/packaged water while the least safe is the river water due to the presence of significant opportunistic pathogens. The results of this study are beneficial for water quality management and could be used for low-cost effective water quality assessment in Jabi.

Development of the self-cleaning and anti-fogging superhydrophobic coating for aluminum surfaces which is durable in the aggressive conditions has raised tremendous interest in materials science. In this work, by employing chemical etching technique with mixture of hydrochloric and nitric acid, followed by passivation with lauric acid, superhydrophobic aluminum surface was synthesized. The surface morphology analysis reveals the presence of rough microstructures on coated aluminium surface. Superhydrophobicity with water contact angle of 170 ± 3.9° and sliding angle of 4 ± 0.5° is achieved. Surface bounces off the high speed water jet, indicating excellent water-repellent nature of coating. It is also continuously floated on water surface for several weeks, showing excellent buoyancy nature. Additionally, coating maintains its superhydrophobicity after undergoing 100 cycles of adhesive tape peeling test. Its superhydrophobic nature withstands 90° and 180° bending, and repeated folding and de-folding. Coating exhibits the excellent self-cleaning property. In low temperature condensation test, almost no accumulation of water drops on the surface, showing the excellent anti-fogging property of coating. This approach can be applied to any size and shape of aluminium surface and hence has great industrial applications.

Diseases in articular cartilages have affected millions of people globally. Although the biochemical and cellular composition of articular cartilages is relatively simple, there is the limitation in self-repair ability of cartilage. Therefore, developing the strategies for cartilage repair is very important. Here, we reported a new manufacturing process of water-based polyurethane based photosensitive materials with hyaluronic acid and applied the materials for 3D printed customized cartilage scaffolds. The scaffold has high cytocompatibility and is one that closely mimics the mechanical properties of articular cartilages. It is suitable for culturing human Wharton's jelly mesenchymal stem cells (hWJMSCs) and the cells showed an excellent chondrogenic differentiation capacity. We consider that the 3D printing hybrid scaffolds may have potential in customized tissue engineering and facilitate the development of cartilage tissue engineering.

Background: This study provides a comprehensive analysis of Acinetobacter baumannii in aquatic environments and fish microbiota by integrating culture-dependent methods, 16S metagenomics, and antibiotic resistance profiling. Methods: A total of 83 A. baumannii isolates were recovered using culture-dependent methods from intra-hospital infections (IHI), wastewater (WW) and surface water (SW) samples from two southern Romanian cities in august 2022. The antibiotic susceptibility was screened using disc diffusion, microdilution, PCR and Whole Genome Sequencing assays. Results: The highest microbial load in the analyzed samples was found in Glina, Bucharest for both WW and SW samples across all investigated phenotypes. For Bucharest isolates, the resistance levels corresponded to fluoroquinolones &gt; aminoglycosides &gt; β-lactam antibiotics. In contrast, A. baumannii from upstream SW samples in Targoviste showed the highest resistance to aminoglycosides. The blaOXA-23 gene was frequently detected in IHI, WW, and SW isolates in Bucharest but was absent in Targoviste. Molecular phylogeny revealed presence of ST10 in Târgoviște isolates and ST2 in Bucharest isolates, while other minor STs were not specifically correlated with a sampling point. Using 16S rRNA sequencing, significant differences in microbial populations between the two locations was identified. The low abundance of Alphaproteobacteria and Actinobacteria in both locations suggests environmental pressures or contamination events. Conclusions: These findings indicate significant fecal contamination and potential public health risks, emphasizing the need for improved water quality monitoring and management.

The binding of actinide ions (Am(III) and U(VI)) in aqueous solutions by hybrid silica-hyperbranched poly(ethylene imine) nanoparticles (NP) and xerogels (XG) has been studied by means of batch experiments at different pH values (4, 7 and 9) under ambient atmospheric conditions. Both materials present relatively high removal efficiency at pH 4 and pH 7 (&gt; 70%) for Am(III) and U(VI). The lower removal efficiency for the nanoparticles is basically associated with the compact structure of the nanoparticles and the lower permeability and access to active amine groups compared to xerogels, and the negative charge of the radionuclide species formed under alkaline conditions (e.g. UO2(CO3)34- and Am(CO3)2-). Generally, the adsorption process is relatively slow due to the very low radionuclide concentrations used in the study and is basically governed by the actinide diffusion from the aqueous phase to the solid surface. On the other hand, the adsorption is favored with increasing temperature assuming that the reaction is endothermic and entropy-driven, which is associated with increasing randomness at the solid-liquid interphase upon actinide adsorption. To the best of our knowledge, this is the first study on hybrid silica-hyperbranched poly(ethylene imine) nanoparticle and xerogel materials used as adsorbents for americium and uranium at ultra-trace levels. Compared to other adsorbent materials used for binding americium and uranium ions, both materials show far higher binding efficiency. Xerogels could remove both actinides even from seawater by almost 90%, whereas nanoparticles could remove uranium by 80% and americium by 70%. The above, along with their simple derivatization to increase the selectivity towards a specific radionuclide and their easy processing to be included in separation technologies, could make these materials attractive candidates for the treatment of radionuclide/actinide contaminated water.

For water-stressed regions like Iran improving the effectiveness and productivity of agricultural water-use is of utmost importance due to climate change and unsustainable demands. Therefore, a hydro-economic model has been developed here for the Zarrine River Basin with the central concept of that demands are value-sensitive functions, where quantities of water-uses at different locations and times have a changeable economic benefits. To do this, the potential crop yields and the surface and groundwater resources, especially Boukan Dam inflow are simulated using the hydrologic model, SWAT, based on predicted climatic scenarios i.e. quantile mapping-downscaled projections. Then, to allocate the agricultural water based on the agro- economic crop water productivity (AEWP) of crops, a basin-wide water management tool, MODSIM, is customized. Next, a simulation- optimization model has been developed using a coupled CSPSO-MODSIM, to optimize the total AEWP, considering climatic impact and crop pattern scenarios, for 2020-2038, 2050-2068 and 2080-2098 periods. Finally, the optimum crop pattern and crop water irrigation depths are presented for different RCPs and periods. The results indicated that this approach will improve considerably the AEWPs and decrease the agricultural water-use up to 40%. Thus, this integrated model is able to support water authorities and other stakeholder in a water-scarce basin, as is the study area.

Cyanobacteria are ubiquitous phototrophic bacteria that inhabit diverse environments across the planet. They dominate many eutrophic lakes impacted by excess nitrogen (N) and phosphorus (P) forming dense accumulations of biomass known as cyanobacterial harmful algal blooms or cyanoHABs. Their dominance in eutrophic lakes is attributed to a variety of unique adaptations including N and P concentrating mechanisms, N fixation, colony formation that inhibits predation, vertical movement via gas vesicles, and the production of toxic or otherwise bioactive molecules. While some of these molecules have been explored for their medicinal benefits, others are potent toxins harmful to humans, animals, and other wildlife known as cyanotoxins. In humans these cyanotoxins affect various tissues, including the liver, central and peripheral nervous system, kidneys, and reproductive organs among others. They induce acute effects at low doses in the parts-per-billion range and some are tumor promoters linked to chronic diseases such as liver and colorectal cancer. The occurrence of cyanoHABs and cyanotoxins in lakes presents challenges for maintaining safe recreational aquatic environments and the production of potable drinking water. CyanoHABs are a growing problem in the North American (Laurentian) Great Lakes basin. This review summarizes information on the occurrence of cyanoHABs in the Great Lakes, toxicological effects of cyanotoxins, and appropriate numerical limits on cyanotoxins in finished drinking water.

Heterocyclic pharmaceuticals are emerging contaminants due to their toxic, carcinogenic nature and detrimental impact on the natural ecosystem. These compounds pose a significant environmental concern given their widespread use in medical therapy, constituting over 90% of new medications. Their unique chemical structure contributes to their persistence in various environmental matrices, necessitating urgent measures to mitigate their risks. This review comprehensively examines the sources, environmental fate, toxicity, and long-term risks associated with heterocyclic pharmaceuticals, proposing potential remediation strategies. The article commences with an overview of the diverse types of heterocyclic pharmaceuticals and their applications, focusing on compounds containing heteroatoms such as nitrogen, oxygen, and sulfur. Subsequently, it explores the sources and pathways through which these pollutants enter the environment, including wastewater discharge, agricultural runoff, improper disposal, resistance to biodegradation, and bioaccumulation. The toxic effects and long-term consequences of exposure to heterocyclic pharmaceuticals are then discussed, encompassing neurotoxicity, genotoxicity, mutagenesis, cardiovascular and metabolic toxicity, carcinogenicity, and teratogenesis. Additionally, the review summarizes various remediation strategies and treatment solutions aimed at reducing the environmental impact of these compounds, drawing insights from the literature. The research concludes by identifying critical areas for future research, emphasizing the urgent need for more effective remediation strategies to address the growing concern posed by these emerging contaminants.

Water networks are critical infrastructure components, ensuring the continuous supply of high-quality drinking water to consumers. To secure such water supply, regular maintenance, including the replacement of deteriorating pipelines, is essential. In this study, a methodology has been developed for determining optimal pipeline replacement solutions in water supply systems at water utilities with limited data availability. Hydraulic analysis has been conducted on the segment of 25 km of the water supply network using the free software EPANET. Applying water network optimization, eight pipeline replacement projects according to 13 pre-defined criteria have been identified and evaluated. The paper outlines the methods for evaluating the criteria, including defining specific quantitative limits. The Analytical Hierarchical Process (AHP) method was used in the paper to determine the weights of the criteria. The reason for applying this method refers to problems that involve a set of criteria with a mixed structure, including both quantitative and qualitative aspects. Also, the paper describes the steps of the multi-criteria optimization method VIKOR, used to select the optimal project. This paper, considered as case studie, describes a method, i.e. application of a new principles and an innovative way to solve a problem for developing countries.

The roles of man-made weirs were well-known as flooding control in summer monsoon, but the function of wintering habitat for wintering water birds were not revealed. This study examined the effects of man-made weirs on the wintering distribution of water birds in Tancheon Stream, Korea, with a focus on the effects of freeze-thaw process. Data collected during January to February 2003 included thawed water surface ratios, water depths, sandbar areas, and bird distribution under different weather conditions. The analysis revealed a strong positive correlation between thawed surface areas in front of weir’s drop structures and the abundance of dabbling and diving water birds during severe cold conditions with temperatures below - 9°C. However, it was also observed that the stagnant water impounded by the weirs tended to freeze easily in winter, making it difficult for water birds to inhabit those areas. These results suggest an adaptation process against man-made weirs by wintering water birds in urban streams, provide significant insights for improving the function of weirs to enhance water birds’ habitats, especially in urban stream management.

In the outskirts of the Pinios dam reservoir (Ilia Regional Unit, Greece) a freshwater refinery serves the water supply needs of the surrounding Municipalities, in which high concentrations of Fe and Mn, before treatment, have been observed. The main purpose of this research is to investigate the mechanism of increased iron (Fe) and manganese (Mn) levels in the reservoir of the Pinios dam, which impacts its freshwater refinery's operation. A comprehensive hydrochemical and sedimentological analysis was conducted over a hydrological year, focusing on the spatial and temporal distribution of Fe and Mn in both water and sediment samples across the established research monitoring stations. Sediment samples from the reservoir's bottom revealed predominantly fine-grained material, rich in total organic carbon, with elevated Mn and Fe oxide levels. Significant seasonal variations in Fe and Mn levels were also discovered, with higher Mn levels observed in the anoxic bottom waters of the reservoir during the dry season, attributed to the reduced conditions favoring Mn oxide dissolution over Fe. Conversely, during the wet season, a homogenization of metal concentrations throughout the water column was observed due to increased oxygenation and freshwater inflow. These outcomes were confirmed by the hydrochemical analysis, indicating that the redox conditions, pH, temperature, as well as the presence of organic matter significantly influence the mobility and bioavailability of these metals in the reservoir. The findings of this study clarify that the high concentration of Fe and Mn can be linked to the mineral composition of the upstream Neogene and flysch formations in the study area. As these formations are affected by geological weathering, they tend to enrich the streams, through soil erosion and runoff processes, in metals like Fe and Mn, which are eventually transported into the dam reservoir. This study highlights the critical role of geological, sedimentological and hydrological factors in shaping the hydrochemistry of dam reservoirs, providing essential insights for water resource management and environmental conservation strategies.

A vast amount of non-biodegradable waste is generated during mining and processing operations of dimensional stones such as marble. This, over the years has become a global nuisance by damaging the environment through means of more than one. Therefore it has become necessary to find a technique to safely dispose or reuse marble waste. This paper reviews the impact of replacement of the conventional materials by marble waste was studied in terms of fresh, mechanical and durability properties of concrete. The air pollution caused by the dust generated in the process of crushing and extracting marble can cause serious problems to the general physiological functions of plants and it affects human life as well. Therefore, the objectives of this study were to assess the air quality of areas with marble factories and areas without marble factories, where the concentration of particulate matter in terms of total suspended particles (TSP) was determined. This paper also reviews some eco-innovation options considering the pollution caused, consumption of water and electricity and the disposal of marble waste and their waste.

This study aimed to compare the effects of adding fermented feed to daily feed on slaughter performance, meat quality, and flavor compounds of cage chickens. Control group (CK) of the Guangxi Partridge chicken received a standard base diet (CK), pellets added with 10% fermented banana peel (Pe-10), 20% fermented banana peel (Pe-20), 10% fermented banana pulp residue (Pu-10) and 20% fermented banana pulp residue (Pu-20). The slaughter performance, meat quality, and flavor compounds in the meat samples of the chicken in these groups were evaluated. The results showed that the chicken in Pe-10, Pe-20, Pu-10, and Pu-20 had pectoral muscle percentages, thigh muscle percentages, and total fatty acids content of chest meat higher than CK. The moisture content, meat color, carcass weight, total net weight, and abdominal fat percentages of the meat samples in these experimental groups were not remarkably different. The flavor compounds in the meat samples of the chicken fed with the two concentrations of fermented banana peel and banana residue were significantly different from those in the control group. When the amount of fermented banana peel added to the daily feed increased from 10% to 20%, the flavor compounds in the chicken samples changed significantly. In conclusion, different proportions of fermented banana peels and dregs in diets can improve slaughter performance and chicken quality and affect its flavors.

Communication pathways are an underestimated source of synthetic particles in the environment. This study investigated the impact of traffic volume on microplastics (MPs) and tire wear particles (TWPs) pollution in road snow. An examination was conducted in a medium-sized city situated in northeastern Poland, known for being one of the cleanest regions in the country. MPs and TWPs were found at all 53 sites, regardless of the intensity of traffic. The average concentration for all samples was 354.72 pcs/L. Statistically significant differences were found between the average values of particles concentration on low, medium, and heavy traffic roads amounted 62.32 pcs/L, 335.97 pcs/L and 792.76 pcs/L respectively. Within all three studied groups of roads, MPs and TWPs with the smallest size, ranging from 50 to 200 μm, were prevalent. In all studied groups of roads, 4 analyzed shapes of particles were found, with irregular fragments being the most abundant form (89.23%). The most frequently recorded color among the collected samples was black (99.85%), and the least frequently recorded was blue, constituting only 0.01%. This study suggests that snow cover on the roads may act like temporary storage of pollutants during winter in the temperate climate zone and after thaw can significantly increase the concentration of MPs and TWPs in surface waters. Possible measures to decrease the release of MPs and TWPs into the environment in the city may include reducing traffic volume and speed, implementing street sweeping, utilizing filtration chambers, and installing stormwater bioretention systems or settling ponds.

The growing threat of antibiotic pollution in water systems demands innovative and sustainable remediation strategies. Nanocellulose-based magnetic metal-organic frameworks (MOFs) represent a cutting-edge solution for the adsorption and removal of antibiotics, leveraging their high porosity, magnetic properties, and environmentally friendly nature. This paper provides an in-depth review of recent advancements in nanocellulose-based MOFs, focusing on their synthesis, adsorption mechanisms, and applications in environmental remediation between 2020 and 2024. By summarizing key studies, we highlight their performance in targeting widely used antibiotics such as tetracyclines and fluoroquinolones. The integration of nanocellulose with MOFs not only enhances adsorption capacity but also offers easy recovery, recyclability, and environmental compatibility. This review explores their adsorption mechanisms, practical applications, and future research directions, contributing to the advancement of scalable and sustainable water treatment technologies.

This research delves into the water hammer occurrences, in the transmission pipeline of the SMD (Manda Daba) Multi Village Water Supply Schemes in Afar, Ethiopia. It utilizes simulation software, Bentley HAMMER version 8i to assess transient flow issues and the effectiveness of protective measures. The study pinpoints high risk areas in Scenario 1 marked by pressure spikes, negative pressures and frequent cavitation highlighting the importance of efforts. Prior to safeguards significant pressures reaching 288.27 m H₂O and minimum pressures dropping as low as 9.98 m H₂O are observed. In Scenario 2 where protective measures are implemented notable enhancements are seen with pressures ranging from 121.38 m H₂O to 150.49 m H₂O improved safety levels and substantial reductions in minimum pressures at pump stations. Moreover the study delves into Scenario 3 which explores pipe materials and diameters to provide insights, for pipeline design standards. It emphasizes how protective measures effectively mitigate water hammer effects while also highlighting cost saving potential by incorporating 2000 liter hydro tanks at pump stations. This integration leads to decreased pipeline collapses and maintenance expenses underscoring the significance of addressing challenges pinpointing failure causes and offering solutions to enhance system performance and strengthen reliability within the SMD water supply system

This paper assessed rice farmers' perceptions of agricultural and irrigation practices through their choices. A survey was carried out among 278 rice farmers on five irrigation schemes in three agro-ecological zones of Togo, viz. the savannah region, the forest region and the coastal region. The sample of random respondents was selected from a list of rice farmers provided by the managers of these irrigated schemes. Data collected through face-to-face interviews using kobocollect software were analyzed with R 4.2 software, and the Pearson test was validated at the 5% level. The results showed that the socio-economic characteristics of the rice growers, such as access to agricultural credit, experience, non-agricultural activities, membership of a rice growers' cooperative, gender, level of education and training in growing irrigated rice, and farm labor, significantly influenced the choice of agronomic practices and irrigation management. Characteristics such as experience, training and hired farm labor enhanced paddy yields, while access to agricultural credit was unproductive. Chemical clearing combined with stump removal, tiller ploughing, transplanting and high plant density are the agricultural practices that increased paddy yields, while tiller mudding and basal mineral fertilization were inefficient. In the same way, water distribution by demand, water depth above the soil of less than 5 cm, use of water-saving technologies and farmer's knowledge of how to improve water and fertilizer use-efficiency also helped to boost paddy yields. For sustainable rice production in the context of labor shortages and the financial resources required, future studies will focus on the effectiveness of motorized mudding and agricultural credits for rice farmers. Furthermore, considering the crucial role of training in the adopting of good agricultural and irrigation practices, future research will study strategies for wide diffusion of knowledge to rice producers.

The wastewater problem is becoming an increasingly significant environmental issue affecting various aspects of human activities. The generation of reactive oxygen species (ROS) in water through certain physicochemical processes, which can oxidize or degrade various organic and chemical compounds, offers an effective purification method. The main advantage of these methods is the elimination of chemical reagents. Aim of this work is to investigate the possibility of regulating the ROS content in water by altering the characteristics of the plasma discharge that occurs under hydrodynamic cavitation in the water flow. ROS concentration was determined using the permanganate oxidation titration technique. It was found that the content of various reactive oxygen species in water after treatment can be controlled by varying the power of the electrical pulses applied. Additionally, the study obtained the dependence of ROS concentration in treated water samples on storage time, indicating a prolonged effect of sonoplasma treatment on the antibacterial properties of water. Analysis of water samples using a biological test culture of Salmonella typhimurium revealed bacteriostatic properties of the water for at least 48 hours after sonoplasma discharge treatment.

Study assessed the wind potential of three sites in Chad: Koro Toro, Salal and Nedeley. Analysis of the Weibull distribution curves reveals marked seasonal variability in wind speed, concentrated around the mean. Three models of high-power wind turbines were analyzed. At Koro Toro, the Siemens Gamesa SG 14-222 DD has a capacity factor of between 0.52 and 0.682, allowing a daily flow of pumped water of between 1.4 and 6.1 million m³. The Enercon E-126 EP4 performs slightly less well. At Salal, the Siemens Gamesa has a capacity factor of between 0.4463 and 0.6605, with a water flow rate of between 0.9 and 3.7 million m³/day. The Vestas V164-10.0 MW has a higher capacity factor (0.6327 to 0.8115) but a lower water flow rate (0.5 to 1.9 million m³/day). Enercon's performance is comparable to that of Siemens Gamesa. The Nedeley study reveals favorable conditions, with seasonal variations in wind speed and capacity factor indicating good wind potential, and maximum daily water flows of between 3 and 6 million m³. Analysis of the wind roses shows interesting potential in these towns, with a dominant east-north-easterly wind at maximum frequencies of 40%. The absence of calm winds is promising, although Nedeley and Salal have a residual presence. This study shows that the sites offer good wind potential This, enabling the production of electricity and heat.

It is vital to analyze ship collision risk for preventing collisions and improving safety at sea. This paper takes Ningbo-Zhoushan Port, a typical complex navigable water, as the research object, propose a probabilistic conflict detection method to estimate the potential collision risk by using a dynamic domain model driven by AIS data. Combined with the algorithm of fast modularity optimization and spectral clustering, a ship group extraction method from the perspective of water navigation management was proposed. Aiming at ship traffic characteristics in complex navigable waters, conduct dynamic calculation of ship collision risk from individual, regional and local multi-scale perspectives. The results show that the proposed method can detect the collision risk in a timely, reliable and effective manner under complex dynamic conditions. As such, they provide valuable insights for ship collision risk prediction and the development of risk mitigation measures.

As waterflooding multi-layer reservoirs get into the high-water-cut stage, inter-layer conflicts become increasingly serious, leading to a worsening development effect over time. Production layers regroup is an effective approach for resolving inter-layer conflicts and improving waterflooding efficiency. At the current stage, there are limitations for most of the methods of production layers regroup. This article proposes a smart method for optimizing the layer regroup plan based on genetic algorithm. Comprehensively considering various factors that affect the regroup of layers, based on the combination principle of "smaller intra-group variance and larger inter-group variance of each influencing factor are expected ", genetic algorithm is used to calculate the fitness value of the initial combination schemes, the advantageous schemes with higher fitness values are selected as the basis of the next generation. Then crossover and mutation operations are performed to those advantageous schemes to generate new schemes. Through continuous selection and evolution, until the global optimal solution with the highest fitness value is found, the optimal combination scheme is determined. Comparative analysis with numerical simulation results demonstrates the reliability of this intelligent method, with an increased oil recovery of 4.34% for the sample reservoir. Unlike selecting a preferable plan from a limited number of predefined combination schemes, this method is an automatic optimization to solve the optimal solution of the problem. It improves both efficiency and accuracy as compared to conventional reservoir engineering methods, numerical simulation methods and most of the mathematical methods, thus could provide effective guidance for EOR strategies of waterflooding reservoirs in high-water-cut stage.

Solar saline water splitting is a promising approach for sustainable hydrogen production, harnessing abundant solar energy and the availability of brine resources, especially in the Atacama Desert. Bischofite (MgCl2·6H2O), a naturally occurring salt, has garnered significant attention due to its wide range of industrial applications and the challenges associated with efficient hydrogen production in arid or hyper arid locations. This work discloses the electrochemical performance of Mn2O3 electrodes using a superposition model based on mixed potential theory and evaluates the superficial performance of this electrode in contact with a 0.5 M nature Bischofite salt solution focusing on hydrogen evolution reaction (HER), and oxygen reduction reaction (ORR), that occurs during saline water splitting. The application of the non-linear superposition model provides valuable electrochemical kinetic parameters that complement the understanding of Mn2O3, this being one of the novelties of the manuscript.

Ca2+ can boost protein-protein interactions and, if present at an appropriate level, can potentially improve the physicochemical properties of protein gels and films. This study aimed to determine the effect of CaCl2 (0, 0.01 0.025 0.05% w/w) on the optical, water affinity, and mechanical char-acteristics of glycerol (Gly)- and sorbitol (Sor)-plasticized pea protein isolate (PPI) films. The CaCl2 caused darkening and a color shift of the films from yellow to yellow-green. Additionally, de-creased light transmission, particularly in the UV range, and reduced moisture content were observed. The CaCl2 decreased the water vapor permeability (WVP) of the Gly-plasticized film by an average of 20%, with no effect on the Sor-plasticized film. All films were completely soluble in water. The CaCl2 negatively impacted the mechanical integrity of the films, reducing the tensile strength of the Gly- and Sor-plasticized films by ~16% and 14-37%, respectively. Further increases in CaCl2 content (0.1% and 0.2% w/w) led to concentration-dependent cracks, suggesting protein over-crosslinking. In summary, the incorporation of CaCl2 into PPI films did not provide signif-icant benefits and actually worsened key properties such as transparency and mechanical strength. The type of plasticizer influenced how CaCl2 affected some properties of the PPI film.

The purpose of this work is to analyze heat-treated ash wood at temperature of 185 ºC, in order to analyze its dimensional stability. For comparison, native ash/ not thermally treated wood, was be used. In order to analyze heat-treated ash wood, some main properties such as water absorption, swelling in thickness, roughness, Brinell hardness, modulus of rupture and elasticity, color change toward black with CIELab space, and many others properties were determined and processed. The results obtained after processing the experimental data have showed that heat-treated ash wood had good physical properties as absorption and swelling in thickness, and the slight increase in elasticity offers new fields of use. As a general conclusion of the work, it was established that the ash wood can be properly thermally treated, the dimensional stability characteristics being very good, and the decrease in bending resistance being almost imperceptible.

This research evaluates the mineral ions and their concentrations in formation water from five well samples of the Bibi Hakimeh oil field. The study reveals the presence of calcium (Ca2+), so-dium (Na+), and magnesium (Mg2+) cations, as well as sulfate (SO42-), bicarbonate (HCO3-), and chloride (Cl-) anions, which are soluble in water within the Bibi Hakimeh oil formation. Fur-thermore, mineral deposits of CaSO4, CaSO4.2H2O, CaCO3, and MgCO3 are investigated. The findings highlight the significant formation of calcium sulfate and calcium carbonate mineral deposits under the operating conditions of the Bibi Hakimeh oil well. Additionally, the study examines the interaction between rock and water of the Bibi Hakimeh formation, revealing a notable correlation between the concentration of calcium and magnesium ions and the water-rock reaction in this field

PFAS are a variety of ecologically persistent compounds of anthropogenic origin loosely included in many industrial products, in which the carbon chain can be fully (perfluoroalkyl substances) or partially (polyfluoroalkyl substances) fluorinated. Their ubiquitous presence in many environmental compartments over the years, and highly long-lasting nature, arose concern because of the possible adverse effects of PFAS on ecosystem and human health. Between the remediation technologies, adsorption has been demonstrated to be a maneageble and cost-effective method for the removal of PFAS in aqueous media. This study tested two novel and eco-friendly adsorbents (pinewood and date seeds biochar) on 6 different PFAS (PFOS, GenX, PFHxA, PFOA, PFDA, PFTeDA). Batch sorption tests (24 hours) were carried out to evaluate the removal efficiency of each PFAS substance in relation to the two biochars. All samples of liquid phase were analysed by a developed and then well-established method: i) pre-treatment (centrifugation and filtration); ii) determination by high-performance liquid chromatography coupled with mass spectrometry (HPLC-MS/MS). Results evidenced a comparable adsorption capacity of both materials, but greater for the long-chain PFAS. Such findings may lead to a promising path for the use of waste origin materials in the PFAS remediation field.

This study investigates cloud cavitation suppression around a model scale NACA66 hydrofoil using active water injection and explores the effect of multiple injection parameters. Numerical simulations and a mixed-level orthogonal test method are employed to systematically analyze the impact of jet angle αjet, jet location Ljet, and jet velocity Ujet on cavitation suppression efficiency and hydrofoil energy performance. The study reveals that jet location has the greatest influence on cavitation suppression, while jet angle has the greatest influence on hydrofoil energy performance. The optimal parameter combination (Ljet = 0.30C, αjet = +60 degrees, Ujet = 3.25 m/s) effectively balances energy performance and cavitation suppression, reducing cavitation volume by 49.34% and improving lift-drag ratio by 8.55%. The study found that the jet's introduction not only enhances vapor condensation and reduces the intensity of the vapor-liquid exchange process but also disrupts the internal structure of cavitation clouds and elevates pressure on the hydrofoil suction surface, thereby effectively suppressing cavitation. Further analysis shows that positive-going horizontal jet components enhance the lift-drag ratio, while negative-going components have a detrimental effect. Jet arrangements near the trailing edge negatively impact both cavitation suppression and energy performance. These findings provide valuable reference for selecting optimal injection parameters to achieve a balance between cavitation suppression and energy performance in hydrodynamic systems.

The maneuverability of ships is influenced by several factors, including ship design, size, propulsion system, hull shape, and external conditions such as wind, waves, and currents. The size, shape, and arrangement of the hull, rudder, and propeller are decisive for maneuverability. Hydrodynamic forces such as bank effect and squat significantly impact the maneuverability of large ships in narrow channels. With the increasing trend of building ever-larger ships, the demand to evaluate the maneuvering performance of the ship at the design stage has become more critical than ever. Both experimental and computational methods are used to obtain accurate maneuvering characteristics of vessels. In this study, the methods for predicting ship maneuvering characteristics are analyzed using a systematic review based on the preferred reporting items for systematic reviews and meta-analyses (PRISMA). This article contributes to a deeper understanding of the hydrodynamic capabilities of ships and identifies possible future challenges in the field of ship hydrodynamics. The findings inform educators and the shipping industry about the importance of predicting the maneuvering performance of ships, with an emphasis on the education and training of seafarers needed to make timely decisions in critical situations.

An analysis of the physical and chemical phenomena accompanying the electrical discharges was carried out, principal factors inactivating microorganisms is studied. Characteristic factors of an electric discharge in cavitation mode providing a synergistic effect when disinfecting water with a discharge and chemical reagents are identified in order of importance. As a result of the integral action of cavitation, the inactivation of bacteria is intensified both due to the emergence of chem-ically active particles and due to local shock waves, acoustic currents and ultraviolet radiation in the area of cavitating bubbles. The similarity of cavitation processes in water systems implemented by underwater electric discharges and with the ultrasound has been experimentally proved. The main advantage of electric discharge cavitation in comparison with ultrasonic one is the wide band of ultrasonic frequencies of radiation inherent in electric discharge, high intensity and power of cav-itation processes, and, accordingly, the possibility of a significant increase in the volume of the disinfected liquid. The study enable better understanding and prediction of the effects that occur during a high-voltage underwater electrical discharge and have a bactericidal effect.

The prospect of drinking water serving as a conduit for gut bacteria, artificially selected by disinfection strategies and lack of monitoring at the point of use, is concerning. Certain opportunistic pathogens, notably some nontuberculous mycobacteria (NTM), often exceed coliform bacteria levels in drinking water, posing safety risks. NTM and other microbiota resist chlorination and thrive in plumbing systems. When inhaled, opportunistic NTM can infect the lungs of immunocompromised or chronically ill patients, and the elderly, primarily postmenopausal women. When ingested with drinking water, NTM often survive stomach acidity, reach the intestines, migrate to other organs using immune cells as vehicles, potentially colonizing tumor tissue, including in breast cancer. The link between the microbiome and cancer is not new, yet the recognition of intratumoral microbiomes is a recent development. Breast cancer risk rises with age, and NTM infections emerged as a concern among breast cancer patients. In addition to studies hinting at a potential association between chronic NTM infections and lung cancer, NTM have also been detected in breast tumors at levels higher than normal adjacent tissue. Evaluating the risks of continued ingestion of contaminated drinking water is paramount, especially given the ability of various bacteria to migrate from the gut to breast tissue via entero-mammary pathways. This underscores a pressing need to revise water safety monitoring guidelines and delve into hormonal factors, which includes addressing the disproportionate impact of NTM infections and breast cancer on women and examining the potential health risks posed by the cryptic and unchecked microbiota from drinking water.

This study aims to evaluate how the operational procedure adopted for the pellets placement and the exposure to subsurface conditions influences the mechanical integrity of bentonite plugs used as barrier elements in the abandonment of petroleum wells. To this end, two methodologies were used to obtain the plugs: from the first methodology, the pellets were immersed in diesel or olefin, which are proposed as displacement fluids in offshore operations, and then, hydrated in deionized water; in the second methodology, representative of onshore operations, the pellets were directly hydrated in deionized water. After that, the plugs were tested by compression and adhesion tests. These mechanical tests were also carried out for test specimens obtained from plugs exposed to four formulations of synthetic formation waters. The results obtained demonstrated that the previous contact with olefin adversely affects the mechanical stability of bentonite plugs, while plugs formed from pellets immersed in diesel presented satisfactory mechanical properties. The mechanical properties of onshore plugs attested the highly successful performance of these elements, once its compressive strength was minimally impacted by exposure to formation waters and more pronounced reductions were observed only in the adhesion properties after the contact with higher salinity formation waters.

This study analyzes the relevance of governance structure for efficiency in revenue collection by Brazilian Water Utilities (WUs). Data was collected from the National Information System on Sanitation (SNIS) for 127 Brazilian WUs, covering a balanced longitudinal panel from 2018 to 2022. Governance structures evaluated included Ownership (public or private) and Corporatization (publicly traded or not). In scientific databases, we did not find studies on the efficiency of specific WUs in collecting customer bills for services rendered and its relationships with this type of governance; thus, this would be the main innovative contribution of the study to the previous literature. In the first stage, the study utilized the Dynamic Slack Based Model (DSBM) to assess revenue collection efficiency. In the second stage, an econometric model with Generalized Estimating Equations (GEE) to explain the efficiency. The findings revealed a global average inefficiency of 50.47% in revenue collection. Corporatization was linked to higher collection efficiencies, while ownership type was significant, but with lower collection efficiency. Factors such as tariff accessibility, urbanization, and the COVID-19 pandemic also influenced efficiency. The study suggests regulatory bodies should consider these insights to implement policies that prevent inefficiencies from affecting the tariff system for services.

Iron tailings are solid waste generated after the mining of iron mines, which have caused serious damage to the surrounding ecology and environment and have attracted widespread attention. By analyzing the formation causes, main components, and environmental effect mechanisms of iron tailings, the article systematically elaborates on the degree and mechanism of the harm of iron tailings to water bodies, atmosphere, soil, and ecosystems, and evaluates its impact on human health and sustainable development of society. On this basis, specific prevention and control measures have been proposed to reduce iron tailings emissions, realize resource recycling, and restore ecosystems. Research shows that iron tailings containing heavy metals can widely pollute the environment through dissolution and migration, and have significant biological toxicity effects. The research results can provide a theoretical reference for decision-making departments to formulate scientific and reasonable iron tailings disposal and ecological protection policies. It is recommended to strengthen specific research on the infiltration of toxic and harmful components in tailings in the future, and develop efficient and stable solidification technology, and vegetation-microbial joint restoration models to further reduce the ecological and environmental risks of iron tailings.

Recent climate change and water pollution has affected algal diversity resulting in emergence of more tolerant species. They can be the indicators of water quality, pollution and seasonal changes. Present study revealed the green algal diversity and distribution pattern according to water parameters and season in the Lucknow City, India. The water sample were collected from seven sites within Lucknow and outskirts. The occurrence of a total of 36 taxa of green algae belonging to 11 genera are recorded. It has been observed that less polluted water is dominated by Spirogyra; where conductivity, TDS and salinity of water were low. Whereas the more polluted water was dominated by desmids. Dominance index was found highest in site 4 (0.61), where only three taxa were identified; whereas the lowest (0.13) was measured in site 1, where nine taxa were identified. This study also recorded several algal taxa for the first time from Lucknow.

The River Habitat Survey (RHS) is a method for assessing the conditions of a river channel and valley, taking into account hydromorphological factors, and assessing the degree of naturalness or the degree of anthropogenic alteration within the channel and valley based on physical and landscape data. The hypothesis tested in this study was that the quality of river habitats demonstrated using the RHS should translate into the composition of their fauna. We investigated aquatic bugs (Heteroptera Aquatica), which are a group with considerable dispersal abilities and, at the same time, composed of stenotopic species associated with a particular environment as well as of eurytopic elements inhabiting a wide range of environments (REF). The research was carried out in a small lowland river, the River Krąpiel (north-western Poland) at 6 sites with 43 sub-sites included. Our analyses suggest the RHS method can predict the composition and quality of the aquatic bug fauna inhabiting a given river. Indicators of river habitat quality (HQA and RHQ) will be associated with different habitat types depending on the geographic location and type of river, once indicating habitats associated with the mainstream river and mineral substrate (mountain and small lowland rivers) and at other times habitats covered by vegetation with relatively slow water flow (large and medium lowland rivers). Therefore, RHS may be a good method for estimating the water bug fauna, linking it to the size and character of the river.

Revealing the spatial distribution mechanism of the coupling effect between soil water and salt is essential for managing saline-alkali farmland. This study utilized the multifractal method to analyze soil water and salt under varying water content levels in arid saline-alkali farmland. Soil samples were collected on the second (S1), fifth (S2), eighth (S3), eleventh (S4), and fourteenth (S5) days after a rainfall event. The findings showed that a significant decrease in soil water content, contrasting with an increase in soil salt content throughout the soil layers post-rainfall. As water content decreased, the spatial variability of soil water initially increased from S1-3 and then decreased, while the spatial variability of soil salt decreased. The spatial distribution between soil water and salt exhibited a high correlation at S3-4 (with relative water content of soil ranging from 0.52 to 0.75) due to their coupling effect. However, soil salt was unevenly leached by rainfall at high water content levels (S1-2) and precipitated at low water content levels (S5), resulting in low spatial variability correlations between soil water and salt. This study elucidated the coupling process of soil water and salt, identifying their spatiotemporal distribution mechanism in dryland agricultural areas.

The opportunities and advantages of implementing Artificial Intelligence (AI) and Machine Learning (ML) to optimize the process control of wastewater treatment in the Oil and Gas industry are discussed in this work. Discussion is centered around five major points: 1) Various types of Oil and Gas wastewater (Sour, Oily, Produced) and industry standards/methods for treatment, including specific case studies and challenges when treating certain wastewater. This section aims at the common types of wastewater in the Oil and Gas industry and how they are generally treated. 2) How AI/ML has been implemented in wastewater treatment in various industries; summary of which AI/ML languages were used along with a brief overview of how they work. This article focused on an understanding of the specific case studies and AI explanations to understand the effectiveness of wastewater treatment using AI/ML. 3) AI that is currently implemented in Oil and Gas such as personal protective equipment (PPE), smartwatches radiofrequency identification etc. This showed that AI/ML already plays a successful role in the Oil and Gas industry and has proven to help optimize many processes and components. Many of these AI/ML implementations are now industry standards and have greatly benefitted the industry. This section demonstrates that the implementation and the use of AI/ML have been proven to be a successful endeavor and that expanding the role of AI/ML would be beneficial. 5) Using the established points from the previous sections the paper outlines why AI/ML is ideal for Oil and Gas wastewater treatment; this argument centers around fit-for-purpose treatment, and the possible uses of the treated water. A determination of the best-suited AI languages, possible implementation scenarios, and how this would shift the way Oil and Gas industries treat and approach wastewater is presented to the reader.

In recent years, Global Navigation Satellite System reflectometry (GNSS-R) has been explored as a methodology for inland water body characterization. However, thorough characterization of the sensitivity and behavior of the GNSS-R signal to inland water bodies is still needed to progress this area of research. In this paper, we characterize the uncertainty associated with Cyclone Global Navigation Satellite System (CYGNSS) measurements on the determination of river width. The characterization study uses simulated data from a forward model that accurately simulates CYGNSS observations of mixed water/land scenes. The accuracy of the forward model is demonstrated by comparisons to actual observations of known water body shapes made at particular measurement geometries. Simulated CYGNSS data is generated over a range of synthetic scenes modeling a straight river subreach, and the results are analyzed to determine a predictive relationship between the peak SNR measured over the river subreaches and the river widths. An uncertainty analysis conducted using the predictive relationship indicates that for simplistic river scenes, the SNR over the river is predictive of the river width to within +/-5m. The presence of clutter (surrounding water bodies) within ~500m of the river causes perturbations in the SNR measured over the river that can render the river width retrievals unreliable. The results of this study indicate that under idealized conditions, GNSS-R data is able to measure river widths as narrow as 160m with high accuracy.

The Eastern Kunlun Fault Zone (EKFZ) is located in a seismic blank area. This study investigates the hydrogeochemical characteristics of varied-temperature springs in the EKFZ to understand the relationship between fractures, fluids and earthquakes. It aids in establishing their induction mechanisms and assists in monitoring the earthquake precursors of the EKFZ. In this study, the main elements, trace elements, hydrogen and oxygen isotopes and strontium isotopes of 23 varied-temperature springs in the EKFZ were analyzed. The results reveal the source of groundwater recharge, hydrochemical types, mineral saturation, and for a select few springs indicative of geothermal activity, collected geothermal reservoir temperatures. The study also explores the relationship between earthquakes and springs, identifying sensitive chemical indicators. Based on continuous monitoring at Maqu Station, we found that before the occurrence of the Maerkang Ms 6.0 earthquake, the concentration of Cl− rose by 2.9 times, and 46 days before the Gande earthquake (Ms = 4.7), the concentrations of Na+ and SO42− significantly increased. Finally, a conceptual model of the hydrogeochemistry of springs is presented to describe the groundwater circulation in the study area. This research is of great significance for the analysis of fluid geochemistry in this area and for assessing the seismic hazards of the EKFZ.

A very detailed water budget was conducted on Lake Trafford in southern Florida. The inflow was dominated by surface-water influx via five canals (61%) with groundwater influx constituting 12% and direct rainfall 27%. Lake discharge was dominated by sheet-flow (69%) and evapotranspiration (30.5%) with groundwater recharge of the hydraulically connected unconfined aquifer accounting for only 0.5%. Removal of 30 M tons (4.4 x 106 m3) of organic sediment impacted groundwater influx, causing enhanced groundwater flows into the deeper parts of the lake and mixed flows along the banks creating a rather unusual pattern. The large number of groundwater seepage meters used during the investigation led to a very reliable set of measurements with occasional failure of only a few meters. A distinctive relationship was found between the wet season lake stage, heavy rainfall events and pulses of exiting sheet-flow from the lake. Estimation of the evapotranspiration loss using data collected from a weather station on the lake allowed the use of three different models which, when averaged, produced results comparable to Lake Okeechobee (southern Florida). A limitation of the investigation was the inability to directly measure sheet-flow discharges, which had to be estimated as a residual within the calculated water budget.

This work presents a numerical study on atmospheric sound propagation over rough water surfaces. A method to generate pseudorandom sea profiles consistent with sea wave spectra is presented. The proposed method is suited to capture the logarithmic nature of the energy distribution of the waves. Sea profiles representing fully developed seas for sea states 2, 3, 4 and 5 are generated from the Elfouhaily et al. (ECKV) sea wave spectra. Excess attenuation caused by refraction and surface roughness is predicted with a parabolic equation (PE) solver. A novel method to estimate equivalent effective impedance based on PE predictions at different sea states is presented. Parametric expressions using acoustic frequency and significant wave height are developed for effective surface impedances. In this work, sea surface roughness is on a scale comparable to the acoustic wavelength. Under this condition, the acoustic scattering is primarily incoherent. This work shows the limitations of using an equivalent surface impedance in such incoherent scattering cases.

Nature-Based Solutions (NBSs) can help to achieve multiple Water-Ecosystem-Food Nexus Do-main Objectives & Nexus Resilience Qualities, facilitating the transition to more resilient agrifood systems and providing an evidence base for a broader Nexus policy dialogue. This paper de-scribes the stepwise methodology developed in the EU-funded LENSES project to carry out a comprehensive analysis of NBSs in 6 pilot areas in 5 Mediterranean countries, and presents the results of NBSs implementation in 4 pilot areas, highlighting obstacles and opportunities. The methodology includes the development of an analytical evaluation framework and of a com-prehensive catalogue of Nexus-related NBSs, whose suitability needs to be assessed at the local level to achieve better use of protected/natural ecosystems, increase the sustainability and mul-tifunctionality of managed ecosystems and design and manage novel ecosystems. Subsequently, in a collective learning process which supported the operationalisation of the WEF Nexus, NBSs were identified that address specific contextual vulnerabilities, improve water distribution and enhance food security, while preserving ecosystems and supporting adaptation to climate change. The added value of the proposed methodology lies in the multi-stakeholder participatory approach to gain in-depth knowledge of local agri-food systems, including their main WEF-related challenges, and to facilitate overcoming barriers to NBS implementation.

The water resources policy under climate change impacts water security, which should ensure enough water of good quality for humans and nature. Integrated water management is the state-of-the-art policy support model that, after 20 years in use, failed to achieve in many countries its primary goal of water bodies' good ecological status. Here, we show that this is due to the substantial externalities the anthropocentric character of the model generates. From the historical analysis, three main results are obtained: 1) the nature-human interplay is always composed of the coexistence of two opposite behaviors of conflict and cooperation; 2) this contradiction is a dialectical, general ontological attribute; 3) on the balance of power between nature and humans, three clusters are identified: i) naturalistic; ii) dualistic; iii) anthropocentric. A novel behaviorist dialectical conflict resolution model can resolve the differences between stakeholders and natural laws. The harmonic symbiosis of humans with nature removes environmental externalities and can lead to sustainable water security. Three case studies from the literature illustrate the merits of the new dialectical model.

Inland waters pose a unique challenge for water quality monitoring by remote sensing techniques due to their complicated spectral features and small-scale variability. At the same time, collecting the high-quality reference data needed to calibrate remote sensing data products is both time consuming and expensive. In this study, we present the further development of a robotic team composed of an uncrewed surface vessel (USV) providing in situ reference measurements and an unmanned aerial vehicle (UAV) equipped with a hyperspectral imager. Together, this team is able to address the limitations of existing approaches by enabling the simultaneous collection of comprehensive in situ data together with high-resolution hyperspectral imagery. We showcase the capabilities of this team using data collected in a north Texas pond during three collections in the fall of 2020. Machine learning models for 13 variables are trained using the data set of paired in situ measurements and coincident reflectance spectra. These models can successfully estimate physical variables, including temperature, conductivity, pH, and turbidity, as well as the concentrations of blue-green algae, colored dissolved organic matter (CDOM), chlorophyll-a, crude oil, optical brighteners and the ions Ca2+, Cl−, and Na+. We extend the training procedure to utilize conformal prediction to estimate 90% confidence intervals for the output of each trained model. The maps generated by applying each trained model to the collected images reveal the small-scale spatial variability within the pond. Additionally, the permutation importance computed for each feature of the trained models highlights the spectral features relevant to each water quality variable.

Based on the analysis of hydrochemical data of 18 samples of shallow groundwater around Hancheng mining area in Guanzhong Basin, Gibbs semi-logarithmic diagram and Piper diagram were used to study the hydrogeochemical behavior of shallow groundwater around Hangcheng mining area in Guanzhong Basin. Chemical composition analysis showed that most of the groundwater was SO₄ · Cl-Ca · Mg type, accounting for 61.1 %. Hydrogen and oxygen isotope data show that groundwater in the study area is recharged by modern precipitation. The main chemical components of most groundwater are Ca²⁺, Mg²⁺, HCO₃^-, Cl^-and SO₄^2-. Ca²⁺, Mg²⁺, and HCO₃^- are mainly dolomite, calcite, and gypsum dissolution precipitation results. Na⁺ and Cl^- originate from the dissolution of halite. The main ion chemistry of shallow groundwater in this area is controlled by rock weathering, and pyrite oxidation is an important factor affecting SO₄^2-concentration. The research results will help analyze the formation mechanism of chemical components and provide some basic data for the evolution of mine water in this area in the future.

A thermal system in very deep Lake Tazawa (maximum depth, 423 m) was investigated by estimating the heat budget. In the heat budget estimate, the net heat input at lake surface and the heat input by river inflow and groundwater inflow were considered. Then, the heat loss by snowfall onto lake surface was taken into account. Meanwhile, lake water temperature was monitored at 0.2 m to the bottom by mooring temperature loggers for more than two years. The heat storage change of the lake from the loggers was calibrated by frequent vertical measurements of water temperature at every 0.1 m pitch by a profiler with high accuracy (± 0.01 °C). The heat storage change (W/m2) obtained by the temperature loggers reasonably accords to that from the heat budget estimate. In the heat budget, the net heat input at lake surface dominates the heat storage change, but the significant heat loss by river inflow sporadically occurred, which is caused by the relatively large discharge from a reservoir in the upper region. How deep the vertical water circulation in the lake occurs in winter was judged by the differences between water temperatures at 0.2 m depth and bottom and between vertical profiles of dissolved oxygen over winter. It is strongly suggested that the whole water circulation does not occur every winter, if any, very weak.

Soil nitrite (NO2‒) is an important reactive intermediate in many nitrogen transformation processes, but it is unstable under acidic conditions. Canonical extraction method of soil NO2‒ with potassium chloride (KCl) solution greatly underestimates its concentration. In order to reflect the concentration more accurately, we optimized the extraction method of soil NO2‒ in this study. Moreover, soil ammonium (NH4+) and nitrate (NO3‒) were also systematically investigated to achieve efficient extraction of soil inorganic nitrogen. The results showed that un-buffered KCl significantly underestimated soil NO2‒ concentration compared to DIW. The highest recovery of NO2‒ was obtained by extracting with DIW at 10 min of oscillation for three soils. Compared with DIW, the concentration of NH4+ and NO3‒ in soil extracted from KCl solution increased significantly. Furthermore, the soil inorganic nitrogen content of extracts stored at 4°C for one day were closer to directly measurements of fresh samples than the other storage methods. Overall, the recommend analysis method for soil NO2‒ was extracted by DIW, oscillated for 10 min, and filtered by a 0.45 µm filter, and soil NH4+ and NO3‒ were extracted with KCl solution and oscillated for 30 min. The extract should be stored at 4°C and analyzed within 24 hours.

Abstract: This study estimates consumers’ willingness to pay (WTP) for sustainability turfgrass attributes such as low-input and stress-tolerance attributes, while considering potential trade-off relationships between aesthetic attributes and sustainability attributes. To address our objectives, our study conducts a choice experiment and estimates two mixed logit models. The first model includes low-input, winter kill, and shade-tolerance attributes as predictor variables, and the second model extends the first model by adding interaction terms between aesthetic and sustainability attributes. Another choice experiment is conducted under water policies with various water rate increase and watering restriction scenarios. Results from the mixed logit models show that overall, higher low-input cost reduction, less winter-damaged, and more shade-tolerance grasses are preferred, the direct effect of aesthetic attributes on consumers’ preference is strong, but the indirect effect represented by the interaction terms are generally statistically insignificant. Our results indicate that consumers like to have a pretty lawn, but no strong consideration is given to the aesthetics of their lawn when selecting low-input and stress-tolerance turfgrasses. Our choice experiment under water policy scenarios suggests that water pricing is more effective than watering restriction in increasing consumer demand for water-conserving turfgrasses.

More water utilities are adopting Aquifer Storage and Recovery (ASR) to balance long-term water supply and demand. Due to large implementation and operation costs, ASR projects need to be optimized, particularly for energy use, which is a major operating expense. This study examines the relationships among energy use, recharge, and recovery at two ASR projects in the western United States. The major finding is an economy of scale for recovery processes, but not for gravity-fed recharge processes. The economy of scale found is as follows: the energy intensity recovered decreases with volume. This suggests it is more energy-efficient to recover large volumes of water in one interval instead of recovering smaller volumes at more frequent intervals. The H2Oaks recovery process experienced a 78% decrease in energy intensity from 0 to 50,000 m3 recovered, while the Sand Hollow site experienced a 43% decrease in energy intensity from 0 to 50,000 m3 recovered. Statistical analyses of the recovery process showed p values lower than 0.0001, R2 values between 0.43 and 0.57, and a RMSE value between 0.55 and 2.1, indicating the presence of a moderate correlation between energy and volume. This economy of scale has been observed in multiple instances in water and wastewater treatment. This finding not only has applications to ASR but also all recovery or recharge wells, whether or not they are paired with each other. Furthermore, this study confirms the need for more reliable and accessible energy data to fully understand the implications of the energy–water nexus.

Water pollution, intensified by the release of hard-to-degrade pollutants, poses severe threats to ecosystems, human health, and economic development. The existing advanced oxidation processes often involve high operational costs and may result in secondary pollution, highlighting the necessity for innovative and more sustainable solutions. To address these challenges, our study introduces a cost-effective and eco-friendly corona discharge barrier plasma discharger for wastewater treatment. Through the central composite design/response surface methodology, a high decolorization rate of 98% of methylene blue (MB) within 10 minutes was achieved by optimizing parameters such as pH and voltage. Furthermore, the mechanisms of the generation of reactive oxygen species via this device was discussed in detail and the degradation pathways of MB were described. Moreover, this device is also very energy-efficient, with a low energy density and electrical energy per order of 0.15 watt/mL and 5.79 kWh/m³/order, respectively. In conclusion, the plasma discharger developed in this study provides a cost-effective and environmentally sustainable solution for dye wastewater treatment. This research contributes significantly to the advancement of sustainable dye wastewater management practices, offering an innovative method that meets both environmental and economic objectives.

Milkfish (Chanos chanos) locally called Bangus in the Philippines, is a popular food fish in terms of production and consumption in the Philippines, Indonesia and Taiwan. This study characterized a typical grow-out milkfish farm in the Davao region in terms of socioeconomic profile, farming practices, and simple costs and returns. Three sites were chosen to conduct this study, mainly in Mati, Pantukan and Panabo in Davao region where N=43 farm workers provided information on their daily farming practices. Farms are commonly stocked with 16,000 fingerlings, harvesting occurs after every 6 months with six feeding times in a day. Moreover, workers were paid an average of Php 10,000 per month while the company had a gross income of Php 930,000 per cropping cycle. The feed cost shares 76% of the overall operational cost with a 27% return on investment for the first year of operation. Climate change impacts (e.g. higher sea surface temperature, unpredictable weather and flooding) and deteriorating water quality conditions were seen as bigger threats. Other results showed a positive relationship between stocking density and volume harvested (df=1, MS=0.0907, F=40.13, P=0.000) and income (df=1, MS=0.048, F=21.22, P=0.000). The study also showed the need for cheaper feed substitute and better benefits to farm workers.

Water electrolysis is a highly efficient route to produce ideally clean H2 fuel with excellent energy conversion efficiency and high gravimetric energy density, without producing carbon trace unlike steam methane reforming, and resolves the issues of environmental contamination via replacing the conventional fossil fuel. Of special importance lies in the advancement of highly effective non-precious catalysts for the oxygen evolution reaction (OER). The electrocatalytic activity of an active catalyst mainly depends on the material conductivity, accessible catalytically active sites, and intrinsic OER reaction kinetics, which can be tuned via introducing heteroatom N in the catalyst stricture. Herein, an efficacious nitrogenation of CuS has been accomplished, which was synthesized using hydrothermal procedure, and characterized for their electrocatalytic activity towards OER. The nitrogen-doped CuO@CuS (N,CuO@CuS) electrocatalyst exhibits superior OER activity than pristine CuS (268 and 602 mV), achieving the low overpotential of 240 and 392 mV at a current density of 10 and 100 mA/cm2, respectively, ascribed to the favorable electronic structural modification triggered by nitrogen incorporation. The N,CuO@CuS also exhibits excellent endurance under varied current rates and a static potential response over 25 h stability measured at 10 and 100 mA/cm2.

We evaluated the transcriptional response of interferon (IFN)-related genes in rock bream iridovirus (RBIV)-infected rock bream under high-, low-, or no-mortality conditions induced by different stocking water temperatures. Under the high susceptibility condition (group A, water temperature 26 °C, 100% mortality), only the Mx gene was expressed early, with prolonged expression, and with heavy viral loads of approximately 106–107 major capsid protein gene copies/μL from 4 to 10 days post infection (dpi). However, IRF1, IRF3, IRF8, STAT1, ISG15, PKR, Viperin, GVIN1, IFI44, and ISG56 were activated at later time points (8 dpi) and then quickly decreased (10 dpi). For the low susceptibility condition, the water temperature was set at 23 °C for 7 days (group B) and then reduced to 17 °C. Group B exhibited a 28% mortality rate, in which persistent and effective antiviral responses were observed for long periods of time. In particular, at 20 and 22 dpi, when virus replication was peaked at approximately 107/μL, the expressions of most of the IFN-related genes (IRF1, IRF3, IRF8, Mx, STAT1, ISG15, PKR, Viperin, GVIN1, IFI44, and ISG56) were significantly higher in group B than in the control group. Moreover, prolonged and higher levels of IRF3 (at least 30 dpi), IRF8 (at least 30 dpi), ISG15 (at least 30 dpi), PKR (at least 28 dpi), Viperin (at least 30 dpi), and IFI44 (at least 30 dpi) were also observed in the recovery stage of infection. Under the no-susceptibility condition at 17 °C (0% mortality), significantly elevated levels of IRF3, Mx, ISG15, and PKR were observed mostly until 20 dpi. The findings indicate that RBIV infection can induce an efficient IFN-mediated antiviral immune response in low- and no-susceptibility conditions. The findings could be valuable for effective control of viral pathogens in fish.

Using numerical software to establish a three-dimensional geological model of shield tunneling through fault fracture zones, considering the synchronous grouting effect at the shield tail, the disturbance of various geotechnical structures in the fault fracture zone under deep burial and high water pressure conditions is studied. According to the comparison between the numerical model analysis results and the on-site inspection results of the entire process of Shiziyang B3 section, synchronous grouting at the shield tail is the main reason for the changes in soil and water pressure in the fault fracture zone area. The soil and water pressure changes strongly during shield tunneling, and the maximum excess pore pressure value occurs when the shield tail passes. When the shield tunneling machine is far away, the soil and water stress shows a downward trend. The impact of synchronous grouting decreases with the increase of tunneling distance. Due to the difference in permeability, the variation law of pore pressure in the fault fracture zone is significantly different from the original rock, leading to a faster increase in pore pressure in the fracture zone area and a wider range of influence.

In this study, we have included the water footprint (WF) in the process of optimising animal feed rations. The global footprint of cattle production accounts for the largest share (33%) of the global water footprint of livestock production. Using two homogeneous groups of Limousine Podolian young bulls, two different diets were compared: corn silage feeding (CSF), with corn silage-based diet; and the triticale silage feeding (TSF), with triticale silage-based diet. Silage constituted about 41% and 46% of the feed composition (for CSF and TSF, respectively). Diets were characterised by the same energy and protein content. Despite the lower WF in the TSF group than in the CSF group (7726 vs 8571 l/day/calf respectively), no significant differences were found in animal performances (i.e., daily weight gain and final weight), feed conversion and income over feed costs. These results show that simple production decisions can have a significant impact on water resource. Therefore, the use of triticale silage should be further promoted, especially in world regions with limited water resources where low WF feed formulation is more strategic than elsewhere.

The anthropogenic deterioration of aquatic ecosystems affects water resources due to agricultural malpractices, pollution from domestic septic tanks, recreational activities, and poor watershed management, among others. This study examines the management of Las Curias Reservoir (176,974 m2), San Juan, Puerto Rico, post the 2016 arrival of the invasive aquatic fern Salvinia molesta. In December 2019, a community-led initiative introduced the Cyrtobagous salviniae weevil, an effective biological control agent for S. molesta, and commenced a mechanical removal campaign using an aquatic harvester. Limnological sampling (September 2019 to March 2022) and drone flights were employed to measure physicochemical and floating plant cover changes, respectively, in the reservoir. Monitoring of weevils in the reservoir demonstrated a rapid establishment and dispersal, which resulted in visible damage including browning of plants and eventually sinking of entire mats. By January 29, 2021, 71% (125,652 m2) of the reservoir surface was covered by salvinia. In 2022, the reservoir recorded an average dissolved oxygen concentration of 2.38 mg/L -1 (± 0.021, n = 144), the highest in the study period and indicative of ecosystem recovery. After three years of control efforts, dissolved oxygen, pH, and specific conductance returned to levels recorded prior to Salvinia molesta introduction. This ecosystem recovery, a first in Puerto Rico, could be attributed to an early use of mechanical control and a long-term impact of biological control.

A single geological carbon dioxide (CO2) storage within salinity aquifer as a paramount stratagem in the context of forthcoming CO2 sequestration initiatives. Within the expansive tapestry of terrestrial salinity aquifers in China, replete with nuances in mineral composition and structural diversity, a paradigm distinct from the marine sedimentary basins of North America, a labyrinthine stratigraphic environment of elevated complexity unfolds. Consequently, conspicuous lacunae and insufficiencies manifest within the existing knowledge reservoir pertaining to CO2-water-rock (mineral) reaction mechanisms. Notably, a conspicuous dearth of insights prevails concerning the dissolution kinetics inherent to individual minerals embroiled in these reactions. The present investigation undertakes a scrupulous exploration into the dissolution and erosive processes manifest within four emblematic terrestrial minerals in conjunction with CO2. Furthermore, the study meticulously scrutinizes the evolution of ionic composition and pH within the formation water throughout the trajectory of the geochemical reactions. To accomplish this, a simulation apparatus is configured to emulate conditions germane to temperature, pressure, and mineralization characteristics characteristic of a prototypical salinity aquifer reminiscent of the Daqing oilfield in China. The findings that emerge from this scrutiny reveal that the erosive action of CO2 fluid begets varying degrees of dissolution within the four minerals under investigation. Moreover, our meticulous inquiry lays bare that, in the terminal phases of the reaction process, feldspar precipitates secondary minerals, characterized primarily by dawsonite, in response to the aquatic milieu typifying the profound salinity stratum of terrestrial sedimentation. This milieu is notably enriched with Na+ ions and NaHCO3. This phenomenon suggests that feldspar, under these specific conditions, assumes the mantle of a mineral amenable to carbon sequestration, thus enriching the reservoir for CO2 mineralization within the salinity stratum of terrestrial sedimentation.

Accurate forecast of tail water level (TWL) is of great importance for the safe and economic operation and management of hydropower stations. The predictive performance is significantly influenced by the backwater effect of downstream hydropower stations and tributaries, but the explicit quantification method of the backwater effect is lacked. In this study, a deep learning model based forecasting framework for TWL predictions is established and applied to forecast TWL of Xiangjiaba (XJB) hydropower stations, which is influenced by the backwater effect of downstream tributaries including Hengjiang River (HJR) and Minjiang River (MJR). Firstly, the lag time of the backwater effect of HJR and MJR is analyzed based on the permutation importance. The results demonstrate that the lag time of backwater effect on the TWL of XJB is 5-7 hours for the HJR and 1-2 hours for the MJR. Then, the runoff thresholds of the HJR and MJR for impacting the TWL of the XJB station are obtained by scenario comparison, and the results show that the thresholds of HJR and MJR are 700 m3/s and 7000 m3/s respectively. Finally, the deep learning methods based TWL forecasting model is established based on the lag time and threshold analysis. The model is used to forecast the TWL in future 48 hours. The results show that the forecasting model has a good predictive performance with 98.22% of absolute errors less than 20 cm. The mean absolute error over the validation dataset is 5.27 cm and the maximum absolute error is 63.35 cm.

A global existential and interlocking environmental, climate and cooperation/equity polycrisis is being faced, which increasingly impacts and is impacted by water and land systems. As a result, transformations in response are gaining increasing traction. Advances in approaches to visualising and communicating how innovations and changes in landscape features enable shifts, transformations and transitions are more crucial than ever before. Visions help focus actions, collaboration and alignment of multiple actors in working towards a common purpose, whilst also entering people’s consciousness at the deep level of values, transforming beliefs and consequently, thinking and action. They give direction on effort and pull on transformational innovation. The evidence-based ‘Water Visions Visualisation Platform’ presents an innovative and accessible way to illustrate, communicate and support future water visioning and strategizing at the landscape scale based on composite paradigms, scenarios, horizons and concepts. Plausible visions of the future are envisioned, illustrated, narratively described and qualitatively assessed, as well as connected with real-world examples and resources through the interactive Platform. This paper outlines the co-creation methodology, the architecture and the co-development of the Platform, as well as a preliminary evaluation through literature-based criteria and the sharing of the Platform with a number of audiences.

Carbon dots are carbon based nanoparticles, which have the characteristics of simple preparation process, photoluminescence, biocompatibility, adjustable surface function, water solubility, and low toxicity. They are widely used in biological applications such as imaging, biosensing, photocatalysis, and molecular transfer. It has also aroused great interest among researchers in agriculture and has made significant progress in improving crop growth and production. This review presents the physiological functions of carbon dots for crop growth and development, photosynthesis, water and nutrient absorption, and abiotic stress resistance and their applications in improving ecological environment and agriculture as biosensors, and the future application prospects and research directions of carbon dots in agriculture were prospected.

This paper presents a parametric study of the multistorey hydro-powered pump, known as "Bunyip," which has demonstrated significant potential in contributing to rural regions. The study aims to understand the underlying physics of the system and enhance its hydraulic performance. A transient three-dimensional model using the commercial Computational Fluid Dynamics (CFD) tool Ansys-Fluent is utilized to gain insights into the fundamental flow mechanics, operational efficiency, standard capacity, and relative delivery. The investigation involves an initial assessment of performance for three Bunyip devices based on manufacturing data. Parametric analysis is conducted, and a parametric dataset is generated through meticulous application and numerical modelling. The CFD results are validated against experimental data. Three design configurations are considered, and 58 sets of varied input parameters are examined. The best design configuration is evaluated against five cases of conventional hydro-power pump systems. The results indicate that a smaller diameter of the pressure chamber and a higher supply head lead to higher pressure, achieving a target head of 3 m with 15% efficiency and a flowrate of 11.82 l/min.

With the gradual improvement of coal mining efficiency, the disturbance of groundwater system caused by the high-intensity mining mode also increases, which is a more severe challenge to the prevention of mine safety and the protection of water resources in mining areas. How to accurately describe the dynamic changes of the groundwater system under mining and quantitatively predict mine water inflow is a major problem in the current research. Based on the full analysis of the response characteristics of groundwater system to the extraction disturbance, this paper forms a kind of method to establish a mine hydrogeological conceptual model that can accurately represent the water inrush process, and uses the MODFLOW non-structural division grid to accurately characterize the formation structure, and finally make accurate water inflow prediction. Taking the Caojiatan Coal Mine in Shaanxi Province, China as an example, a numerical model of unstructured mine water inrush was established for the first time, and the changes of water inflow source and water inflow intensity were quantitatively evaluated. Compared with the traditional water inflow prediction method, it is found that the prediction accuracy is improved by 12%~17% by detailing the response characteristics of complex groundwater system under high-strength coal seam mining conditions. The method is of great significance and promotion value for the comprehensive understanding of the disturbance characteristics of human underground engineering activities, such as coal mining, on the groundwater system, and for accurately predicting water inflow.

Hydrogels can be considered as mimics of extracellular matrix (ECM).Cytoskeleton through integrins is connected with ECM and cytoskeleton tension depends on ECM stiffness.A number of age-related diseases depend on cellular processes related with cytoskeleton function.Some examples of cancer initiation and progression and heart disease in relationship with ECM stiffness has been analysed.Incorporation of rigid particles in ECM can increase ECM stifness and to promote formation of internal residual stresses. Water migration, changes of water binding energy to biomactomolecules, changes of the state of water from tightly bound water to free and loosely bound water changes stiffness of ECM. Risks related with rigid particles incorporation into ECM have been also iscussed.

During the development of horizontal wells in bottom water reservoirs, the strong heterogeneity of reservoir permeability leads to premature bottom water breakthrough at locations with high permeability in the horizontal wellbore, and the water content rises rapidly, which seriously affects production. In order to cope with this problem, a new technology has emerged in recent years that utilizes gravel filling to block the flow in the annulus between the horizontal well and the borehole, and utilizes the Inflow Control Device (ICD) completion tool to carry out segmental water control in horizontal wells. Unlike conventional horizontal well ICD completions that use packers for segmentation, gravel pack combined with ICD completions breaks the original seg-mentation routine and increases the complexity of production dynamic simulation. In this paper, the flow in different spatial dimensions such as reservoir, gravel packed layer, ICD completion section and horizontal wellbore is modeled separately, and the annular pressure at different locations is used as the solution variable for the coupled solution, which realizes the prediction of oil production, water production and water content of gravel pack combined with ICD completions of horizontal wells. The model was used to calculate the effects of different crude oil viscosities, different reservoir permeabilities, different permeabilities of gravel packed layers, and different development stages on the water control effects of gravel pack combined ICD completions and conventional ICD completions at field conditions. This study provides a basis for using gravel pack combined ICD completions in horizontal wells in bottom water reservoirs.

The cutting of difficult-to-machine materials, including their preconditioning, often requires specialised tools and machinery. An alternative processing technology can be cutting materials with a water jet. From the initial stage, the selection of appropriate technological parameters will influence what further finishing treatments will be applied. Vibrations occurring during this process can negatively affect the quality of the cutting edges and surfaces. Therefore, this study analysed vibrations during water-jet cutting with variable technological parameters (speed vfi and pressure pi). To measure the vibrations, a three-axis accelerometer from SEQUOIA was used in water-jet cutting of three materials: aluminum alloy, titanium alloy, and steel. Based on the study, it was found that the maximum value of vibration amplitude reaches the lowest value of vibration acceleration for aluminum alloy (not exceeding 5 m/s2), regardless of the value of pressure during the cutting process. This, taking into account the material properties, indicates that aluminum alloy is the material most susceptible to the cutting process while maintaining a high quality of the cutting surface. Significantly higher values of vibration acceleration amplitude (reaching up to 60 m/s2) during cutting were registered for steel and titanium alloy in all zones and phases of the process (entry zone, cutting zone, and exit zones).