Whereas waste management research has focused on mostly urban municipalities in South Africa, not much is known about the current performance of waste management services from the perspective of community residents in rural municipalities. This study reports on the status and effectiveness of waste management practices from the perspective of community residents in the Umkhanyakude and Zululand Districts in the rural areas of the KwaZulu-Natal province of South Africa. Making use of structured questionnaires, primary data was obtained by interviewing 333 respondents representing households in the study area. Results have revealed several shortfalls in the provision of municipal waste management services, except for solid waste removal from households (66%), and management of landfill sites (41%). The degree of dissatisfaction for waste management services rendered was very high (97.3%). Furthermore, the majority (61.4%) of respondents were not willing to participate in waste segregation due to lack of appropriate knowledge and infrastructure. The study also pinpointed some benefits associated with waste minimization, as well as barriers constraining effective waste recycling. Based on these findings, there is a dire need for transforming current waste management practices toward increased recycling rates by creating more environmental awareness and a supporting infrastructure.

Driven by environmental sustainability concerns, the integration of biobased components in curtain wall systems is gaining traction in both research and the construction market. This paper explores the development and validation of a bio-based façade system within the Basajaun H2020 project. The project aimed to demonstrate the feasibility of introducing environmentally friendly bio-based components into the mature curtain wall façade industry. The paper focuses on identifying technological solutions for replacing key components such as profiles, insulation, and the tightness system with bio-based and less environmental impact alternatives presenting the results achieved in the façade system design of the Basajaun project funded by European Union. These solutions aimed at creating a bio-composite-based curtain wall façade that adheres to current building envelope standards and normative; to implement diverse façade typologies for vision panels, opaque sections, and integrated windows; to engineer the prefabrication process for industrialization, enabling wider market replication and simplified transport and installation. The results demonstrate that the Basajaun façade successfully integrates selected components and meets the performance requirements set by regulations. However, questions remain regarding the workability of bio-based profiles as a commercially viable, ready-to-market solution that can replace traditional aluminum profiles in the curtain wall façade industry.

The rapid increasing rate of soil and water bodies pollution is the main anthropogenic effect caused by the mismanagement of post-consumer plastics. This research evaluated the effectiveness of cattail (Typha Latifolia) fibers (CFs) as bio-adsorbents of microplastic particles (MPPs) from wastewater. The effect of the adsorption environment composition on the adsorption rate was investigated. Batch tests were conducted to evaluate the “spontaneous” adsorption of MPs onto CFs. Five MPPs materials (PVC, PP, LDPE, HDPE, and Nylon 6) were evaluated. An industrial wastewater (PW) and Type II Distilled Water (DW) were employed as adsorption environments. The batch tests results show that CFs are effective in removing MPPs from DW and PW. However, higher removal percentage of MPPs were obtained in PW, ranging from 89% to 100% for PVC, PP, LDPE, and HDPE; while the adsorption of Nylon 6 increased to 29.9%, a removal increased of 50%. These observations indicate that hydrophobic interactions drive the “spontaneous and instantaneous” adsorption process and that adjusting the adsorption environment effectively enhances the MPPs removal rate. This research demonstrates the important role that bio-substrates can play in reducing the environmental pollution as efficient, sustainable, low cost, and reliable adsorbents for the removal of MPPs from wastewaters.

Indigo leaves form various plant species are sources of dyes/pigments, not fully exploited for making sustainable textiles. Blue indigo vat dye extracted from indigo leaves, yields high wash colorfastness but fades slowly with light, and is not easily used for direct printing. Indigo leaves can be used to produce textiles of various color shades, while light resistant Mayan-inspired hybrid pigments have not yet been used for textile coloring. Using blue indigo dyes from 3 plant species, with exhaustion dyeing, intense wash resistant blue colored textiles are produced, and in the case of Indigofera Persicaria tinctoria, textiles have antibacterial activity against S. Epidermis and E. Coli.100% Natural Mayan-inspired blue indigo pigment, made from Sepiolite clay and indigo dye, was used both in powdered and paste forms to perform pigment textile dyeing by pad cure process, and direct screen printing on textiles. A water-based bio-binder (40%) was used efficiently for both padding and printing. Bio-based Na Alginate thickener allowed color fast printing on both polyester and cotton fabrics, while bio-based glycerin allowed good print color fastness on polyester only, yielding prints with excellent color fastness to wash (5/5), to dry and wet rubbing (5/5) and light (7/7).

The use of food waste disposers in gastronomical facilities influence the municipal wastewater composition. Ground food waste poses problems in the operation of the sewerage network and generates high electric energy consumption in wastewater treatment plants (WWTP). The study aimed to determine, for five towns with a PE of 4,000 to 220,000, the volumes of catering waste discharged to the WWTPs. The towns differed in the number of inhabitants, beds in hotel and catering places. The calculations were made based on data received from the operators of WWTP. The pollutant concentrations in 2019, were compared with data from the "pandemic" year - 2020. The loads of catering waste entering the sewerage system in 2019 ranged from 32.7 to 1062 tons. In town with the largest tourist base, the BOD value in 2020 accounted for 62.3% of 2019 value. In the largest town, the annual energy consumption for food waste treatment could be up to 2,539,770 kWh. If the waste was fermented, it could be obtained up to 1,376,650 m3 of methane. There is a strong need for implementing a collection system for food waste from catering facilities and its fermentation to produce methane, which can be used for energy purposes.

In this paper, a completely different metaheuristic algorithm called the Orangutan Optimization Algorithm (OOA) is introduced, which replicates the complex and adaptive behaviors of Orangutans in their natural habitat. The main inspiration for OOA lies in the strategic foraging techniques of Orangutans, alongside their highly developed nesting abilities. More words are used to provide a detailed theoretical explanation of OOA, followed by a comprehensive modeling of the algorithm’s implementation in two key phases: exploration and exploitation. These phases are mathematically structured to ensure the balance required for optimal search processes. The performance of OOA is rigorously evaluated using twenty-nine benchmark functions from the CEC 2017 test suite, with problem dimensions of 10, 30, 50, and 100. More sentences are included to elaborate on the optimization outcomes, which reveal that OOA effectively balances the exploration and exploitation stages, yielding suitable and competitive solutions across the benchmark functions. Additionally, to further validate its quality, the results from OOA are compared against twelve other well-established metaheuristic algorithms. The analysis of these simulation results demonstrates that OOA consistently outperforms competing algorithms by achieving superior results across most benchmark functions. Furthermore, to assess its real-world applicability, OOA is implemented on a set of twenty-two constrained optimization problems drawn from the CEC 2011 test suite. The extended simulation results clearly indicate that OOA is highly efficient in solving real-world optimization challenges, consistently delivering a superior performance when compared to other competitor algorithms.

The effects of reaction temperature, reaction time, heating rate, nitrogen flow rate and catalyst quality on the oil yield and oxygen content in the oil were investigated by using the single factor principle. Too high and too low reaction temperature, nitrogen flow rate, heating rate and reaction time have improved the yield of bio-oil, but the oxygen content in bio-oil is higher. The reduction of catalytic dose is beneficial to the increase of oil yield but not conducive to the increase of aromatic compound content. The optimal reaction conditions were observed as reaction temperature of 500℃, nitrogen flow rate of 110 mL/min, heating rate of 20℃/min, reaction time of 15min, mass ratio of catalyst to coconut coat powder was 1, and the oil yield was 4.97%, aquatic yield was 35.80%, and solid yield was 30.78%. The gas yield was 28.45%, the oxygen content was 10.3%, and the aromatic compound content was 89.7%.The analysis of catalytic cracking mechanism shows that most of the oxygen-containing compounds in the bio-oil are generated into water and aromatic compounds by catalytic cracking reaction at high temperature, thus removing oxygen.

The nuclear fusion reaction can be catalyzed in a suitable fusion fuel by muons(heavy electron)."For the fractal relation, ranging from DNA knots to solar neutrino flux signals" ever derived f scale-invariant properties distinguished between classical invariant theory & quantum invariant theory subfactors. Accompanying isomorphicity & Connes Fusion Tensor Product retrieved to muon-catalyzed fusions where surroundings of room temperature fusion driven by the balance in mt-Dna fusion &fission.

In this study, a field experiment was conducted to evaluate the growth and yield responses of Sri Lankan lowland rice (Oryza sativa L.) with the application of beneficial Arbuscular mycorrhizal fungi (AMF) inoculum, and inter-cropping with highly mycorrhizal dependent vetiver grass (Chrysopogon zizanioides L.) under two different soil nutrient management systems (NMSs): conventional/chemical (CNMS) and organic (ONMS). The experiment was designed as a split plot with three blocks. Each CNMS and ONMS experiment included untreated control (T0), and three treatments—AMF inoculation (T1), vetiver intercropping (T2), and the combination of AMF and vetiver (T3). According to the results, colonization of rice roots with AMF was not affected significantly by the treatments and ranged from 0‒15.8%. The effect was very low or absent in the early stage and then higher in the later stages of the rice plant. Furthermore, plant growth was not significantly different between the two NMSs, although grain yield was significantly higher (P < 0.05), with the order T1 (0.45 kg/m2) >T2 (0.42 kg/m2) >T3 (0.41 kg/m2) in CNMS and T2 (0.44 kg/m2) >T1 (0.41 kg/m2) >T3 (0.40 kg/m2), in ONMS than for the respective controls (T0), thus suggesting beneficial utilization of AMF and vetiver in the lowland rice farming system.

Antimicrobial peptides (AMPs) have emerged as a promising class of bioactive molecules with the potential to combat infections associated with medical implants and biomaterials. This review article aims to provide a comprehensive analysis of the role of antimicrobial peptides in medical implants and biomaterials, along with their diverse clinical applications. The incorporation of AMPs into various medical implants and biomaterials has shown immense potential in mitigating biofilm formation and preventing implant-related infections. We review the latest advancements in biomedical sciences and discuss the AMPs that were immobilized successfully to enhance their efficacy and stability within the implant environment. We also highlight successful examples of AMP coatings for the treatment of surgical site infections (SSIs), Contact lenses, Dental Applications, AMP-Incorporated Bone Grafts, Urinary tract infections (UTIs), Medical Implants, etc. Additionally, we discuss the potential challenges and prospects of AMPs in medical implants, such as effectiveness, instability and implant-related complications. We also discuss strategies that can be employed to overcome the limitations of AMP-coated biomaterials for prolonged longevity in clinical settings.

The utilization of lignocellulosic biomass as an alternative energy source presents a promising opportunity to achieve a future energy system that is clean and free from CO2 emissions. To realize this potential, it is crucial to develop effective techniques for converting biomass and organic solid waste into secondary energy sources. Among the available options, hydrogen production stands out due to its numerous advantages, including its cleanliness, versatility in conversion and utilization technologies, high energy efficiency, and dense energy content per unit weight. This article offers a comprehensive overview of different conversion pathways and important technologies for generating hydrogen from biomass and organic solid waste. It specifically focuses on the thermochemical conversion process, which shows promise as an economically viable approach. While certain thermochemical conversion processes are still in the developmental phase, utilizing organic biomass for hydrogen production is widely recommended due to its ability to yield higher amounts of end products and its compatibility with existing facilities. However, it should be noted that this method necessitates a substantial amount of energy due to its endothermic nature. The article also explores alternative hydrogen conversion technologies and their potential for utilizing organic biomass as a feedstock, while addressing the challenges and limitations associated with these methods.

: Microbial fuel cell (MFCs) devices utilise the metabolic processes of bacteria to generate electricity from various organic substrates. Due to the enormous amount of energy that organic waste produces, scientists are highly interested in advanced MFCs. MFCs serve as a multidisciplinary research platform at the engineering and natural sciences intersection. MFCs have various uses besides being used as energy sources, such as sensing capabilities. Despite showing considerable promise, only a few marine sediment MFCs have been deployed in real-world applications to supply current for low-power devices. It is now required to maintain track of the work being done by research groups worldwide and regularly compile significant discoveries due to the rising quantity of research publications. Review papers are a traditional beginning point for a literature review for new scholars. This review is a fast reckoner that directs readers to pertinent reviews and research publications detailing significant advances in microbial fuel cell research during the previous two decades. An overview of key advances in MFC research over the past two decades is provided as a quick reference in this review article. In addition, the report identifies research gaps that, if filled, could bring this technology closer to real-world use.

Natural astaxanthin is a precious substance obtained from some organisms such as microalgae. This plant has many benefits for humans, so research into its cost-effective and economical production has recently increased. For this purpose, some methods such as the use of different culture media, gene engineering, different stresses, nanoparticles, bio acids, and phytohormones are important. Accordingly, this review study was conducted to demonstrate the effect of the factors mentioned above for the high production of astaxanthin in microalgae, especially Haematococcus pluvialis (H.p).

Briquetting of biomass is an ideal technique for improvising both its volumetric and net energy density; besides, serving as an effective means for reducing pollution. In general, numerous biomass and organic by-products are discarded as wastes, citing their non-edibility, composition of chemical compounds present in their raw form, in addition to their zero usage value. Yet, these biomass wastes hold significant heating values, which promote them into promising solid biofuels, either in their existing or pre-treated form. Accordingly, this review article discusses about the various biomasses used as raw feedstock for briquetting, besides summarising the works carried out in relevance to their respective briquettes. In addition, proximate and lignocellulosic composition of these biomasses, and their pre-treatment techniques followed to prepare them for briquetting, have also been discussed. This study suggested that the heating value of biomasses ranged between 10-20 MJ/kg, whilst, their briquettes reported between 15 and 25 MJ/kg; thereby citing their potential as viable replacement for existing fossil coals. Besides, factors affecting different thermal and physicochemical properties of these briquettes have also been studied and concluded that these properties play a crucial role in deciding the overall quality of the briquettes. Ultimately, this study proposed that any biomass with good calorific value and lignin content can be processed into briquettes with good strength and durability; however, the choice of biomass will also be accounted for by its availability, geographical distribution, and handleability.

The natural forests of Northern Thailand are the mother source of many utilisable natural products because of their diverse flora and fauna. Among many plant species found within Northern Thai forests, detergent plants are known for its distinctive cleansing properties. Several local species of detergent plants in Thailand are traditionally used by the locals and indigenous people. However, these plants may become extinct because their habitats have been replaced by industrial agriculture, and their uses have been replaced by chemically synthesised detergents. Researchers need to study and communicate the biology, phytochemistry, and the importance of these plants to conserve natural biodiversity of Northern Thailand. Of many utilisable detergent phytochemicals, natural saponins are known as bio-surfactant and foaming agents. Their physiochemical and biological properties feature structural diversity, which leads to many industrial applications. In this review, we explained the term “detergent” from the physiological mechanism perspective and the detergent effects of saponin. We also compiled a list of Thai local plants with cleansing properties focusing on the saponin-containing plants. Future studies should investigate information relative to plant environment, ethnobotanical data and bioactive compound content of these plants. The knowledge acquired from this study will promote the maintenance of the local biodiversity and the conservation of the detergent plant species found in Thailand.

Water and sanitation facilities in sub-Saharan Africa and Africa in general are appalling and for the most part absent. Progress continues with respect to the development of plant materials as potent adsorbents, disinfectants, coagulants, flocculants, wetland species and lots more as substitutes for the dangerous chemical disinfectants. This research presents the potential of phyto-active components of Zanthoxylum zanthoxyloides and Gongronema latifolium as effective biocides against water microbial contaminants. Dry powder of Zanthoxylum zanthoxyloides and Gongronema latifolium were extracted and prepared into different concentrations with ethyl acetate and chloroform, ranging from 25 to 500 mg/ml. These fractions were then examined for antimicrobial activities against inherent bacterial and fungal water contaminants using disc diffusion assay. Fractions were afterwards screened for phytochemical active compounds using standard methods. Crude extracts of the different plant examined selectively comprise saponins, tannins, reducing sugars, anthraquinones, flavonoids, terpenoids, phlobatanins and alkaloids. All plant extracts showed broad spectrum antibiosis against selected gram positive and gram negative bacteria including E. coli, P. aeruginosa, Klebsiella sp, S. pneumoniae and B. cereus, as well as tested fungi, including A. niger, A. flavus, Trichoderma sp and Candida sp. While all extracts exhibited maximum antibiosis at 500 mg/ml, the chloroform extracts compared well than ethyl acetate extracts. The overall results revealed that antimicrobial activities of the plant extracts are dose dependent with comparative activity greater than that of commercial antibiotics at the concentration of extracts tested. E.coli was the most susceptible microbial isolate tested and represents the potential of the extract against a group of coliform which are important indicators of microbial pollution in water. Other microbial isolates also recorded sensitivity to extracts tested at varying degrees. The findings indicate that microbes tested were mostly susceptible to chloroform extract of Z. zanthoxyloides and G. latifolium except for the activity of ethyl acetate extract of Z. zanthoxyloide against E.coli. Results of phytochemical screening of the extract also showed the varied presence of alkaloids, saponins, tannins, flavonoids, terpenoids and anthraquinones The results indicated that plant materials investigated can be developed as effective biocides against water microbial contaminants

Any Hospital’s primary goal is to restore human health and save lives through health services provided to patients, but at the same time, hazardous wastes are produced. Inconsistent management of unsafe wastes might cause adverse effects and other issues to workers, the environment and public health. Segregation is considered the critical stage for a successful Healthcare Waste Management. Mixing hazardous waste with non-hazardous waste will be avoided by correctly applying practices at the segregation stage. This study aimed to assess personnel’s knowledge about Infectious Medical Waste and segregation practices used at six wards in Nicosia General Hospital. An analytical cross-sectional study was conducted, and data were collected through a structured self-administered questionnaire. The Statistical Package of Social Science (SPPS) version 25 was used with a minimum statistical significance α=0.05. The study population was nurses, nurse assistants, ward assistants and cleaners working at the study wards. Out of 191 questionnaires, 82 were received, with a response rate of 42.93%. Most participants were female (72%) and nurses (85,4%). Participants had medium to good knowledge about Infectious Medical Waste management and good knowledge regarding segregation practices applied in their ward. Segregation was not carried out as it should have since most participants stated that Infectious Medical Wastes were mixed with non-hazardous waste. Correct answers given by the participants regarding color-coding of different Healthcare Waste categories was 67.5%, and only four answered correctly to all questions. Although participants knew segregation practices and the colour-coding process applied for Healthcare Waste, they didn’t use them satisfactorily. They applied methods regarding segregation without specific training, knowledge and guidance. Due to the issue's importance, training programs must be implemented and performed.

The management and classification of solid waste is one of the most important challenges around the world, in order to sustain economic growth and preserve the environment. The objective is to propose the use of Smart Ecological Points as a strategy to address the problem related to the solid waste management system at the source, which has become one of the biggest problems globally and Colombia is no exception. The article describes the current state of the problem in the country and in turn, presents the possibility of developing a prototype corresponding to a low-cost Smart Ecological Point supported by the use of an experimental capacitive sensor and Machine Learning algorithms, which will reduce the time necessary for the classification of recyclable and non recyclable waste, minimizing the health risks and increasing the percentage of waste that can be reused, by reducing the probability of being contaminated at the source, an aspect that is very common when done manually. According to the results obtained, it was evident that the proposed prototype made an adequate classification of waste, generating the possibility of being manufactured with existing technology in the environment, in order to promote adequate waste classification at the source.

The article discusses an alternative way of recycling radioactive waste (RW), presented in the form of radioactive building materials - concrete and reinforced concrete structures and metal fittings, with the further use of materials, obtained during recycling, in the space industry. That is, it is supposed to send radioactive waste into space not as a passive ballast, but as a payload that will operate in space under conditions of increased radiation.

Insecticide testing facilities that evaluate a variety of vector control products may generate large amount of hazardous wastes from routine operations. These wastes originate from degraded technical grade materials, sprayed substrates, redundant stock or working insecticidal solutions. The washing of Long-Lasting Insecticidal Nets (LLINs) during preparation for laboratory and experimental hut trials also contribute to waste water with insecticide content. Human and environmental exposure to insecticidal waste can occur during transport, categorization, storage and disposal in resulting in environmental pollution and potential health effects. Various national and international guidelines have been devised for safe disposal and should be strictly followed to avoid adverse effects on humans or environment. The current paper describes a case study from insecticide test facility in north-eastern Tanzania in management of insecticidal waste.

Solid-state lighting has been replacing conventional lighting in the market, raising concerns for implementing an efficient end-of-life management system. Since LED waste streams have not been quite dominant, characterization studies (product-level characteristics, component-wise information, bill of materials, diversity, and differences) are inconsistent and having substantial gaps. This study investigates the end-of-life LED lamp literature, focusing on the bill-of-materials, and reveals that the characterization procedure suffers from a severe lack of sample representativeness. Consequently, characterization results are widely varied and not generalizable. Moreover, most of the studies did not inform and document the detailed sample characteristics, precluding the possibility of identifying reasons for variation. Combining available information from the recent studies, we present a mass distribution at the component level, exemplifying the prospect for meeting EU regulatory limit and the need for more insight at the lamp and component level. To fill the disconnection between lamp level characteristics and component and material content, we propose a characterization protocol that carefully documents lamp, component, and material level information by establishing a lamp-component–material composition nexus. The protocol may help researchers, policymakers, and industrial stakeholders conduct a systematic characterization, analyze complexities and prepare for a sustainable solution.

Lignocellulosic fungi are highly versatile organisms with valuable applications in bioremediation processes, including the biodegradation of agro-industrial effluents. In this work, the use of a native strain of the white-rot fungus, Pycnoporus aff. sanguineus, was studied for its use in the bioremediation of the sugar industry waste called vinasse, originating from the San Martín del Tabacal Sugar Mill, located in the north of the Salta province, Argentina. We studied under controlled laboratory conditions the bioremediation process of 3 concentrations of vinasse (5, 10, and 25% in distilled water) with a native isolated strain. The results showed biomass growth at all three tested concentrations, with a maximum at the highest vinasse concentration (25%), while the percentages of color and Chemical Oxygen Demand (COD) removal indicated that the most efficient treatment was with 10% vinasse. The results obtained are promising for the treatment of effluents from the sugar industry using white-rot fungi considering the valuable subproducts of Pycnoporus spp. biomass.

This report aims to document the extent of plastic waste pollution in lorry stations in Accra, assess its impact on public health and propose actionable solutions for effective waste management in stations. By highlighting the severity of the issue as well as providing recommendations for solutions, we seek to inform and inspire municipal assemblies, policymakers and other stakeholders to take decisive action against plastic waste pollution in lorry stations in Accra. Plastic waste pollution is a growing concern in Ghana, with lorry stations being particularly affected due to high foot traffic and inadequate waste management infrastructure within stations. This report is significant because of its implications for addressing public health hazards, continuing the ongoing efforts to reduce plastic pollution in Ghana and addressing community concerns. Through this comprehensive analysis, Mckingtorch Africa aims to drive meaningful change and create a cleaner, healthier Ghana for present and future generations.

Traditional lime-based materials have considerable potential for use as components of green materials for plastering and finishing building surfaces in both new construction and historic heritage conservation. The paper presents the preliminary results of a research activity aimed at developing pre-packaged products based on Traditional Lime Putty (TLP) by partially replacing natural aggregates with Stone Waste Sludge (SWS), with a low rate of recovery from Apricena limestone production district in Apulia. The mineralogical and chemical analysis carried out by means XRD (X-Ray Diffraction), TG-DTA (Thermo Gravimetry-Differential Thermal Analysis) and hydrochloric acid attack test showed that the SWS consisted of 98.4 % CaCO3 by mass. The particle sizes measured by laser diffraction technique are below 22.5 μm for the 92% by mass of the sample. The high fineness of the stone waste was confirmed by the Blaine specific surface method equal to 9273.79 cm2/gr. The behavior of three fresh mixtures for prepacked coarse plaster, fine plaster, and finishing plaster with 12.90%, 17.94%, and 18.90 by mass of SWS, respectively, was evaluated by spreading test and applicability tests on a perforated ceramic slab. The finishing plaster has the highest consistency value of 235 mm, while the fine plaster and the coarse plaster have values of 205 mm and 155 mm, respectively. The coarse plaster is suitable for the use as base plaster (arriccio) or second layer rendering (tonachino) up to a thickness of approximately 1 cm. Both the fine plaster and finishing plasters can be used for the surfaces finishing with the application of layers of a few millimeters thick.

Plastics, once regarded as a revolutionary material shaping modern society, now poses an unprecedented threat to our environment. Household solid waste sorting stations produce several fractions, one of which contains a high concentration of Low-Density Polyethylene (LDPE) film waste (packaging, sunscreen film, etc.). This fraction is difficult to recycle because it contains quite a lot of impurities. Usually, it is sent to the cement factories that burn it together with other fuels. However, with some processing techniques such catalytic pyrolysis this fraction could be valorized. In this paper the experiments which were carried out at a laboratory scale installation, in batches with a processing capacity of 1-3 kg of waste. The pyrolysis reactor is connected to a distillation column giving the possibility to separate the fractions. The gaseous and liquid fractions were characterized by GC-FID-TCD (gases) and GC-MS (liquids) analysis. Natural catalysts such as bentonite or clinoptilolite were studied and used in the melting of plastic mass to simplify the process as much as possible. To test the activity of the catalysts, the pyrolysis of LDPE granules was initially studied. It was found that natural zeolites are much more active than bentonite and that a minimum concentration of 5-10% is needed to have a positive effect on the composition of the fractions (increasing the weight of the light fractions C1-C6, C6-C10 and C11-C13) in relation to the heavy fractions C13-C20 and C20+. Catalytic pyrolysis gives a completely different distribution of light hydrocarbons. The best catalyst selected from LDPE lab experiments, was then tested upon the pyrolysis of plastic film waste obtained by a waste treatment plant. The research objective reported in this paper was to obtain a fraction of combustible gases in the largest possible proportion, which can be much easier exploited by burning in an engine that drives an electric generator.

This research seeks to solve the multi-faceted problem of waste disposal by analyzing the application of waste plastic and tyre material within non-structural concrete to ensure more sustainability and less environmental degradation. Study focusses on material properties including specific gravity, water absorption and bulk density and characteristics of the concrete that is produced by the utilization of the above waste aggregates including workability, compressive strength, flexural strength and tensile strength. This paper employs secondary data collection and MATLAB in the analysis of the findings pointing to the fact that the mechanical properties reduce with the level of waste content yet emphasizing the green aspect of such materials. Thus, a complex and diverse effect is demonstrated by the life cycle assessments (LCA) for global warming, ozone depletion, terrestrial ecotoxicity, and acidification. Furthermore, the utilization of waste materials decreases the compressive, flexural, and tensile strength, but it provides distinct ecological benefits which prove the importance of proper mix proportions for concrete performance. The outcomes of this research will be useful for further investigation in the application of the concept as well as to call for the development of new ideas for the improvement of bonding of wastes to aggregates in concrete.

The paper presents a thorough examination of the burgeoning field of utilizing manufacturing waste for sustainable energy generation, aligning with the global imperative for resource efficiency and clean energy solutions. With the manufacturing sector being a significant contributor to waste generation, this study explores innovative approaches to transform waste materials into valuable resources, thereby mitigating environmental impacts and contributing to a circular economy. This work critically reviews current trends, emphasizing technological advancements, policy interventions, and market dynamics shaping the manufacturing waste utilization landscape. Noteworthy developments, such as advanced sorting technologies and the integration of digital solutions, are discussed in detail, showcasing their role in enhancing the efficiency of waste management processes. The study outlines future trends in the field, anticipating a shift towards closed-loop systems guided by circular economy principles. This comprehensive review aims to contribute to the discourse on sustainable waste management and energy generation by providing a holistic perspective on the field's current state and offering insights into the future trajectories that will propel manufacturing waste toward a more sustainable and circular future. The synthesis of technological innovation, collaborative efforts, and evolving regulatory frameworks presents a compelling case for the continued exploration of manufacturing waste as a valuable resource in the pursuit of a more sustainable and energy-efficient world.

In South Korea, demolition waste (DW) management has become increasingly significant owing to the rising number of old buildings. Effective DW management requires an efficient approach that accurately quantifies and predicts the generation of DW (DWG) of various types, which necessitates access to the required information or technology capable of achieving this. Hence, we developed an artificial intelligence-based model that predicts the generation of ten DW types, specifically from buildings in redevelopment areas. We used an artificial neural network algorithm with < 10 neurons in the hidden layer to derive individual input variables and optimal hyperparameters for each DW type. All DWG prediction models achieved an average validation and test prediction performance (R²) of 0.970 and 0.952, respectively, with their ratios of percent deviation ≥ 2.5, ver-ifying them as excellent models. Moreover, a Shapley additive explanations analysis revealed that DWG was most impacted by the floor area for all the DW types, with a positive correlation with DWG. Conversely, other factors showed either a positive or negative correlation with DWG de-pending on the DW type. The study findings will enable demolition companies and local gov-ernments in making informed decisions for efficient DW management and resource allocation by accurately predicting the generation of various types of DW.

Waste recovery is an important aspect towards human and environmental health protection. Unfortunately, proper food waste management is among the serious challenges in the field of solid waste management worldwide. Therefore, it is of great importance to conduct studies towards achieving efficient and cost-effective approaches for food waste management. This study investigated the potential of recovering food waste through maggots’ production as animal feed. The influence of fly attractant application on maggot production was also investigated. The study also investigated the potential of maggot production for waste recovery and reduction. Four different types of food waste (starch food leftovers, rotten bananas and peels, rotten pineapple and peels, and rotten oranges) were used in the investigation process. From the results, it was observed that the application of fly attractants had a significant effect on the production of maggots as determined by the weights after harvesting. Average weight of 94 g/kg of maggot was achieved from banana materials with an application of fly attractant during the 8th day of the cultivation; which is equivalent to a 32.4% increase from the same day when the material was cultured without applying fly attractant. Also, from the starch materials, about 77 g/kg of maggot weight was achieved; which is a 54.6% increase from the same day and the same material but without application of fly attractant. Moreover, the relative dry weight reduction in the trials varied from 52.5% to 82.4%.

The recycling, incineration, and final disposal rate of municipal solid waste (MSW) are calculated based on the total amount of waste input to each facility in many countries. These statistic data have serious limitation in setting the national goal and policy for effective waste management because it is not considering the amount of foreign objectives in the process of each life-cycle stage. This case study is to estimate the actual rates of recycling, incineration, and final disposal by material flow analysis (MFA) after the collection of MSW in Korea. The actual rates of recycling, incineration and final disposal for MSW in 2016 were 49.9%, 32.9% and 23.1% respectively, indicating that the recycling rate was lower by 10.1%, while the incineration and final disposal rates were raised by 7.6% and 8.4% respectively, compared with the statistics for current MSW. In addition, the changed actual rates of recycling, incineration treatment, and final landfill, and variation of waste treatment charge according to treated amounts per treatment method was analyzed. This results of this study will contribute to establish national level of plan on effective waste management.

SDG target 12.3 calls for halving food waste at retail, food service, and household by 2030. The food waste index for this purpose includes parts attached to food that are usually removed intentionally ("unavoidable food waste") and allows counting the conversion to animal feed and utilisation as biomaterial as means of reduction. In Japan, the "Food Waste Recycling Law" which has been in effect since 2001, promotes the recycling of food waste generated from businesses, designating feed conversion as top priority. On the other hand, based on the more recent "Food Loss Reduction Promotion Act" of 2019, the government is currently promoting the reduction of avoidable food waste, as to meet the SDG target. Based on statistical sources and interviews with Ministry officers, this paper explains the history and achievements of Japan's 23-year policy based on the Food Recycling Law, as well as the tension between the two legislations.

Global warming and climate change have been the major concern for multiple disciplines. Population growth, urbanization, and industrialization are major contributing factors to such a problem by escalating the use of fossil fuels to meet their energy demands. The building sector has the largest share in using the total globally produced energy and emitting tons of greenhouse gas emissions. Emerging eco-friendly technologies such as solar and wind energy harvesting are being extensively explored but still, they are insufficient. Nature-inspired technologies can be the solution to our problem. For instance, algae are microorganisms that use water, light, and CO2 to produce energy and sustain life. Exploiting such characteristics in the built environment is termed algae building technology, a very efficient and green application for a sustainable future. Algae-integrated façades show great versatility through biomass and energy production, wastewater treatment, shading, and thermal and acoustic insulation. In this paper, algae will be introduced as a robust tool toward a greener and more sustainable future, The algae-building technology and its implementation will be demonstrated. Steps for applying this sustainable approach in Egypt will be discussed.

Molluscs are significant species in aquatic ecology. Molluscs are crucial for maintaining ecological balance as secondary consumers and serving as bioindicator species in biomonitoring systems. Molluscs are threatened by pesticides such as commonly used pyrethroid insecticides. Pyrethroids are typical insecticides used to control insects in agriculture and gardening. Pyrethroids are increasingly being utilized in both agricultural and human activities. Pyrethroids enter aquatic bodies through rainfall and drainage systems. The use of pyrethroids is becoming a significant concern for aquatic creatures, particularly molluscs. The discussion will focus on the increasing issue of pyrethroids becoming a nightmare for molluscs. Pyrethroids, due to their lipophilic nature, pose a significant risk to molluscs by affecting their metabolites, producing reactive oxygen species, and influencing neurotransmitter actions. Molluscs are crucial organisms in aquatic ecosystems, and their threats warrant significant discussion and attention. This review will delve into the behaviour of pyrethroids on molluscs.

The biofibres wide application as mortars enhancement have been so far restricted by factors related to their chemical composition and hygroscopic nature. Their hydrophilic behavior increases the water demand of mortar-mixtures and diminishes their adhesion to the matrix, while further moisture-related fibre degradation issues may arise. Additionally, the natural fibres seem to be susceptible to degradation caused during the exposure to alkaline environments conditions, such as those of cement mortars, restricting their utilization in construction industry. Therefore, the current study focusses on the potential of fibre modification through treatments that would permanently alter their structure and chemical composition in the whole mass or surface towards their performance improvement. In this study, mild hydrothermally treated wood fibres of black pine and beech species were prepared and incorporated in cement mortars to assess their performance, applying the proportion of 1.5% v/v in the mortar. The mortars workability (at fresh state), physical, hygroscopic, chemical, thermal, and mechanical characteristics at the age of 28, 90 and 365 days and weathering performance by subjecting them at different artificial ageing environments (freeze-thaw cycles or outdoor exposure) were examined. The results indicated the beneficial role of the treated fibres in the dimensional stability, flexural strength, thermal insulation properties and capillary absorption of the mortar specimens, especially during ageing process, with the black pine fibres to reveal the highest improvement. The hydrothermally treated wood fibres seem to ensure the integrity maintenance of cement mortars under all ageing conditions, proving that the specific bio-additives could provide low-cost and eco-friendly mortar enhancement pathways.

The results of the investigation showed that second-order kinetics govern the adsorption process, and the corresponding rate constants were found. To evaluate the parameters related to the adsorption process, the adsorption equilibrium was examined using a variety of mathematical models, such as the Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich isotherm models. The Langmuir isotherm was found to be the best appropriate among all models for describing the adsorption of Cu2+ and Ni2+ ions using bio-nanocomposite beads. The positive values of ΔH° indicate that the adsorption is physical and endothermic, in agreement with experimental results. The negative value of ∆G° shows that the adsorption process is spontaneous. Positive ΔS° values indicate increased randomness at the solid/liquid interface, during adsorption of Cu2+ and Ni2+ cations onto the engineered bio-nanocomposite. The maximum adsorbed amounts of metal ions by the bio-nanocomposite used were 370.37 mg/g for Ni2+ and 454.54 mg/g for Cu2+ from single system. For the binary system, according to the Langmuir isotherm, the maximum adsorbed amounts of Ni2+ and Cu2+ were 357.14 mg/g and 370,37 mg/g, respectively. There is proof that Alginate-Moroccan clay bio-nanocomposites can serve as a different, less expensive source of sorbents for the removal of metal ions from single and binary systems.

Tomato quality is intricately regulated by a combination of factors, including the presence of bioactive compounds referred to as secondary metabolites and various organoleptic characteristics. These attributes are notably influenced and harmonized by the specific growing conditions, with a particular emphasis on the type of fertilization employed. Traditionally, chemical fertilizers have been favoured in crop cultivation due to their cost-effectiveness and ability to accelerate crop growth. However, in pursuit of sustainable and intelligent agricultural practices, there is a growing need for alternative fertilizers. In this context, the present study aimed to assess the impact of fertilizers derived from waste materials, specifically sulphur bentonite and orange residue (referred to as SB), on tomato quality. This assessment extended to examining qualitative and quantitative alterations in aroma-related volatile compounds and the antioxidant systems of tomatoes, in comparison to the conventional use of fertilizers such as horse manure and NPK (nitrogen, phosphorus, and potassium). The results obtained revealed distinct effects of different fertilizers on tomato quality. Notably, parameters such as TPRO (total protein), TCARB (total carbohydrate), LIC (lycopene content), TCAR (total carotenoid content), total phenols, total flavonoids, and aroma profiling exhibited significantly superior values in the group treated with SB fertilizer. These findings strongly suggest that the novel fertilizer functioned as a bio-stimulant, enhancing the nutraceutical and sensory attributes of tomatoes, with a pronounced impact on the synthesis of secondary metabolites and the aroma profile of the fruits.

This paper investigates the dynamic properties of artificial neural networks using differential equations and explores the influence of parameters on stability and neural oscillations. By analyzing the equilibrium point of the differential equations, we identify conditions for asymptotic stability and criteria for oscillation in artificial neural networks. Furthermore, we demonstrate how adjusting synaptic weights between neurons can effectively control stability and oscillation. The proposed model offers potential insights into the malfunctioning mechanisms of biological neural networks implicated in neurological disorders like Parkinson's disease tremors and epilepsy seizures, which are characterized by abnormal oscillations.

Considering the current energy environment, both efficient and environmentally friendly solutions have to be developed for building construction. Bio-based building materials offer new perspectives through their insulating and natural humidity regulation capacities. Nevertheless, these materials are as complex as they are promising and grey areas still remain regarding their behavior. Their water sorption and desorption curves recorded in experimental work demonstrate a hysteresis phenomenon and, although plausible hypotheses have been formulated in the literature, there is currently no consensus on its causes. Furthermore, it is important to emphasize that no reference considers the hydrophilic nature of the resource. Yet this is a specificity of raw material coming from the plant world. In this context, this paper explores the microstructure and chemical composition of plant aggregates to propose a new explanation for the hysteresis. It is based on recent work demonstrating the existence of differentiated hydrogen bonds between the water sorption and desorption phase in cellulose. Obviously, hysteresis also has an origin at the molecular scale. Lastly, the hypothesis put forward here is supported by the swelling of bio-based materials that has been observed at high relative humidity and this study aims to identify a link between the mechanical (swelling/shrinking) of bio-based materials and their hygroscopic behavior. This leads to a better understanding of the hydro-mechanical coupling of these materials.

In terms of obtaining fuels as well as chemicals with or without catalysts at different conditions, the plum seed stands out as an alternative biomass source. Under varying heating rates (10, 50, and 100ºC min-1) and pyrolysis temperatures (400, 450, 500, 550 and 600 °C), the plum seed was pyrolysed at constant sweep gas flow at a constant rate (100 cm3min-1) in a tubular fixed bed reactor. According to the results, an oil yield reaching to a maximum of %45 was procured at the heating rate of 100 ºCmin-1 and the pyrolysis temperature of 550ºC in non-catalytic procedure. The catalytic pyrolysis was carried out in optimum conditions with two selected commercial catalysts, namely ZSM-5 and PURMOL-CTX and clinoptilolite (natural zeolite, NZ) with catalyst ratio of 10 % of raw material. Along with the catalyst addition, the quantity and the quality of bio-oil increased including the calorific value, removal of oxygenated groups, and hydrocarbon distribution. An increase related to the desirable products like phenols, alkene, and alkane and a decrease in undesirable products like acids were observed in the presence of catalysts. When all the results are considered and evaluated, using zeolite materials in the pyrolysis as catalysts is a recommendable option to achieve enhanced chemicals and fuels.

This work aimed to study the thermal and crystalline properties of poly (1,4-phenylene sulfide)@carbon char nanocomposites. Coagulation-processed nanocomposites of polyphenylene sulfide were prepared using synthesized mesoporous nanocarbon of coconut shell as reinforcement. The mesoporous reinforcement was synthesized using a facile carbonization method. The investigation of the properties of nanocarbon was done by SAP, XRD, and FESEM analysis. The research was further propagated via the synthesis of nanocomposite by the addition of characterized nanofiller into poly (1,4-phenylene sulfide) at five different combinations. The coagulation method was utilized for the nanocomposite formation. The obtained nanocomposite was analyzed using FTIR, TGA, DSC, and FESEM analysis. The BET surface area and average pore volume of bio-carbon prepared from coconut shell residue were calculated to be 1517 m2/g and 2.51 nm respectively. The addition of nanocarbon to poly (1,4-phenylene sulfide) has led to an increase in thermal stability and crystallinity up to 6% loading of filler. The minimum achievable glass transition temperature is for 6 % doping of filler into the polymer matrix. It was established that the thermal, morphological, and crystalline properties have been tailored by synthesizing their nanocomposites with mesoporous bio-nanocarbon obtained from coconut shells. So, the loading of filler into poly (1,4-phenylene sulfide) can be optimized to enhance its thermoplastic properties for surface applications.

Recent advances in microscopy imaging and image analysis motivate more and more institutes world-wide to establish dedicated core-facilities for bio-image analysis. To maximize the benefits research groups at these institutes gain from their core-facilities, they should be established to fit well into their respective environment. In this article, we introduce common collaborator requests and corresponding potential services core-facilities can offer. We also discuss potential conflicts of interests between the targeted missions and implementations of services to guide decision makers and core-facility founders to circumvent common pitfalls.

Molecular communication (MC) is a promising bio-inspired paradigm for exchanging molecule information among nanomachines. This paper proposes a synchronisation-assist photolysis MC system that aims to transmit the bio-sensing signal of the tumour microenvironment, facilitated by mitigating redundant molecules for improved bit error rate (BER) performance. Benefits from bio-compatible MC, biosensors could transmit bio-sensing signals of the tumour in $vivo$ instead of converting them to electrical signals. Due to diffusion motion's slow and stochastic nature, inter-symbol interference (ISI), resulting from previous symbols' residual information molecules, inevitably occurs in diffusion-based MC. ISI is one of the challenges in diffusion-based MC, which significantly impacts signal detection. Inspired by on-off keying (OOK) modulation, the proposed modulation implements a switch of molecules and light alternatively. The light emitted is triggered by a synchronisation signal, and the photolysis reactions could reduce the redundant molecules. An expression for the relevant channel impulse response (CIR) is derived from a hybrid channel model of diffusion and photolysis-reaction. This paper implements the maximum posterior estimation scheme to find the optimal decision threshold and analysis the BER performance in terms of different time intervals of the system. Numerical simulations demonstrate that the proposed method can improve the channel capacity and BER performance. We believe that our work may pave the way for MC application in bio-sensing.

Bio-economy is a major area of the strategy that can afford the European Union to achieve growth: (i) smart, through the development of knowledge and innovation; and (ii) sustainable, based on a greener, more efficient economy in resource management. We believe that the progress of bio-economy cannot be achieved without the harnessing of intellectual capital. Our research aimed to emphasize the benefits of the dynamics of the intellectual capital growth on the evolution of the bio-economy. Thus, the information published by Eurostat (European Statistic Institute) during a period spanning seven years (2011-2018) was used to assess the influence exerted by the conduct of the harness of intellectual capital related to sustainability as well as for the reporting of indicators relevant to appreciating an economic progress and sustainability (renewable waste material, share of renewable energy and energy intensity of the economy). The ultimate goal was represented by the generation of a regression model to see what factor influences mostly the progress of the bio-economy at European and Romanian level. Significant dependency relationships were identified. The results remain robust even after the introduction of certain control variables, such as gross domestic product rate, food production, population growth, urbanization growth and inflation. Our paper sets out to contribute to expanding the specialty literature by highlighting the involvement of intellectual capital as a factor in optimizing sustainability growth and, at a methodological level, by using a multiple regression.

Bio-economy is a major area of the strategy that must enable the European Union to achieve growth: smart, through the development of knowledge and innovation; and sustainable, based on a greener, more efficient economy in resource management. We believe that the progress of bio-economy cannot be achieved without the harnessing of intellectual capital. Our research aimed to emphasize the benefits of the dynamics of the intellectual capital growth on the evolution of the bio-economy. The aim of this analysis was to study the established link between the Energy Intensity of the Economy (EIE) and a number of factors that can measure the intellectual capital, such as: Market Capitalization of Bitcoin, Patent applications listed by European Patent Office and the Turnover from Innovation as a proportion of the total Turnover. The ultimate goal was represented by the generation of a regression model to see what factor influences mostly the progress of the bio-economy at European and Romanian level.

Bio-separation of natural molecules as well as clinical compounds has been constantly developed in last decades. Several techniques are available but the majority of them presents drawbacks such us impossibility to be applied for industrial purposes. The main limitations for the scaling up are high costs and the fact that the devices work with microfluid dynamics. Nevertheless, magnetic bio-separation is considered the most prone to be used for large scale applications. Herein, we propose a simple magnetic separation method that is not based on microfluid dynamics, can work in a continuous- and high-flow rate and can be easily automated in order to be used for standard separation purposes. It is based on the use of an anisotropic flexible ferric magnetic strip, Teflon hoses and a pumping device. We show the modelling of the separation process along with an experimental test on iron oxide magnetic particles. The results showed that it is possible to remove, and separately collect, more than 92% of magnetic particles from a liquid solution of 100 ml in roughly 15 minutes.

The characteristics of biogenic aerosols in urban area were explored by determining the composition, temporal distribution of saccharides in PM_2.5 in Shanghai. The total saccharides showed a wide range of 15.2 ng/m³ to 1752.8 ng/m³, with the averaged concentrations were 169.8 ng/m³，300.5 ng/m³，288.4 ng/m³，688 ng/m³ in spring, summer, autumn, and winter, respectively. The concerned saccharides include anhydrosaccharides (levoglucosan and mannosan), which were higher in cold seasons due to the increased biomass burning, saccharide alcohols (mannitol, arabitol, sorbitol) and monosaccharides (fructose, glucose), which showed more abundant in warm seasons attributed to the biological emissions. By PMF analysis, four emission sources of saccharides were demonstrated, including biomass burning, fungal spores, soil suspension and plant pollens. Resolution of backward trajectory and fire points showed a process of high concentrations of levoglucosan. We found that concentrations of anhydrosaccharides showed relatively stable under different pollution levels while saccharide alcohols exhibited an obvious decrease, indicated that biomass burning was not the core reason of the heavy haze pollution, however, and high level PM_2.5 pollution might inhibit effects of biological activities.

Spent nuclear fuel and high-level radioactive waste can be disposed in deep horizontal drillholes in sedimentary, metamorphic, or igneous rocks. Horizontal drillhole disposal has safety, operational, and economic benefits: The repository is deep in the brine-saturated zone far below aquifers in a reducing environment of formations that can be shown to have been isolated from the surface for millions of years; its depth provides safety against inadvertent intrusion, earth¬quakes, and near-surface perturbations; it can be placed close to the reactors and interim storage facilities, minimizing transportation; disposal costs per ton of waste can be kept substantially lower than for mined repositories by its smaller size, reduced infrastructure needs, and staged imple¬mentation; and, if desired, the waste could be retrieved using “fishing” technology. In the proposed disposal concept, corrosion-resistant canisters containing unmodified fuel assemblies from commercial reactors would be placed end-to-end in up to 50 cm diameter horizontal drill¬holes, a configuration that reduces mechanical stresses and keeps the temperatures below the boiling point of the brine. Other high-level wastes, such as capsules containing 137Cs and 90Sr, can be disposed in small-diameter drillholes. We provide an overview of this novel disposal concept and its technology, discuss some of its safety aspects, and compare it to mined repositories and the deep vertical borehole disposal concept.

Current agriculture intensifies crop cultivation to meet food demand, leading to unsustainable use of chemical fertilizers. This study investigates a few physiological and agronomic responses of common wheat following the inoculation with plant growth-promoting bacteria to reduce nitrogen inputs. A field trial was conducted in 2022-23, in Legnago (Verona, Italy) on Triticum aestivum var. LG-Auriga comparing full (180 kg ha-1) and reduced (130 kg ha-1) N doses, both with and without foliar application at end tillering of the N-fixing bacterium Methylobacterium symbioticum. Biofertilization did not improve shoot growth, while it seldom increased root length density in the arable layer. It delayed leaf senescence, prolonged photosynthetic activity, amplified stomatal conductance and PSII efficiency under reduced N dose. Appreciable ACC-deaminase activity of such bacterium disclosed augmented nitrogen retrieval and reduced ethylene production, explaining ameliorated stay-green. Yield and testing weight were unaffected by biofertilization, while both glutenin-to-gliadin and HMW-to-LMW ratios increased together with dough tenacity. It is concluded that Methylobacterium symbioticum can amplify nitrogen metabolism at reduced nitrogen dose, offering a viable approach to reduce chemical fertilization under suboptimal growing conditions for achieving a more sustainable agriculture. Further research over multiple growing seasons and soil types is necessary to corroborate these preliminary observations.

The organic fraction of municipal solid waste (OFMSW) is a significant environmental threat, and an economic and social challenge to manage. As such, the efficient treatment of OFMSW is a significant key factor in achieving sustainable waste management. Decentralized Composting (DC) develops a new framework of waste management. The DC Analysis Model (DCAM), proposed in our previous study, provides a powerful tool for decision makers, based on the quantification of the DC project characteristics. In this paper, we focus on the qualitative analysis as a complementary tool to support decision making, in cases where quantitative analysis is unequivocal. The qualitative analysis identifies the main players in the field, the critical stakeholders and the potential conflicts between them. It also reveals the root problems and the core competencies for the project's implementation. DCAM qualitative analysis in Shefa-Amr (case study) indicates that unresolved root problems, such as the “lack of national regulation”, “clear ownership of the project” and “lack of ongoing budget” can result in an unsustainable composting system. Countering that, “the commitment of the municipality”, together with “economic viability” and securing “suitable areas for placing composters” are among the most important core competencies for the effective implementation of DC projects.

Millions of tons of wool waste are produced yearly by textile industries, which may become a serious environmental hazard in the near future. Given this concern, it is crucial to explore strategies to reduce the amount of wool waste generated worldwide and adopt more sustainable practices for dissolving and regenerating wool keratin (WK) from textile waste. Most traditional methods involve the use of expensive, toxic, harmful, and poorly biodegradable compounds. To overcome these limitations and facilitate the reuse of wool waste through a cascade valorization strategy, researchers have started testing the use of deep eutectic solvents (DES) as a more sus-tainable and eco-friendlier alternative for WK dissolution and regeneration. In this study, the potential of two different DES mixtures, Choline chloride (ChCl): Urea and L-Cysteine (L-Cys): Lactic acid (LA), was explored for dissolving wool waste. Subsequently, the obtained gels based on DES-WK were blended with polyvinyl alcohol (PVA) in different ratios to produce nanofibers using the electrospinning technique. The effect of pH and the properties of the electrospinning solutions, namely electrical conductivity and viscosity, on the morphology of the gel solutions were evaluated. Moreover, the morphological features of the produced gel-based electrospun PVA/DES-WK nanofibrous membranes were analyzed using scanning electron mi-croscopy (SEM). Additionally, the PVA/L-Cys: LA DES-WK, which proved to be the most effective DES mixture for fabricating WK gel-based nanofibers, were characterized through Fourier transform infrared spectroscopy (FTIR) and tensile tests. Furthermore, their antioxidant and an-timicrobial abilities were evaluated. The results obtained revealed that this approach to valorize textile waste offers a unique avenue for the development of sustainable functional materials with potential applications in various biomedical and industrial fields.

Sharing the same raw material, recycling and composting are in direct conflict with incineration of municipal solid waste in combined heath and power plants. Indeed, waste-to-energy plants in regions with high recycling rates import urban waste from other countries to use otherwise unused capacity, and raise revenues. Using the case of Italy’s second largest and economically most developed region, I discuss the economic viability of municipal solid waste incineration to produce electricity and heath in the context of the increasing role of electricity production from renewable energy sources as well as of the emerging mass-scale uptake of bioplastics. Four lessons and three guidelines aimed to local authorities and policy makers emerge from the present study.

Lean is one of the systematic approach to achieve higher value for organizations through eliminate non-value-added activities. It is an integrated set of tools, techniques, and principles designed to optimize cost, quality and delivery while improving safety. In Vietnam, industry waste management and treatment has become serious issue. The aim of this research is to present the effective of Lean application for industrial wastes collecting and delivery improvement. Through a case study, this paper showed the way of Lean tools and principles applied for wastes management and treatment such as Value Stream Mapping, Pull system, Visual Control, and Andon.... to get benefit on both economic and environment. In addition, the results introduced a good experience for Vietnamese enterprises in cost saving and sustainable development in waste management.

Continuity of activities and projects are important for sustainably developing organizations, especially universities. The purpose of this research study is to find university development guidelines regarding waste management according to the green university ranking criteria for sustainable developments by studying and collecting the data covering the last five years (2019 - 2023) of Mahasarakham University. We also analyzed and synthesized lessons learned from the details of the operations and the factors involved in successes while comparing and providing suggestions for the operations in the next year. It was found that waste management that resulted in continuous developments that achieved the goals of Mahasarakham University consisted of the five guidelines. (1) Making green university policies and using them as the (key performance index) KPI of the divisions and also announcing the university's waste management policies by applying the principles of 3R (Reuse-Reduce-Recycle). (2) Allocating the budgets supporting the projects' activities according to the evaluation criteria. (3) Student and personnel participation as well as the mechanisms used by the committees from various administrative divisions such as Student Council, Student Association and clubs to drive the operations. (4) Identifying the main responsible individuals and committees for the green university who communicated and drove the operations while collecting, analyzing and preparing the data. (5) Follow-ups and evaluations of the project's activities with the Plan-Do-Check-Act (PDCA) processes for continuous and sustainable developments and improvements leading to the green university. With the above operations, Mahasarakham University's waste management scores of the six indices during 2019 - 3023 increased annually as follows: 900, 900, 1050, 1275 and 1350.

Objective: The aim of this study is to explore what inside the lipid lump obtained from skin. Try to understand the reasons for these physiological functions. In this paper, the lipid droplets or lumps was aimed to shed light on, figuring out what kind of cracks from metabolism were embedded inside. Results: A novel method was introduced for the detection of pathogens within lipid droplets extracted from acne or inflamed pores, as well as normal pores, using microscopic analysis. Through this technique, the presence of cracks from our body within these lipid droplets were identified. Methods: Observations were conducted using a microscope, with samples placed on slides and grind like blood smear. To enhance the transparency of the samples, tween-20 was utilized. This reagent was first time to be used for observing such big lipid lump of skin secretion. The evidences were recorded using the DMi8 camera from Leica.

Nano-emulsions of essential oils (EO) and their chemical constituents are promising raw materials for the ecological control of Tribolium castaneum. Curcuma longa Linn is a plant known for the properties of its rhizome which is used in food, health and hygiene products. Its leaves are by-products with no commercial value, but with unexplored bioactive volatile constituents. This study aims to evaluate the repellency of nano-emulsions containing the EO from leaves of C. longa or its three main chemical constituents against T. castaneum. The representative mixture of EO extracted in four different months showed p-cymene (26.0%), 1,8-cineole (15.1%) and terpinolene (15.5%) as major compounds. Nano-emulsions of EO (HLB 16.7), terpinolene (HLB 15.0), 1,8-cineole (HLB15.0) and p-cymene (HLB 15.0) were repellent at concentrations of 11 μg/cm2 (EO, terpinolene and p-cymene) and 1.1 μg/cm2 (1,8-cineole). The EO nano-emulsion droplet size increased linearly over time, remaining below 300 nm for 35 days and below 600 nm for 80 days. The EO nano-emulsion proved to be a green alternative to synthetic pesticides, as it was safe against the bioindicator Chlorella vulgaris. Terpinolene, 1,8-cineol and p-cymene were able to inhibit the enzyme telomerase from T. castaneum in an in silico assay, which may explain the repellency of these samples. This study provides ideas for the utilization of EO from leaves of C. longa as raw material of new environmentally friendly plant-derived nanobiopesticides.

This study aimed to investigate the effect of reducing the amount of organic waste on the weight of cats in Tehran. The weight of 4192 cats was measured from spring 2016 to the end of winter 2020. They were classified into 6 age groups, 2 gender groups, and 13 geographical areas. Their weight was measured for 48 months (16 seasons). The statistical parameters analysis showed no weight loss in 2017, but since 2018, cats have been losing weight every year. They had lost about 178g of their weight in 2018. The sharpest annual decrease was observed in 2019 when about 301g of weight loss was recorded. In the winter of 2020, 115g of weight loss took place. In the spring of 2017, no weight change was observed, but in the spring of 2018, the cats lost 155g of their weight. Their weight loss intensified in the spring of 2019 and about 299g of weight loss was observed. In the summer of 2017, as in the spring of the same year, no weight loss was recorded, but for the summer of 2018, the weight loss was evident and about 205g of the weight of the cats had been reduced. The weight loss in the summer of 2019 not only continued but intensified and about 304g of weight loss was recorded for cats. Weight change was not observed in the fall of 2017 as in the spring and summer of the same year. In the fall of 2018, weight loss was recorded for cats. They had lost about 324g of their weight in the fall of 2018. Also, they experienced a weight loss of about 218g in the fall of 2019. During the spring, summer, and autumn of 2017, no weight loss was observed in the cats for the winter of 2018, but in the winter of 2019, the cats faced the most severe weight loss (seasonally). They lost about 401g of weight in the winter of 2019. Of course, in the winter of 2020, about 186g of weight loss was observed in cats. The results showed that female cats did not lose weight in 2017 but experienced weight loss in 2018 with a weight loss of 181g. The weight loss of females intensified in 2019 and 294g of weight loss was recorded. Female cats lost 186g of their weight in the winter of 2020. Male cats did not lose weight like female cats in 2017. But in 2018, a weight loss of 166g was observed in male cats. The weight loss of male cats continued in 2019 and 311g of weight loss was recorded for them. However, in 2020, unlike females, weight loss was not observed in male cats. It can be said that both sexes lost more weight in the winter of 2019 than in other seasons. In 2017, weight loss was observed only for the region of 10, and in the same year, weight gain was recorded for the region of 15. But in 2018, except for regions 3, 4, 15, and 19, weight loss was observed in other regions. In 2019, the weight loss of cats spread and weight loss was observed in all regions except the region of 12. In winter 2020, weight loss was recorded only in the region of 4. In the end, it can be concluded that the weight of cats has decreased since the spring of 2018 because the beginning of the decrease in the amount of organic waste has been recorded since the winter of 2018. So, there is a direct relationship between the weight of cats and the amount of organic waste (access to food). The amount of garbage has been decreasing since the winter of 2018, and the average weight of cats has also been decreasing since the spring of 2018 due to the decrease in access to food.

Mining is an important industry that provides products and services through infrastructure systems worldwide. However, the global development promotes the steady growth and accelerated demand for minerals, resulting in the accumulation of hazardous waste in land, sea and air environments and, consequently a series of environmental and health problems. Restoration techniques from mining tailing have become increasingly discussed among scholars due to their potential to offer benefits over reducing tailings levels, thereby reducing environmental pressure for the correct management and adding value to previously discarded waste. This review paper critically explores available literature on the main techniques of mining tailing recycling, and discusses leading recycling technologies, including the advantages and drawbacks, as well as future perspectives. The findings of this review contribute as a reference for scholars as well as support for decisionmakers concerning the related environmental issues.

Forest recreation can be successfully used for the psychological relaxation of respondents and can be used as a remedy for common problems with stress. The special form of forest recreation intended for restoration is forest bathing. These activities might be distracted by some factors, such as viewing buildings in the forest or using a computer in nature, which interrupt psychological relaxation. One factor that might interrupt psychological relaxation is the occurrence of an open dump in the forest during an outdoor experience. To test the hypothesis that an open dump might decrease psychological relaxation, a case study was planned that used a randomized, controlled crossover design. For this purpose, two groups of healthy young adults viewed a control forest or a forest with an open dump in reverse order and filled in psychological questionnaires after each stimulus. A pretest was used. Participants wore oblique eye patches to stop their visual stimulation before the experimental stimulation, and the physical environment was monitored. The results were analyzed using the two-way repeated measures ANOVA. The measured negative psychological indicators significantly increased after viewing the forest with waste, and the five indicators of the Profile of Mood States increased: Tension-Anxiety, Depression-Dejection, Anger-Hostility, Fatigue, and Confusion. In addition, the negative aspect of the Positive and Negative Affect Schedule increased in comparison to the control and pretest. The measured positive indicators significantly decreased after viewing the forest with waste, the positive aspect of the Positive and Negative Affect Schedule decreased, and the Restorative Outcome Scale and Subjective Vitality scores decreased (in comparison to the control and pretest). The occurrence of an open dump in the forest might interrupt a normal restorative experience in the forest by reducing psychological relaxation. Nevertheless, the mechanism of these relevancies is not known, and thus, it will be further investigated. In addition, in a future study, the size of the impact of these open dumps on normal everyday experiences should be investigated. It is proposed that different mechanisms might be responsible for these reactions; however, the aim of this manuscript is to only measure this reaction. The identified psychological reasons for these mechanisms can be assessed in further studies.

The aim of this research study was to develop hydrogels samples for using in potential biomedical applications. Hydrogels consisting of different volumes of keratin, polyvinyl alcohol (PVA), Polyvinylpyrrolidone (PVP), and starch. The keratin is derived from the chicken was the primary material on the hydrogels due to attractively for the potential wound healing application. The hydrogel samples were made by using the freeze‑thawing method, and they were examined using the Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), porosity amusement, swelling ratio and keratin release kinetic models that analyzed using (zero-order, first-order Higuchi and Korsmeyer-Peppas models). These results were indicated that feather keratin could use with formulated hydrogels suitably for controlled keratin release studies .

Highlights: A new material with a bending strength higher than that of concrete was developed using vegetable or fruit waste. The new material maintains the color, taste, and flavor of the original vegetable or fruit. Without water resistant treatment, the material is edible and can be conditioned with seasonings

Solid waste management is a global issue that affects every individual living in the world directly or indirectly. Failing to manage the waste properly will cause harm on public health, our natural environment, and even our happiness and prosperity. When asked about the reason behind the failure of third time plastic ban in Bhutan, one of the Bhutanese said it’s because of the lack of cooperation from public to support the move of government. Clean Bhutan, a non-governmental organization (NGO) that aims Zero Waste Bhutan by 2030, has collected around 5,900 metric tons of waste from December 2014 to February 2018. This project will create some awareness regarding the management of waste at individual level when people come in contact with the family of the researcher. It also talks abot how waste management and biodiversity conservation can go side by side.

Biofuels have become an integral part of everyday life in modern society. Bioethanol and fatty acid methyl esters are a common part of both the production of gasoline and diesel fuels. Also, pressure on replacing fossil fuels with bio-components is constantly growing. Waste vegetable fats can be replacing biodiesel. HVO seems to be a better alternative. This fuel has a higher oxidation stability for storage purposes, a lower temperature of loss of filterability for the winter time, a lower boiling point for cold starts and other. Viscosity, density, cold filter plugging point of fuel blend, and flash point were measured to confirm that a fuel from HVO is so close to a fuel standard that it is possible to use it in engines without modification. The objective of this article is to show the properties of different fuels with and without HVO admixtures and to prove the suitability of using HVO compared to FAME. HVO can also be prepared from waste materials and no major modifications of existing refinery facilities are required. No technology in either investment or engine adaptation of fuel oils is needed in fuel processing.

Resilience embodies the personal qualities that enable one to thrive in the face of adversity. A previous Italian study showed that injured workers had a lower level of resilience than non-injured workers. The aim of this paper is to examine the relationship between occupational injuries and psychological resilience. The subjects were 197 drivers from two Finnish waste transport companies. As a part of larger questionnaire, they fulfilled the Connor-Davidson Resilience Scale, which consisted of 25 items. Drivers reported their occupational injuries during the last three years. The drivers involved in occupational injuries had higher score (average 69.3) on Connor-Davidson Resilience Scale than drivers avoided injuries (67.7). According to Student’s t-test the difference between groups was highly significant (t = 40.44, df = 196, p<0.001). The result of this study was contradictory to earlier Italian study. One explanation may be that the Italian study was done with traumatic context with seriously injured patients. Waste transport drivers were rather young and fit males, who had suffered only minor injuries.

When municipal solid waste (MSW) is landfilled, it begins to decompose under anaerobic conditions and is formed landfill gas is dominated by methane (CH4) and carbon dioxide (CO2). Reducing methane emissions is essential in the fight against climate change. It must be implemented at global and European levels, as set out in 2030 in the impact assessment of the climate goals plan. This assessment states that to achieve the goal by 2030 and to reduce greenhouse gas emissions by at least 55%, the methane emissions must be reduced, considering the goals of the Paris Agreement. The Glasgow Climate Pact includes a global mitigation target of 2030 year: to reduce CO2 emissions by 45%, the emissions of methane and other greenhouse gases. For that purpose, looking for new, more advanced ways of managing such waste is necessary. The main objective of the experimental study was to evaluate the influence of aeration, probiotic introduction, and water supply on the production of landfill gases (CO2, CH4, N2, H2, etc.) in the different fifth landfills’ models during the management of MSW and to propose the best solutions for reducing environmental pollution. The results of the research showed that the first and second models of landfills, using only anaerobic conditions, can be used for the treatment of MSW for the production of biogas (CH4, CO2), as up to 40–60% of it was released during the 120-experiment period. The third landfill model can be applied in old, already closed landfills, where rapid stabilization and aeration of MSW are required to minimize pollutant emissions (N2, etc.) and unwanted odors and shorten biodegradation processes. The results of the fourth and fifth landfill models, in which aerobicanaerobic conditions were applied, showed that the developing nitrification-denitrification processes resulted in complete nitrogen removal (from 20% to 0%), and overall waste stabilization improved the biodegradation of the MSW. Later, relatively good (on average 30%) results of biogas (CH4, CO2) emissions are achieved during anaerobic conditions formation results. Summarizing all experiment results of all landfill models for further evaluation of the processes, all models can be applied in real practice depending on where they will be used and what result they want to achieve.

Today, with the increase in population, technological developments, industrialization and urbanization, the problems related to waste management (WM) have become increasingly important to sustainably global clean environment. The gradual change in the quality of the elements that make up the environment, increasing environmental problems, and gaining global quality have caused societies to focus more on environmental problems. Waste management is a form of management that includes the prevention, non-prevention, reuse, recovery, and disposal of domestic, medical, hazardous, and non-hazardous wastes. In this study, it is aimed to prioritize critical success factors with the Analytical Hierarchy Process (AHP) in industrial waste management and to determine the most important critical success factor. The four main criteria and 23 sub-criteria were scored by the AHP method by five expert environmental engineers. Accordingly, after critical success factors were determined, survey questions were prepared to make employees rank these factors. While "national/local waste management strategies and policies" factor was the most important critical success factor according to experts, the most important critical success factor for employees was "enterprise waste management strategies and policies". In addition, differences in the priorities of CSFs were found in the opinions of employees in different sectors.

Solid waste management is a major environmental challenge, especially in developing countries, with increasing amounts of waste glass (WG) and waste plastics (WP) not being recycled. In Ethiopia, managing WG and WP requires innovative recycling techniques. This study examines concrete properties with WG and WP as partial replacements for fine aggregate. Tests were conducted on cement setting time, workability, compressive strength, splitting tensile strength, and flexural strength. Concrete grade C-25, with a compressive strength of 25 MPa, was prepared using an optimum ratio of 14% WG and 6% WP. Mechanical properties were tested at 7 and 28 days of curing. At 20% replacement, workability decreased at water-cement ratios of 0.5 and 0.6 but remained stable at 0.4. Thus, a 0.4 ratio was used. For 10% replacement, compressive strength increased by 12.55% and 6.44% on the 7th and 28th days, respectively. At 20% replacement, compressive strength decreased by 14.35% and 0.73% on the 7th and 28th days, respectively. On the 28th day, splitting tensile strength at optimum replacement was 4.3 MPa, an 8.5% reduction from the control mix. However, flexural strength increased by 19.7%, from 12.46 MPa to 15.52 MPa. Overall, WG and WP improved flexural strength but slightly reduced splitting tensile strength.

A suitable waste management strategy is crucial for a sustainable and efficient circular economy in the construction sector, and requires precise data on the volume of demolition waste (DW) gen-erated. Therefore, we developed an optimal machine learning (ML) model to forecast the quantity of recycling and landfill waste based on the characteristics of DW. A dataset comprising infor-mation on the characteristics of 150 buildings, demolition equipment utilized, and volume of five waste types generated (i.e., recyclable mineral, recyclable combustible, landfill specified, and landfill mix waste, and recyclable minerals) was constructed. ML models were developed to predict the quantities of such waste. Artificial neural network, decision tree, gradient boosting machine, k-nearest neighbors, linear regression, random forest (RF), and support vector regression were applied, and optimal models were derived via hyperparameter tuning. The RF model demonstrated superior performance. In both validation and test phases, the “recyclable mineral waste” and “recyclable combustible waste” models achieved accuracies of of 0.987 and 0.972, re-spectively. The “recyclable metals” and “landfill specified waste” models achieved accuracies of 0.953 and 0.858 or higher, respectively. Moreover, the “landfill mix waste” model exhibited an accuracy of 0.984 or higher. SHapley Additive exPlanations analysis highlighted floor area as the primary input variable influencing model performance. The type of equipment employed in demolition emerged as another crucial input variable impacting the volume of recycling and landfill wastes generated. The developed model can provide precise data on waste management, thereby facilitating the decision-making process for industry professionals.

In the face of 21st-century environmental challenges, including climate change, migration pressures, and waste disposal issues, certain healthcare sectors, notably dentistry, pose a significant global environmental footprint with concerns about carbon emissions and waste production. This scoping review delves into the paradox that healthcare, while dedicated to safeguarding health, inadvertently contributes to environmental degradation through waste accumulation and disposal. The analysis of relevant pertinent literature emphasizes the imperative for an environmentally sustainable approach to dental waste measurement, disposal methods, and comprehensive education for stakeholders. Aligned with the World Conference on Sustainable Development and the United Nations' 2030 Agenda, the study adhered to PRISMA-ScR scoping review guidelines and Institute of Medicine's recommendations. The study utilized Medline/PubMed and international organization websites for data retrieval, employing Boolean operator queries in Medline. A systematic literature analysis identified six cross-sectional studies (2004-2018) highlighting variations in dental waste composition due to the lack of standardized identification methods. This heterogeneity underscores the need for a proposed research model, emphasizing comprehensive methodologies and healthcare staff training in waste management. The study advocates for environmentally conscious dental practices, contributing to broader sustainable healthcare goals through sharing of a research protocol for dental solid waste management.

Natural fibers have attracted increasing interest as an alternative to produce environmentally friendly and sustainable materials. Particularly, hemp fibers have revealed to be widely used in various industrial applications due to their extremely unique properties. However, hemp can generate a large amount of agro-waste, and results in an attractive source of biopolymers for the development of low-cost materials in alternative to the raw materials and conventional petroleum-based plastics. In addition, deep eutectic solvents (DESs), a new type of truly green solvents, have been tested to remove gums, lignin, and other non-cellulosic components from hemp fibers. Reusing these components dissolved into the DESs to fabricate new materials directly by electrospinning is a very attractive but still unexplored endeavor. Thus, this innovative research to venture new upcycling pathways is focused on the fabrication of composite nanofibers by electrospinning of a gel-based blend of Poly(vinyl alcohol) (PVA) and hemp agro-waste (HW) dissolved into choline chloride (ChCl) : Glycerol (1:2) and ChCl : Urea (1:2) DES mixtures. The results obtained revealed that the produced nanofibers displayed uniform appearance with diameters ranging from 257.72 ± 65.63 nm to 380.78 ± 133.98 nm. In addition, the mechanical properties of the electro-spun composite nanofibers produced from the gel-based blends of HW dissolved in DESs and PVA (HW-DESs_PVA) were found to be superior, resulting in an enhanced tensile strength and Young’s modulus. Furthermore, the incorporation of HW into the nanofibers was able to provide bioactive antioxidant and antibacterial properties. Overall, this study demonstrated a promising, more sustainable, and eco-friendly way to produce electrospun composite nanofibers using HW in a circular economy perspective.

The accurate classification of landfill waste diversion plays a critical role in efficient waste management practices. Traditional approaches, such as visual inspection, weighing and volume measurement, and manual sorting, have been widely used but suffer from subjectivity, scalability, and labour requirements. In contrast, machine learning approaches, particularly Convolutional Neural Networks (CNN), have emerged as powerful deep learning models for waste detection and classification. This paper analyses VGG-16, InceptionResNetV2, DenseNet121, Inception V3, and MobileNetV2 models to classify real-life waste when trained on pristine and unadulterated materials, versus samples collected at a landfill site. When training on DiversionNet, the unadulterated material dataset with labels required for landfill modelling, classification accuracy was limited to 49.69% in the real environment. Using real-world samples in the newly formed RealWaste dataset showed that practical applications for deep learning in waste classification is possible, with Inception V3 reaching 89.19% classification accuracy on the full spectrum of labels required for accurate modelling.

Waste orange peel represents a heavy burden for the orange juice industry, estimated in several million tons per year worldwide; nevertheless, this by-product is endowed with valuable bioactive compounds, such as pectin, polyphenols and terpenes. The potential value of the waste orange peel has stimulated the search for extraction processes, alternative or complementary to landfilling or to the integral energy conversion. This study introduces controlled hydrodynamic cavitation processes, as a new route to the integral valorization of this by-product, based on simple equipment, speed, effectiveness and efficiency, scalability, and compliance with green extraction principles. Waste orange peel, in batches of several kg, was processed in more than 100 L of water, absent any other raw materials, in a device comprising a Venturi-shaped cavitation reactor. The extractions of pectin, endowed with a very low degree of esterification, polyphenols (flavanones and hydroxycinnamic acid derivatives), and terpenes (mainly d-limonene) were effective and fast (high yield, few min of process time), as well as the biomethane generation potential of the process residues was effectively exploited. The achieved results proved the viability of the proposed route to the integral valorization of waste orange peel, though wide margins exist for further improvements.

This study was undertaken to forecast waste generation rates of accommodation sector of North Cyprus as a case. Three predictor models including multiple linear regression (MLR), artificial neural networks (ANNs) and central composite design (CCD) were applied to predict the waste generation rate during the lean and peak seasons. ANN showed highest prediction performance, specifically, lowest values of the standard error of prediction (SEP = 2.153), mean absolute error (MAE=1.378) and highest R2 value (0.998) confirmed the accuracy of the model. The analysed wastes were categorised into recyclable, general waste and food residues. The authors estimated the total waste generated during the lean season as 2010.5 kg/day, in which large-sized hotel accounted for largest fraction (66.7%), followed by the medium hotels (19.4%) and guesthouse accounted for smallest part (2.6%). During the peak season, about 49.6% increases in the waste generation rates were obtained. Interestingly, 45% of the wastes were generated by the British tourists while the least waste was generated by African tourists (7.5%). The ANN predicted that the small and large hotels would produce 5.45 and 22.24 tons of waste by the year 2020, respectively. The findings herein are promising and useful in establishing a sustainable waste management system.

The “Pay-as-you-throw” scheme, PAYT, is an economic instrument of waste management that implements the “polluter pays” principle by charging inhabitants of municipalities according to the amount of residual, organic and bulky waste they send for third-party waste management. When combined with well-developed infrastructure to collect the different waste fractions (residual waste, paper and cardboard, plastics, bio waste, green cuttings, many recyclables) as well as with a good level of citizen’s awareness, its performance has frequently been linked to high collection rates of recyclables. However, the establishment and operation of PAYT systems can require significant resource inputs from municipalities. In this paper, PAYT is analysed through a case study from the German County of Aschaffenburg, covering nearly 20 years of implementation across 173,000 inhabitants. Key performance indicators applied include temporal trends in the county’s recyclables collection rate, waste treatment fees for residents and municipal waste management costs, benchmarked against German municipalities not implementing PAYT.

Bio-char is a charcoal-like substance made through the pyrolysis of organic biomass. It has the potential to address issues related to agriculture and the environment. This thorough analysis examines the potentials of bio-char in Ethiopia to enhance crop productivity, reduce climate change, and improve soil fertility. Drawing from academic databases and peer-reviewed literatures, the review explores the production and characterization of bio-char, its impact on soil fertility and crop productivity, and its role in carbon sequestration and greenhouse gas mitigation. The review emphasizes on how bio-char may improve plant nutrition and soil fertility, which raises agricultural yields and quality while improving drought resistance. The review also emphasizes the potential of bio-char for greenhouse gas mitigation and carbon sequestration, enhancing Ethiopia's efforts to mitigate climate change. Yet the study also points out several challenges and opportunities that need to be addressed to allow Ethiopians to use bio-char technology on a large scale. These include the need for appropriate policy and regulatory frameworks, the availability and accessibility of bio-char feedstocks, and the importance of continued research and development to optimize production methods and application strategies. The review concludes by highlighting the groundbreaking potential of bio-char in promoting environmentally friendly agricultural practices and sustainable agriculture in Ethiopia. It necessitates a coordinated effort to solve the problems and grasp the opportunities by making sound decisions in policy integration, research, and development. Ethiopia can advance its sustainable development goals by using bio-char to create a road towards increased food security, healthy soil, and environmental resilience.

Both, in developed and developing countries, atmospheric pollution with particulate matter (PM) remains an important issue. Despite the health effects of poor air quality, studies on air pollution are often limited by the high costs of continuous monitoring and the need of extensive sampling. Furthermore, these particles are often enriched in potentially toxic trace elements and organics pollutants. This study evaluates both, the composition of atmospheric dust accumulated during a certain time-span on leaves of Hedera helix and Senecio cineraria, as well as the potential to use them as bio-monitors. The test plants were positioned nearby automatic air quality monitoring stations at four different sites with respectively high, moderate and low traffic intensity. Gravimetric deposition of PM10 and PM2.5 on leaves was consistent with data recorded by the monitoring stations and related to the weather conditions reported by Argentina´s National Meteorological service. To determine the presence of trace elements enriching the PM deposited on leaves, two analytical techniques were applied, XRF (not destructive) and ICP (destructive). The results indicated that only in the unpaved street location (site 2), PM10 and PM2.5 concentrations in the air exceeded WHO guidelines. However, several trace elements were found enriching PM deposited on leaves from all sites. Predominantly, increased concentrations of Cd, Cu, Ti, Mn, Zn and Fe were found, which were associated to construction, traffic and unpaved street sources. Furthermore, based on its high capability to sequester PM and trace elements Senecio cineraria can be take into consideration to be adopted as a bio-monitor or even for PM mitigation.

A key component of nanomaterials, carbon dots (CDs) are zero-dimensional solids, smaller than 10 nm in size that include carbon as their backbone structure. Herbal medicine carbon dots (HM-CDs) are nanoparticles developed from medicinal plants. Owing to their advantageous properties, they are extensively employed in biological domains such as drug administration, bio-imaging, biosensors, and DNA interactions. It's interesting to note that, carbon dots pro-duced from herbal medicines as a raw material have surfaced as the most recent addition to the CD family. This article provides an overview of the several sources of green precursor, preparation tech-niques, characterization, and applications of CDs. It reviews recent advancements in synthe-sizing CDs made from green carbon materials and their potential uses as bioimaging, catalysts and sensing. Furthermore, several difficult issues and future directions for this potent and amazing content are also covered.

Syndemics theory has been applied to study interactions between biomedical and social factors leading to clustering of diseases. Because syndemics theory focuses on interactions that enhance risk, the concept of vulnerability is central to this approach. We conducted a scoping review to better understand how syndemics theory helped to define, operationalize, and tackle issues of vulnerability during the COVID-19 pandemic. Original research, review, and opinion pieces elaborating on syndemics, vulnerability and COVID-19, published between December 2019 and October 2022 and available in PubMed, were eligible. We analysed 40 records and identified three framings of syndemics operating during this period: (1) interactions between COVID-19, diseases/health conditions and specific social factors; (2) interactions between COVID-19 and social determinants of health; and (3) impacts of COVID-19 on specific populations. Emerging conceptualizations described vulnerability to COVID-19 as a systemic issue; explained the impact of COVID-19 control measures on increased vulnerability; and presented COVID-19 as a syndemic on its own. However, this theory's potential for deepening our understanding of vulnerability during this pandemic was constrained by superficial explorations of the interactions between biomedical and social spheres, and insufficient theoretical and methodological support from the social sciences.

Ethical considerations regarding our treatment of animals have gained strength, leading to legislation and a societal focus across various disciplines. This is a subject of study within curricula related to agri-food sciences. The aim was to determine the perceptions of agronomy university students concerning animal welfare in livestock production systems. A survey was conducted to encompass various aspects, from participants' sociodemographic attributes to their attitudes and behaviors regarding animal welfare and the consumption of animal products. Statistical analysis, performed using R software, delved into the associations between participants' characteristics and their perspectives on the ethical, bioethical, and legal dimensions of animal welfare. Associations between demographic factors and ethical viewpoints among students were identified. Gender differences emerged in animal treatment perceptions, while rural and urban environments impacted perspectives on various animals. Bioethical considerations revealed distinctive disparities based on gender and education in concerns for animal welfare, value perceptions, evaluations of animal behaviors, and opinions on animal research. It is crucial to distinguish between animal welfare and ethical considerations arising from coexisting with sentient beings capable of experiencing suffering. Ethical theories provide a lens through which we perceive our obligations toward animals. The responsibility to ensure animal welfare is firmly rooted in recognizing that animals, like humans, experience pain and physical suffering. Consequently, actions causing unjustified suffering or mistreatment, particularly for entertainment purposes, are considered morally unacceptable.

Diabetes mellitus (DM) is a metabolic disorder characterized by the deficiency of insulin production and is one of the concerning health problems worldwide, especially in developing countries. Considering the systemic toxicity associated with current antidiabetic medications and their limited efficacy, there is an urgent need to discover new plant-based natural antidiabetics. Since time immemorial, medicinal plants have played an important role in the management of health disorders. In recent years, herbal medicine has experienced exponential growth in popularity worldwide, owing to its natural origin and fewer side effects, appealing to both developing and developed nations. Ecuador has a rich cultural history in ethnobotany that plays a crucial role in their people's lives. Several Ecuadorian medicinal plants have hypoglycemic or an-ti-hyperglycemic properties that are rich with bioactive phytochemicals. These medicinal plants were extensively used in traditional medicine preparation in Ecuador for many decades to treat diabetes because of their cost-effectiveness, available traditional knowledge, and low toxicity. Many Ecuadorian medicinal plants are reported to have antidiabetic properties that reduce blood sugar levels, and oxidative stress, regulate intestinal function, improve insulin resistance, inhibit α-amylase and α-glucosidase, lower gluconeogenic enzymes, stimulate glucose uptake mechanisms, and play an important role in glucose and lipid metabolism, yet there is a substantial lack of integrated approach between the existing ethnomedicinal practice and pharmacological research. Therefore, this review aims to discuss and explore the traditional medicinal plants used in Ecuador for treating DM and their bioactive phytochemicals, which are mainly responsible for their anti-diabetic properties.

This article introduces a novel nature-inspired metaheuristic algorithm called Frilled Lizard Optimization (FLO), which emulates the hunting behavior of frilled lizards in their natural habitat. FLO draws in-spiration from the sit-and-wait strategy observed in frilled lizards during hunting. The underlying theory of FLO is presented and mathematically formulated in two phases: (i) an exploration phase, simulating the frilled lizard's attack towards prey, and (ii) an exploitation phase, simulating the lizard's retreat to the top of the tree after feeding. To assess FLO's efficacy in solving optimization problems, the algorithm's performance is evaluated across fifty-two standard benchmark functions, encompassing unimodal, high-dimensional multimodal, fixed-dimensional multimodal, and the CEC 2017 test suite. Comparative analyses with twelve existing metaheuristic algorithms are conducted. The simulation results reveal that FLO, distinguished by its adeptness in exploration, exploitation, and balancing them during search process, outperforms competing algorithms. Additionally, FLO is implemented on twenty-two constrained optimization problems from the CEC 2011 test suite and four engineering design problems, demonstrating its effectiveness in addressing real-world optimization applications.

Naturally-derived synthetic leather is a widely used and high-quality type of faux leather or synthetic leather. Many consumers prefer authentic leather goods due to their exceptional qualities, including high water vapor permeability and superior wearing comfort. Consequently, the exploration of artificial leather made from natural materials with exceptional qualities as an alternative to genuine leather has garnered significant interest and is now a highly studied subject. Synthetic leather, sometimes known as imitation leather, has gained popularity recently as a highly suitable alternative to genuine leather. Continuous advances in this area of research increase the range of uses for synthetic leather using natural fibers. Thus, this research aims to explore synthetic leather materials using orange peel waste, which can be applied to the fashion industry. This research applies several types of orange peel waste, such as Pomelo, Sweet orange, and Sunkist orange, to different compositions and strengthening materials, such as bandages and dacron. The resulting bio-composite materials' morphology, mechanics, and adhesive properties were evaluated following ASTM D 2209-00 and ASTM D 4533-04 standards. The results indicate that specimen 1A (Pomelo using bandage as reinforcement) has the most significant effects, with a tensile test value of approximately 472 N/cm2, an elongation of roughly 67.28 % was the highest value on sweet orange using bandage as reinforcement, and a tear resistance of around 14.28 N/cm2 for Pomelo with bandage as reinforcement. Furthermore, the test results also show that composition 2B still does not meet the standards of SNI 1294:2009 and ISO 3376 for tensile strength and ISO 3377-1 for tear strength. Additionally, statistical analysis showed no appreciable changes in the samples analyzed. Furthermore, statistical evaluations showed no significant alterations in the studied samples. The results of this experimental investigation can be explored further and used as a basic framework for the creation of bio-composites from orange peel waste for future fashion.

Coronary artery disease is the most prevalent cardiovascular disease, claiming millions of lives annually around the world. The current treatment includes surgically inserting a tubular construct called as a stent inside arteries to restore blood flow. However, due to lack of patient-specific design, the commercial products cannot be used with different vessel anatomies. In this review, we have summarized the drawbacks in existing commercial metal stents which face problems of restenosis and inflammatory responses, owing to the development of neointimal hyperplasia. Further, we have highlighted the fabrication of stents using biodegradable polymers, which can circumvent most of the existing limitations. In this regard, we elaborated on utilization of new fabrication methodologies based on additive manufacturing such as three-dimensional printing to design patient-specific stents. Finally, we have discussed on the functionalization of these stent surfaces with suitable bioactive molecules which can prove to enhance their properties in preventing thrombosis and better healing of injured blood vessel lining.

During the last forty years, the use of strontium isotopes in archaeology and biogeochemical research has spread widely. These isotopes, alone or in combination with others, can contribute to trace past and present environmental conditions. However, the interpretation of the isotopic values of strontium is not always simple and requires good knowledge of geochemistry and geology. This short paper on the use of strontium isotopes is aimed at those who use this tool (archaeologists, but not only) but who do not have a thorough knowledge of mineralogy, geology, and geochemistry necessary for a good understanding of natural processes involving these isotopes. We report basic knowledge and suggestions for a correct use of these isotopes. The isotopic characteristics of bio-assimilable strontium depend not so much on the isotopic characteristics of the bulk rock as, rather, on that of its more soluble minerals. Before studying human, animal and plant remains, the state of conservation and any conditions of isotopic pollution should be carefully checked. Samples should be collected according to random sampling rules. The data should be treated by a statistical approach. To make comparisons between different areas, it should be borne in mind that the study of current soils can be misleading since the mineralogical modification of the soil over time can be very rapid.

This study explores the impact of temperature and molarity on the pyrolysis of Açaí seeds (Euterpe Oleraceae, Mart.) activated with KOH on the yield of bio-oil, hydrocarbon content of bio-oil, an-tioxidant activity of bio-oil and chemical composition of aqueous phase. The experiments were carried out at 350, 400, and 450 °C and 1.0 atmosphere, with 2.0 M KOH, and at 450 °C and 1.0 atmosphere, with 0.5 M, 1.0 M and 2.0 M KOH, in laboratory scale. The composition of bio-oils and aqueous phase determined by GC-MS, while the acid value, a physical-chemical property of fundamental importance in biofuels, of bio-oils and aqueous phases by AOCS methods. The an-tioxidant activity of bio-oils determined by the TEAC method. The solid phase (biochar) charac-terized by X-ray diffraction (XRD). The diffractograms identified the presence of Kalicinite (KHCO3) in biochar, and those higher temperatures favor the formation peaks of Kalicinite (KHCO3). The pyrolysis of Açaí seeds activated with KOH show bio-oil yields from 3.19 to 6.79 (wt.%), aqueous phase yields between 20.34 and 25.57 (wt.%), solid phase yields (coke) between 33.40 and 43.37 (wt.%), and gas yields from 31.85 to 34.45 (wt.%). The yield of bio-oil shows a smooth exponential increase with temperature. The acidity of bio-oil varied between 12.3 and 257.6 mgKOH/g, decreasing exponentially with temperature, while that of aqueous phase between 17.9 and 118.9 mgKOH/g, showing and exponential decay behavior with temperature, demonstrating that higher temperatures favor not only the yield of bio-oil but also bio-oils with lower acidity. For the experiments with KOH activation, the GC-MS of bio-oil identified the presence of hydro-carbons (alkanes, alkenes, cycloalkanes, cycloalkenes, and aromatics) and oxygenates (carboxylic acids, phenols, ketones, and esters). The concentration of hydrocarbons varied between 10.19 to 25.71 (area.%), increasing with temperature, while that of oxygenates from 52.69 to 72.15 (area.%), decreasing with temperature. For the experiments with constant temperature, the concentrations of hydrocarbons in bio-oil increase exponentially with molarity, while those of oxygenates de-crease exponentially, showing that higher molarities favor the formation of hydrocarbons in bio-oil. The antioxidant activity of bio-oils decreases with increasing temperature, as the content of phenolic compounds decreases, and decreases with increasing KOH molarity, as higher molarities favors the formation of hydrocarbons. Finally, it can be concluded that chemical activation of Açaí seeds with KOH favors the not only the yield of bio-oil but also the content of hydrocarbons. The study of process variables is of utmost importance in order to clearly assess reaction mechanisms, economic viability and design goals that could be derived from chemically activated biomass pyrolysis processes.

The aerospace industry demands high-performance materials that can withstand extreme conditions and maintain efficiency in a variety of applications. Bio-inspired polymer coatings have emerged as a promising approach to meet these demands, by drawing inspiration from natural systems to develop new coatings that exhibit enhanced properties, such as self-cleaning, anti-icing, thermal management, and corrosion resistance. In this review, recent developments in the field of bio-inspired polymer coatings for aerospace applications are presented, covering a range of coatings and their respective properties. We discuss the recent developments and applications of bio-inspired coatings, with a focus on their advantages and challenges in aerospace applications. We also highlight the potential for future research and development in this field, including the integration of advanced technologies such as nanotechnology and additive manufacturing. The review aims to provide insights into the current state-of-the-art of bio-inspired polymer coatings for aerospace applications and to inspire further research in this rapidly growing field.

As the human-body controls depend on the brain neuro current, here assay is related to thinking nerve detection. For this purpose, the brain current was analyzed by electrochemical three-electrode systems using 0.1-mm micro wire in vivo probe, which probe was made by using carbon nanotube paste coated needle type. Here working electrode was inserted in the rat brain’s muscle core with a 0.3-mm-diameter needle type Ag/AgCl Cl-coated Ag wire reference, and counter electrode of 0.1-mm-diameter Pt micro needle was inserted 5 mm deep into the in vivo muscle skin, under anesthesia with 2.0 ~ -2.0 V potential windows, 50 mv/s cyclic scan and 1.0x10-5A chrono amperometric sensitivity on the body systems. Under the optimum conditions, diagnostic application was performed to such as smell signal, muscular strength, five sense assay and thinking neuro current.

The current concerns of both society and materials industries about the environmental impact of thermoset composites, as well as new legislation, have led the scientific sector to search for more sustainable alternatives to reduce the environmental impact of thermoset composites. Until now, to a large extent, sustainable reinforcements have been used to manufacture more sustainable composites and thus contribute to the reduction of pollutants. However, in recent years, new alternatives have been developed such as thermosetting resins with bio-based content and/or systems such as recyclable amines and vitrimers that enable recycling/reuse. Throughout this review, some new bio-based thermoset systems as well as new recyclable systems and sustainable reinforcements are described and a brief overview of the biocomposites market and its impact is shown.

Latterly, the development of green synthesized polymeric nanoparticles with anticancer studies has been an emerging field in academia, and in the pharmaceutical and chemical industry. Vegetable oils are potential substitutes for petroleum derivatives, as they present themselves as a clean and environmentally friendly alternative and are available in high quantities at relatively low prices. Biomass-derived chemicals can be converted into monomers with unique structures, generating materials with new properties for the synthesis of sustainable monomers and polymers. In this way, the production of bio-based polymeric nanoparticles appears as a great application of green chemistry for biomedical uses. There is an increasing demand for biocompatible and biodegradable materials for specific applications in biomedical as cancer therapy, encouraging scientists in working on research towards designing polymers, with enhanced properties and clean processes, containing oncology active pharmaceutical ingredients (APIs). The nanoencapsulation of these APIs in bio-based polymeric nanoparticles can control the release of the substances, increase bioavailability, reduce problems with volatility and degradation, reduce side effects, and increase treatment efficiency. Thus, this review aims to discuss the use of green chemistry for bio-based nanoparticle production and its application in anticancer medicine. The use of vegetable oils for the production of renewable monomers and polymers will be discussed, bringing castor oil as an ideal candidate for such application, as well as more suitable methods for the production of bio-based nanoparticles and some oncology APIs available for anticancer application.

Fossil-based plastics are significant contributors to global warming through CO₂ emissions. For more sustainable alternatives to be successful, it is important to ensure that consumers become aware of the benefits of innovations such as bio-based plastics, in order to create demand and a willingness to initially pay more. Given that consumer attitudes and (inaccurate) beliefs can influence the uptake such new technologies, we investigated participants’ attitudes towards fossil-based and bio-based plastic, their perceived importance of recycling both types of plastic, their willingness to pay, and their perceptions of bio-based plastic in four studies (total N = 961). The pre-registered fourth study experimentally manipulated information about bio-based plastic and measured willingness to pay for different types of plastic. The results suggest participants hold very favourable attitudes and are willing to pay more for bio-based products. However, they also harbour misconceptions, especially overestimating bio-based plastic’s biodegradability, and they find it less important to recycle bio-based than fossil-based plastic. Study 4 provided evidence that educating consumers about the properties of bio-based plastic can dispel misconceptions, retain a favourable attitude and a high willingness to pay. We found mixed evidence for the effect of attitudes on willingness to pay, suggesting other psychological factors may also play a role. We discuss how attitudes and misconceptions affect the uptake of new sustainable technologies such as bio-based plastics and consumers’ willingness to purchase them.

Bio-surfactants are surface-active molecules which are produced by the wide range of microbes including bacteria, fungi, and yeast. This study was conducted to identify bio-surfactants by Bacillus subtilis combined with use of cheap substrates and industrial wastes (Mustard cake, Whey and Soya cake) which are found locally in Nepal. Bacillus subtilis, one of the most potential bio-surfactants producer; was isolated from soil sample of hydrocarbon contaminated site. Isolates were grown in a Minimal Salt Media (MSM) with 10% (v/v) mustard oil cake, whey and soya cake separately. The presence and potential of surfactant was determined by the oil spreading technique, emulsification index (%E24) and surface tension measurement. It was revealed that the surface tensions of cell free extract were 54.41, 60.02 and 56.64 mN/m for from mustard cake, whey and soya cake respectively as compared to distilled water (72.09) at 25oC. The emulsification index values are was found to be highest in engine oil from the bio-surfactant extracted from mustard cake, soya cake and whey respectively. Similarly, mustard oil showed the lowest value of emulsification index. The highest emulsification activity was shown in mustard oil i.e. 1.13 from the cell free extract from mustard oil and lowest in engine oil i.e., 0.07, by the extract from soya cake medium, when measured in spectrophotometer at 540 nm. In conclusion, strain of Bacillus subtilis was found to be the potential surface active agent producers on the mustard oil cake, which can be useful medium for various environmental, food and industrial processes.

Carboxylic acids such as acetic acid and propionic acid have been investigated as representative components for fast pyrolysis (FP) bio-oil upgrading. Selective catalytic conversion of carboxylic acids can enhance bio-refinery processing economics through catalyst preservation and process intensification. Various metal-doped molybdenum carbide bead catalysts have been synthesized and developed in this work. Our aim is to enable selective conversion of carboxylic acids. In the case of acetic acid conversion, calcium doped Mo₂C beads offer the highest yield of acetone ~96% at 450 °C among undoped and Ca or Ni doped catalysts. By comparing hot gas filter with and without Ca-Mo₂C catalyst tested with real FP vapors, the former showed a 36.7% reduction of acetic acid, a 37.5% reduction of small ketones in aqueous phase, and a ~50% reduction of methoxies (methoxy phenols and methoxy aromatics) in organic phase. The conversion resulted in the formation of more long chain chemicals in the organic phase, which are more amendable for downstream upgrading.

High density polyethylene (HDPE) and poly(lactic) acid (PLA) blends with different ratios of both polymers, namely 30:70, 50:50 and 70:30, were produced. Polyethylene grafted maleic anhydride and a random copolymer of ethylene and glycidyl methacrylate, were also proposed as compatibilizers to modify HDPE-PLA optimal blends and were added in the amounts of 1, 3 and 5 wt.%. Blends properties have been evaluated through different aspects by performing tensile tests, scanning electron microscopy to analyze blend morphology and interfaces, and thermomechanical analysis through differential scanning calorimetry, thermo-gravimetric analyses and infrared spectroscopy. The second blend, the one with equal amounts of HDPE and PLA seems to represent a good balance between high amount of bio-derived charge and acceptable mechanical properties. This suggests a good potential of these blends, which would be a good starting point for the production of composites with lingo-cellulosic fillers.

The species and bio-availability of phosphorus (P) in primary, secondary and digested sludge were fractionated and further analyzed in this study. Results showed that inorganic P (IP) was the primary P fraction in the secondary sludge and digested sludge, in which non-apatite IP (NAIP) amounted to 91.6% and 69.3% of IP, respectively. Organic P (OP), accounting for about 71.7% of total P (TP), was the dominant P composition in primary sludge. The content of bio-available P was about 9.7, 43.4, 29.8 mg-P/g-TS in primary sludge, secondary sludge and digested sludge, respectively, suggesting secondary sludge is the optimal choice when land application of sewage sludge is taken into consideration, followed by digested sludge and primary sludge. Polyphosphate and orthophosphate, comprising approximately 54.3% and 89.2% of TP, was the dominant P species in the secondary sludge and digested sludge, respectively. Monoester-P (54.6% of TP in extract) and diester- P (24.1%) were identified as OP species in primary sludge by Phosphorus-31 nuclear magnetic resonance (31PNMR). The present results would be helpful for P recovery and recycle from sewage sludge in wastewater treatment plant.

Adenine nucleotide (AN) 2^nd messengers such as 3’,5’-cyclic adenosine monophosphate (cAMP) are central elements of intracellular signaling, but many details of underlying processes remain still elusive. Like all nucleotides, cyclic nucleotide monophosphates (cNMPs) are net-negatively charged at physiologic pH which limits their applicability in cell-based settings. Thus, many cellular assays rely on sophisticated techniques like microinjection or electroporation. This setup is not feasible for medium- to high-throughput formats, and the mechanic stress that cells are exposed to raises the probability of interfering artefacts or false-positives. Here, we present a short and flexible chemical route yielding membrane-permeable, bio-reversibly masked cNMPs for which we employed the octanoyloxybenzyl (OB) group. We further show hydrolysis studies on chemical stability and enzymatic activation, and present results of real-time assays, where we used cAMP and Ca²⁺ live cell imaging to demonstrate high permeability and prompt intracellular conversion of some selected masked cNMPs. Consequently, our novel OB-masked cNMPs constitute valuable precursor-tools for non-invasive studies on intracellular signaling.

The impact of nanomaterials on lung fluids or on the plasma membrane of living cells has prompted researchers to examine the interactions between nanoparticles and lipid vesicles. Recent studies have shown that nanoparticle-lipid interaction leads to a broad range of structures including supported lipid bilayers (SLB), particles adsorbed at the surface or internalized inside vesicles, and mixed aggregates. Today, there is a need to have simple protocols that can readily assess the nature of structures obtained from particles and vesicles. Here we apply the method of continuous variation for measuring Job scattering plots and provide analytical expressions for the scattering intensity in various scenarios. The result that emerges from the comparison between modeling and experimental measurements is that electrostatics plays a key role in the association, but it is not sufficient to induce the formation of supported lipid bilayers.

1) Background: The environmental, financial and social questions in Africa remain unanswered up-to-date, with the rapid increase in human population and the demand for fuel energy, trigger the need to generate data on the socio-economic factors influencing the knowledge of use and adoption of family-sized bio-digesters. The increasing prices of fossil fuels and taxes on energy sources require finding the alternative, clean and economical sources of energy for households in developing countries. Moreover, in Africa, the consumption of firewood and charcoal continues to increase, with wood fuel consumption predicted to increase by 2030 to over 140%. The study objectives were 1) to determine the socio-economic characteristics of the people in Ngoma district, 2) to assess socio-economic factors influencing people to use and adopt family-sized bio-digesters. 2) Methods: Quantitative data collected with semi-structured questionnaires and interviews were analyzed using descriptive statistics. 3) Results: The results show that many households had not realized the potential benefits of biogas use and adoption in Rwanda. The study further found that a number of factors such as household income levels, socio-economic, technological, and institutional influence the household use and adoption of biogas energy. 4) Conclusions: At the end, the study suggests the need for all players such as Government, Non-Governmental Organizations (NGO's) and local communities to work together to provide incentives and favorable environment that can attract individual households to invest in biogas energy production and utilization.

A tumbler screen type residual film–impurity mixture wind separator as a key equipment for secondary utilization of farmland residual film. During the working process, the proportion of impurities in the separated waste mulch film intermittently increases, resulting in poor working stability of the device, which may hamper long-term operation. In this study, the material inside the separation unit was continuously monitored, and the main factor affecting separator per-formance was determined to be the challenges in the effective depolymerization of some residual film–impurity mixtures. The principles of agglomeration and depolymerization of the residual film–impurity mixtures were analyzed using computational fluid dynamics (CFD) and discrete element method (DEM) flow-solid coupling simulation methods. The key factor affecting the disaggregation of the mixture was the collision force between the residual film–impurity mixture and the trommel screen. The collision force was maximum when the residual film–impurity mixture first collided with the trommel screen when it was fed into the separation device. As determined by force analyses, the key factors affecting the collision force of the process were the material feeding amount and the structure of the inlet. Furthermore, simulations were carried out for different inlet structure forms; the evaluation index was the maximum collision force of the residual film–impurity mixture agglomerate on the trommel screen. The best disaggregation effect was obtained with a square feed inlet and at a feeding rate of 202 kg/h. A prototype was built using these specifications for verification. The average value of the ratio of impurities in the re-sidual film was 6.966%, the coefficient of variation was 7.38%, and the dispersion of statistical results was small. The ratio of impurities in the residual film was kept constant during the con-tinuous operation of the wind separator. Thus, this study analyzed the agglomerate disaggregation process and provided theoretical insights for deter-mining the optimal structures of the inlets of various cleaning devices and the feeding volumes.

In this study, a decentralized incineration facility was evaluated over a three-year period, focusing on performance aspects such as burning rate, ash production, fuel and electricity consumption, and ash composition while processing animal by-products (ABP). The total cost for ABP incineration was determined to be 159 € per ton of ABP, with the major components being capital depreciation (42%), maintenance expenditures (26%), labor (18%), and transportation costs (9%). Liquified petroleum gas (LPG) consumption ranged from 3-7 kg per ton of ABP, while electricity use was between 15-20 kWh per ton of ABP incinerated. The incineration process generated 7-10% (by weight) ABP ash, which was characterized by high calcium and phosphorus content and low levels of hazardous trace elements. Leaching tests demonstrated the potential for recovering the alkaline supernatant for flue gas treatment and the phosphorus-rich slurry for fertilizer production. The findings suggest that energy recovery and valorization are crucial for minimizing operational costs and environmental impact, emphasizing the benefits of integrating advanced resource recovery techniques in ABP incineration facilities.

By the end of 2023, biowaste must be completely separated or recycled at source based on the EU legislation. Separate biowaste collection and valorisation towards biofuels could play an essential role in the biobased circular economy. In this context, the principal goal of this paper was to demonstrate in pilot scale the technological solution of bioethanol production via the utilisation of urban source-separated biowaste within the city context of Athens, Greece. More specifically, the main aim was the demonstration of a pilot system in continuous operation (over 10 operating cycles) with real feedstock – wet separately collected biowaste. From the 11 pilot trials performed with wet feedstock, the mean starch and cellulose degradation of the pilot trials amounted up to 80.69±16.27% and 79.41±10.37% respectively, while the bioethanol yield was 74.05±6.82%. The latter was comparable to that of more intensive pretreatment methods. Homogenization and shredding that was applied in this study, stand as promising and cost-effective pretreatment methods for bioethanol production from wet feedstock. Further research is needed to optimize conditions and evaluate scalability. Nevertheless, pilot scale testing is a crucial step in the development and deployment of this technology since it serves as a bridge between laboratory research and full-scale implementation, offering a practical and controlled environment to validate and optimize the technology while minimizing risks and uncertainties.

The basic principles of geological risk calculation through Probability of Success (PoS) are mostly applied for numerical estimation of additional hydrocarbon existence in proven reservoirs or potential hydrocarbon discoveries in selected geological regional subsurface volume. It can be tailored and validated for a comprehensive input dataset collected in the selected petroleum province, adapted by dividing up geological events into several probability categories and classes. The most applied categories are (existence of) reservoir rocks, traps and isolators, source rocks, migration pathways and preservation conditions for hydrocarbons The methodology results in unique probability values as multiplication of independent statistical events, which can also be applied in the assessment of a potential hydrocarbon discovery of desired minimal volume and its value in any virtual currency like risk-neutral dollars. Such methodology has been extensively developed in the last decades in the Croatian subsurface, mostly in the Croatian part of the Pannonian Basin System (CPBS). Through the adaptation of geological categories, it was also applied in hybrid, i.e., stochastical, models developed in the CPBS (Drava Depression). Stochastically estimation of porosity was already applied. As the robustness of this methodology is very high, it was also modified to estimate the influence of water-flooding in increasing oil recovery in some proven Neogene sandstone reservoirs in the CPBS (Sava Depression). This new modification is being presented to be applied to geological risk calculation, intending to assess the safety of geological environment in deep wells, where depleted radioactive fuel would be disposed, a subject of great importance. The case study encompassed the magmatic and metamorphic rocks in the pre-Neogene basement of the CPBS. For disposal purpose, these are regionally lithologies considered as to be the safest ones considering petrophysical values, water saturation, recent weathering and tectonic activity.